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Journal of the Optical Society of America B

Journal of the Optical Society of America B


  • Editor: G. I. Stegeman
  • Vol. 22, Iss. 12 — Dec. 1, 2005
  • pp: 2601–2609

Effect of chloride ions' introduction on structural, thermal stability, and spectroscopic properties in Yb3+Er3+-codoped germanate-bismuth-lead glasses

Hongtao Sun, Lili Hu, Lei Wen, Zhongchao Duan, Junjie Zhang, and Zhonghong Jiang  »View Author Affiliations

JOSA B, Vol. 22, Issue 12, pp. 2601-2609 (2005)

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Yb3+Er3+-codoped chloride-modified germanate-bismuth-lead glasses have been synthesized by the conventional melting and quenching method. Structural and thermal stability properties have been obtained on the basis of the Raman spectra and differential thermal analysis, which indicate that the PbCl2 addition has an important influence on the phonon density of states, maximum phonon energy, and thermal stability of host glasses. The Judd-Ofelt intensity parameters and quantum efficiencies were calculated on the basis of the Judd-Ofelt theory and lifetime measurements. For the 1.53 µm emission band, the full widths at the half-maximum increase and peak wavelengths are blueshifted with increasing PbCl2 content. Moreover, the effect of the PbCl2 addition on the phonon density of states, OH content, and upconversion luminescence has been discussed and evaluated. Our results reveal that, with increasing PbCl2 content, the decrease of phonon density and OH content contributes more to the enhanced upconversion emissions than that of maximum phonon energy.

© 2005 Optical Society of America

OCIS Codes
(160.2750) Materials : Glass and other amorphous materials
(160.4670) Materials : Optical materials
(260.2510) Physical optics : Fluorescence

ToC Category:

Hongtao Sun, Lili Hu, Lei Wen, Zhongchao Duan, Junjie Zhang, and Zhonghong Jiang, "Effect of chloride ions' introduction on structural, thermal stability, and spectroscopic properties in Yb3+Er3+-codoped germanate-bismuth-lead glasses," J. Opt. Soc. Am. B 22, 2601-2609 (2005)

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  1. H. T. Sun, S. Q. Xu, S. X. Dai, J. J. Zhang, L. L. Hu, and Z. H. Jiang, "Intense frequency upconversion emission of Er3+/Yb3+-codoped natrium-barium-strontiam-lead- bismuth glasses," Solid State Commun. 132, 193-196 (2004).
  2. H. T. Sun, S. X. Dai, S. Q. Xu, L. Hu, and Z. H. Jiang, "Frequency upconversion emission of Er3+-doped strontium-lead-bismuth glasses," Chin. Phys. Lett. 21, 2292-2294 (2004).
  3. S. Q. Xu, J. J. Zhang, and G. N. Wang, "Blue upconversion luminescence in Tm3+/Yb3+-codoped lead chloride tellurite glass," Chin. Phys. Lett. 2, 106-109 (2004).
  4. F. Auzel, K. E. Lipinska-Kalita, and P. Santa Cruz, "A new Er3+-doped vitreous fluoride amplification medium with crystal-like cross-sections and reduced inhomogeneous line width," Opt. Mater. 5, 75-78 (1996).
  5. H. T. Sun, D. B. Zhang, S. Q. Xu, S. X. Dai, L. L. Hu, and Z. H. Jiang, "Physical properties of novel lead-bismuthate glasses with large transmitting windows," Chin. Phys. Lett. 21, 1759-1761 (2004).
  6. Y. D. Huang, M. Mortier, and F. Auzel, "Stark levels analysis for Er3+-doped oxide glasses: germanate and silicate," Opt. Mater. 15, 243-260 (2001).
  7. H. Yamada and K. Kojima, "Upconversion fluorescence in Er3+-doped Na2O-GeO2 glasses," J. Non-Cryst. Solids 259, 57-62 (1999).
  8. P. Laporta, S. de Silvestri, V. Magni, and O. Svelto, "Diode-pumped cw bulk Er:Yb glass laser," Opt. Lett. 16, 1952-1954 (1991).
  9. J. A. Hutchinson and T. H. Allik, "Diode array-pumped Er, Yb: phosphate glass laser," Appl. Phys. Lett. 60, 1424-1426 (1992).
  10. L. Dong, W. H. Loh, and J. E. Caplen, "Efficient single-frequency fiber lasers with novel photosensitive ErYb optical fibers," Opt. Lett. 20, 337-339 (1995).
  11. Z. M. Yang, S. Q. Xu, L. Hu, and Z. H. Jiang, "Thermal analysis and optical properties of Yb3+/Er3+-codoped oxyfluoride germanate glasses," J. Opt. Soc. Am. B 21, 951-957 (2004).
  12. H. T. Sun, L. Y. Zhang, S. L. Zhao, J. J. Zhang, C. L. Yu, D. B. He, Z. C. Duan, L. L. Hu, and Z. H. Jiang, "Structural and upconversion fluorescence properties of Er3+/Yb3+-codoped oxychloride lead-germanium-bismuth glass," Solid State Commun. 133, 357-361 (2004).
  13. S. Q. Xu, Z. M. Yang, and G. N. Wang, "Effects of chloride introduction on upconversion luminescence in Tm3+ doped tellurite glasses," Spectrochim. Acta, Part A 60, 3025-3028 (2004).
  14. B. Chen, X. Kong, S. Ye, and W. Qin, "Upconversion analysis in Tm3+-doped PWG glass," Chin. J. Lumin. 20, 1-4 (1999).
  15. Z. Pan, D. O. Henderson, and S. H. Morgan, "A Raman investigation of lead haloborate glasses," J. Chem. Phys. 101, 1767-1774 (1994).
  16. Z. Pan, D. O. Henderson, and S. H. Morgan, "Vibrational spectra of bismuth silicate glasses and hydrogen-induced reduction effects," J. Non-Cryst. Solids 171, 134-140 (1994).
  17. H. Verweij and J. Buster, "The structure of lithium, sodium and potassium germanate glasses, studied by Raman scattering," J. Non-Cryst. Solids 34, 81-99 (1979).
  18. K. E. Lipinska-Kalita, "FT infrared and laser Raman spectroscopy of amorphous and crystalline germanates," J. Non-Cryst. Solids 119, 41-48 (1990).
  19. T. Sekiya, N. Mochida, and A. Ohtsuka, "Raman spectra of binary tellurite glasses containing tri- or tetra-valent cations," J. Non-Cryst. Solids 191, 115-123 (1995).
  20. H. Burger, K. Kneipp, and H. Hobert, "Glass formation, properties and structure of glasses in the TeO2-ZnO system," J. Non-Cryst. Solids 151, 134-142 (1992).
  21. A. A. Kharlamov, R. M. Almeida, and J. Heo, "Vibrational spectra and structure of heavy metal oxide glasses," J. Non-Cryst. Solids 202, 233-240 (1996).
  22. L. G. Hwa, Y. R. Chang, and W. C. Chao, "Infrared spectra of lanthanum gallogermanate glasses," Mater. Chem. Phys. 85, 158-162 (2004).
  23. A. E. Miller, K. Nassau, and K. B. Lyons, "The intensity of Raman scattering in glasses containing heavy metal oxides," J. Non-Cryst. Solids 99, 289-307 (1988).
  24. L. Baia, T. Iliescu, S. Simon, and W. Kiefer, "Raman and IR spectroscopic studies of manganese doped GeO2-Bi2O3 glasses," J. Mol. Struct. 599, 9-13 (2001).
  25. L. Baia, R. Stefan, and J. Popp, "Vibrational spectroscopy of highly iron doped B2O3-Bi2O3 glass systems," J. Non-Cryst. Solids 324, 109-117 (2003).
  26. M. J. Weber, "Radiative and multiphonon relaxation of rare-earth ions in Y2O3," Phys. Rev. 171, 283-291 (1968). [CrossRef]
  27. M. J. Weber, "Spontaneous emission probabilities and quantum efficiencies for excited states of Pr3+ in LaF3," J. Chem. Phys. 48, 4774-4780 (1968).
  28. R. R. Jacobs and M. J. Weber, "Dependence of the F3/24-I11/24 induced-emission cross section for Nd3+ on glass composition," IEEE J. Quantum Electron. QE-12, 102-111 (1976).
  29. J. Heo, Y. B. Shin, and J. N. Jang, "Spectroscopic analysis of Tm3+ in PbO-Bi2O3-Ga2O3 glass," Appl. Opt. 34, 4284-4289 (1995).
  30. S. Tanabe, T. Ohyagi, N. Soga, and T. Hanada, "Compositional dependence of Judd-Ofelt parameters of Er3+ ions in alkali-metal borate glasses," Phys. Rev. B 46, 3305-3310 (1992). [CrossRef]
  31. H. T. Sun, S. X. Dai, and D. B. Zhang, "Optical transitions and frequency upconversion emission of Er3+ ions in novel lead-bismuthate glass," Physica B 353, 248-254 (2004).
  32. R. Reisfeld and Y. Eckstein, "Radiative and non-radiative transition probabilities and quantum yields for excited states of Er3+ in germanate and tellurite glasses," J. Non-Cryst. Solids 15, 125-140 (1974).
  33. M. D. Shinn, W. A. Sibley, and M. G. Drexhage, "Optical transition of Er3+ ions in fluorozirconate glass," Phys. Rev. B 27, 6635-6648 (1983). [CrossRef]
  34. J. A. Capobianco, G. Prevost, and P. P. Proulx, "Upconversion properties of Er3+ doped lead silicate glasses," Opt. Mater. 6, 175-184 (1996).
  35. R. Reisfeld, G. Katz, and N. Spector, "The comparison of calculated transition probabilities with luminescence characteristics of erbium(III) in fluoride glasses and in the mixed yttrium-zirconium oxide crystal," J. Solid State Chem. 41, 253-261 (1982).
  36. M. Wachtler, A. Speghini, K. Gatterer, and H. P. Fritzer, "Optical properties of rare-earth ions in lead germanate glasses," J. Am. Ceram. Soc. 81, 2045-2052 (1999).
  37. A. Jha, S. Shen, and M. Naftaly, "Structural origin of spectral broadening of 1.5-µm emission in Er3+-doped tellurite glass," Phys. Rev. B 62, 6215-6227 (2000). [CrossRef]
  38. M. Mortier, Y. D. Huang, and F. Auzel, "Crystal field analysis of Er3+-doped glasses: germanate silicate and ZBLAN," J. Alloys Compd. 300-301, 407-413 (2000).
  39. Y. G. Choi and J. Heo, "1.3 µm emission and multiphonon relaxation phenomena in PbO-Bi2O3-Ga2O3 glasses doped with rare-earths," J. Non-Cryst. Solids 217, 199-207 (1997).
  40. M. P. Hehlen, N. J. Cockroft, and T. R. Gosnell, "Spectroscopic properties of Er3+ and Yb3+-doped soda-lime silicate and aluminosilicate glasses," Phys. Rev. B 56, 9302-9315 (1997). [CrossRef]
  41. J. M. F. van Dijk and M. F. H. Schuurmans, "On the nonradiative and radiative decay rates and a modified exponential energy gap law for 4f-4f transitions in rare-earth ions," J. Chem. Phys. 78, 5317-5323 (1983).
  42. T. Miyakawa and D. L. Dexter, "Phonon sidebands, multiphonon relaxation of excited states, and phonon-assisted energy transfer between ions in solids," Phys. Rev. B 1, 2961-2969 (1970). [CrossRef]
  43. C. B. Layne, W. H. Lowdermilk, and M. J. Weber, "Multiphonon relaxation of rare-earth ions in oxide glasses," Phys. Rev. B 16, 10-20 (1977). [CrossRef]
  44. L. A. Riseberg and H. W. Moos, "Multiphonon orbit-lattice relaxation of excited states of rare-earth ions in crystals," Phys. Rev. 174, 429-438 (1968). [CrossRef]
  45. Z. Pan, S. H. Morgan, and K. Dyer, "Host-dependent optical transitions of Er3+ ions in lead-germanate and lead-tellurium-germanate glasses," J. Appl. Phys. 79, 8906-8913 (1996).
  46. W. S. Tsang, W. M. Yu, and C. L. Mak, "Evidence of the influence of phonon density on Tm3+ upconversion luminescence in tellurite and germanate glasses," J. Appl. Phys. 91, 1871-1874 (2002).
  47. K. Kobayashi, "Development of infrared transmitting glasses," J. Non-Cryst. Solids 316, 403-406 (2003).
  48. M. V. D. Vermelho, A. S. Gouveia-Neto, and H. T. Amorim, "Temperature investigation of infrared-to-visible frequency upconversion in erbium-doped tellurite glasses excited at 1540 nm," J. Lumin. 102-103, 755-761 (2003).

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