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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Editor: G. I. Stegeman
  • Vol. 22, Iss. 11 — Nov. 1, 2005
  • pp: 2444–2449

Nonlinear susceptibility of colloids consisting of silver nanoparticles in carbon disulfide

Edílson L. Falcão-Filho, Cid B. de Araújo, André Galembeck, Marcela M. Oliveira, and Aldo J. G. Zarbin  »View Author Affiliations


JOSA B, Vol. 22, Issue 11, pp. 2444-2449 (2005)
http://dx.doi.org/10.1364/JOSAB.22.002444


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Abstract

Measurements of the effective third-order susceptibility χ<sup>(3)</sup><sub>eff</sub>(ω,ω,−ω,ω) of a colloid consisting of silver nanoparticles (NPs) in liquid carbon disulfide (CS2) are reported for excitation at 532 nm. Changes in χ<sup>(3)</sup><sub>eff</sub>(ω,ω,−ω,ω) were controlled varying the NP filling factor f. Cancellation and sign reversal of the nonlinear (NL) index of refraction and the NL absorption coefficient of the colloid were observed owing to competing contributions from the NP and the CS2 molecules. The Re χ<sup>(3)</sup><sub>eff</sub>(ω,ω,−ω,ω) and Im χ<sup>(3)</sup><sub>eff</sub>(ω,ω,−ω,ω) change linearly when f assumes values from 0.4×10<sup>−5</sup> to 4.0×10<sup>−5</sup>. An analysis of the results is provided using a generalized Maxwell Garnett model that allowed evaluation of the NL susceptibility of the NP.

© 2005 Optical Society of America

OCIS Codes
(160.4330) Materials : Nonlinear optical materials
(190.3970) Nonlinear optics : Microparticle nonlinear optics
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials
(240.6680) Optics at surfaces : Surface plasmons

ToC Category:
Nonlinear Optics

Citation
Edílson L. Falcão-Filho, Cid B. de Araújo, André Galembeck, Marcela M. Oliveira, and Aldo J. G. Zarbin, "Nonlinear susceptibility of colloids consisting of silver nanoparticles in carbon disulfide," J. Opt. Soc. Am. B 22, 2444-2449 (2005)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-22-11-2444


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References

  1. D. Ricard, Ph. Roussignol, and C. Flytzanis, “Surface-mediated enhancement of optical phase conjugation in metal colloids,” Opt. Lett.  10, 511–513 (1985).
  2. F. Hache, D. Ricard, and C. Flytzanis, “Optical nonlinearities of small metal particles: surface-mediated resonance and quantum size effects,” J. Opt. Soc. Am. B  3, 1647–1655 (1986).
  3. See, for example, M. Yamane and Y. Asahara, Glasses for Photonics (Cambridge U. Press, 2000).
  4. V. M. Shalaev, Nonlinear Optics of Random Media (Springer, 2000).
  5. M. H. G. Miranda, E. L. Falcão-Filho, J. J. Rodrigues Jr., C. B. de Araújo, and L. H. Acioli, “Ultrafast light-induced dichroism in silver nanoparticles,” Phys. Rev. B  70, 161401 (2004). [CrossRef]
  6. H. Kuwata, H. Tamaru, K. Esumi, and K. Miyano, “Resonant light scattering from metal nanoparticles: practical analysis beyond Rayleigh approximation,” Appl. Phys. Lett.  83, 4625–4627 (2003).
  7. K. L. Kelly, E. Coronado, L. L. Zhao, and G. C. Schatz, “The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment,” J. Phys. Chem. B  107, 668–677 (2003).
  8. Z. S. Pillai and P. V. Kamat, “What factors control the size and shape of silver nanoparticles in the citrate ion reduction method,” J. Phys. Chem. B  108, 945–951 (2004).
  9. C. Voisin, D. Chistofilos, N. Del Fatti, F. Valée, B. Prével, E. Cottancin, J. Lermé, M. Pellarin, and M. Broyer, “Size-dependent electron–electron interactions in metal nanoparticles,” Phys. Rev. Lett.  85, 2200–2203 (2000). [CrossRef]
  10. N. Del Fatti, F. Vallée, C. Flytzanis, Y. Hamanaka, and A. Nakamura, “Electron dynamics and surface plasmon resonance nonlinearities in metal nanoparticles,” Chem. Phys.  251, 215–226 (2000).
  11. Y. Hamanaka, A. Nakamura, N. Hayashi, and S. Omi, “Dispersion curves of complex third-order optical susceptibilities around the surface plasmon resonance in Ag nanocrystal-glass composites,” J. Opt. Soc. Am. B  20, 1227–1232 (2003).
  12. V. P. Drachev, E. N. Khaliullin, W. Kim, F. Alzoubi, S. G. Rautian, V. P. Safonov, R. L. Armstrong, and V. M. Shalaev, “Quantum size effect in two-photon excited luminescence from silver nanoparticles,” Phys. Rev. B  69, 035318 (2004). [CrossRef]
  13. R. A. Gannev, M. Baba, A. I. Ryasnyansky, M. Suzuki, and K. Kuroda, “Characterization of optical and nonlinear optical properties of silver nanoparticles prepared by laser ablation in various liquids,” Opt. Commun.  240, 437–448 (2004).
  14. I. Antonov, F. Bass, Yu. Kaganovskii, M. Rosenbluh, and A. A. Lipovskii, “Fabrication of microlenses in Ag-doped glasses by a focused continuous wave laser beam,” J. Appl. Phys.  93, 2343–2348 (2003).
  15. J. Qiu, X. Jiang, C. Zhu, H. Inouye, J. Si, and K. Hirao, “Optical properties of structurally modified glasses doped with gold ions,” Opt. Lett.  29, 370–372 (2004).
  16. J. W. Sipe and R. W. Boyd, “Nonlinear susceptibility of composite optical materials in the Maxwell Garnett model,” Phys. Rev. A  46, 1614–1629 (1992). [CrossRef]
  17. M. Brust, M. Walker, D. Bethell, D. J. Schiffrin, and R. Whyman, “Synthesis of thiol-derivatized gold nanoparticles in a 2-phase liquid-liquid system,” J. Chem. Soc. Chem. Commun.  7, 801–802 (1994).
  18. M. Brust, J. Fink, D. Bethell, D. J. Schiffrin, and C. Kiely, “Synthesis and reactions of functionalised gold nanoparticles,” J. Chem. Soc. Chem. Commun.  16, 1655–1656 (1995).
  19. M. M. Oliveira, D. Ugarte, D. Zanchet, and A. J. G. Zarbin, “Influence of synthetic parameters on the size, structure and stability of dodecanethiol-stabilized silver nanoparticles,” J. Colloid Interface Sci., submitted for publication.
  20. U. Kreibig and C. V. Fragstein, “The limitation of electron mean free path in small silver particles,” Z. Phys.  224, 307–323 (1969).
  21. M. Sheik-Bahae, A. A. Said, T. H. Wei, D. J. Hagan, and E. W. Van Stryland, “Sensitive measurements of optical nonlinearities using a single beam,” IEEE J. Quantum Electron.  QE-26, 760–769 (1990).
  22. H. Ma, A. S. L. Gomes, and C. B. de Araújo, “Measurements of nondegenerate optical nonlinearity using a two-color single beam method,” Appl. Phys. Lett.  59, 2666–2668 (1991).
  23. X. Liu, S. Guo, H. Wang, N. Ming, and L. Hou, “Investigation of the influence of finite aperture size on the Z-scan transmittance curve,” J. Nonlinear Opt. Phys. Mater.  10, 431–439 (2001).
  24. D. D. Smith, G. Fisher, R. W. Boyd, and D. A. Gregory, “Cancellation of photoinduced absorption in metal nanoparticle composites through a counterintuitive consequence of local field effects,” J. Opt. Soc. Am. B  14, 1625–1631 (1997).
  25. E. L. Falcão-Filho, C. A. C. Bosco, G. S. Maciel, L. H. Acioli, C. B. de Araújo, A. A. Lipovskii, and D. K. Tagantsev, “Third-order optical nonlinearity of a transparent glass ceramic containing sodium niobate nanocrystals,” Phys. Rev. B  69, 134204 (2004). [CrossRef]

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