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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Editor: G. I. Stegeman
  • Vol. 22, Iss. 12 — Dec. 1, 2005
  • pp: 2664–2685

Femtosecond-to-nanosecond nonlinear spectroscopy of polymethine molecules

Richard S. Lepkowicz, Claudiu M. Cirloganu, Jie Fu, Olga V. Przhonska, David J. Hagan, Eric W. Van Stryland, Mikhail V. Bondar, Yuriy L. Slominsky, and Alexei D. Kachkovski  »View Author Affiliations


JOSA B, Vol. 22, Issue 12, pp. 2664-2685 (2005)
http://dx.doi.org/10.1364/JOSAB.22.002664


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Abstract

The linear and nonlinear optical properties of a series of polymethine molecules are investigated to study the effects of molecular structure and the host environment on overall nonlinear absorption performance. The linear characterization includes measuring the solvatochromic shifts between absorption and fluorescence peaks and studying the excited-state orientational diffusion kinetics. The nonlinear characterization involves measuring the excited-state absorption spectra with a femtosecond white-light-continuum pump–probe technique and performing Z scans and nonlinear transmission measurements from the picosecond to the nanosecond time regimes. The results of these experiments allow us to develop an energy-level structure for the polymethines, which accurately predicts nonlinear absorption properties from the picosecond to the nanosecond time regimes. From this model we are able to identify the key molecular parameters for improved nonlinear absorption.

© 2005 Optical Society of America

OCIS Codes
(140.3360) Lasers and laser optics : Laser safety and eye protection
(190.4180) Nonlinear optics : Multiphoton processes
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials

ToC Category:
Nonlinear Optics

Virtual Issues
Vol. 1, Iss. 1 Virtual Journal for Biomedical Optics

Citation
Richard S. Lepkowicz, Claudiu M. Cirloganu, Jie Fu, Olga V. Przhonska, David J. Hagan, Eric W. Van Stryland, Mikhail V. Bondar, Yuriy L. Slominsky, and Alexei D. Kachkovski, "Femtosecond-to-nanosecond nonlinear spectroscopy of polymethine molecules," J. Opt. Soc. Am. B 22, 2664-2685 (2005)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-22-12-2664


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References

  1. J. W. Perry, "Organic and metal-containing reverse saturable absorbers for optical limiters," in Nonlinear Optics of Organic Molecules and Polymers, H.S.Nalwa and S.Miyata, eds. (CRC Press, 1997), pp. 813-840.
  2. E. W. Van Stryland, D. J. Hagan, T. Xia, and A. A. Said, "Application of nonlinear optics to passive optical limiting," in Nonlinear Optics of Organic Molecules and Polymers, H.S.Nalwa and S.Miyata, eds. (CRC Press, 1997), pp. 841-860.
  3. L. W. Tutt and T. F. Boggess, "A review of optical limiting mechanisms and devices using organics, fullerenes, semiconductors and other materials," Prog. Quantum Electron. 17, 299-338 (1993). [CrossRef]
  4. O. V. Przhonska, J. H. Lim, D. J. Hagan, E. W. Van Stryland, M. V. Bondar, and Y. L. Slominsky, "Nonlinear light absorption of polymethine dyes in liquid and solid media," J. Opt. Soc. Am. B 15, 802-809 (1998). [CrossRef]
  5. J. H. Lim, O. V. Przhonska, S. Khodja, S. Yang, T. S. Ross, D. J. Hagan, E. W. Van Stryland, M. V. Bondar, and Yu. L. Slominsky, "Polymethine and squarylium molecules with large excited-state absorption," Chem. Phys. 245, 79-97 (1999). [CrossRef]
  6. D. A. Oulianov, A. S. Dvornikov, and P. M. Rentzepis, "Optical limiting and picosecond relaxation of carbocyanines upper electronic states," Opt. Commun. 205, 427-436 (2002). [CrossRef]
  7. R. A. Negres, O. V. Przhonska, D. J. Hagan, E. W. Van Stryland, M. V. Bondar, Yu. L. Slominsky, and A. D. Kachkovski, "The nature of excited-state absorption in polymethine and squarylium molecules," IEEE J. Sel. Top. Quantum Electron. 7, 849-863 (2001). [CrossRef]
  8. R. S. Lepkowicz, O. V. Przhonska, C. M. Cirloganu, D. J. Hagan, E. W. Van Stryland, M. V. Bondar, Yu. L. Slominsky, A. D. Kachkovski, and E. I. Mayboroda, "Absorption anisotropy studies of polymethine dyes," Chem. Phys. 306, 171-183 (2004). [CrossRef]
  9. R. S. Lepkowicz, O. V. Przhonska, J. M. Hales, J. Fu, D. J. Hagan, E. W. Van Stryland, M. V. Bondar, Yu. L. Slominsky, and A. D. Kachkovski, "Nature of the electron transitions in thiacarbocyanines with a long polymethine chain," Chem. Phys. 305, 259-270 (2004). [CrossRef]
  10. O. V. Przhonska, D. J. Hagan, E. Novikov, R. Lepkowicz, E. W. Van Stryland, M. V. Bondar, Yu. L. Slominsky, and A. D. Kachkovski, "Picosecond absorption anisotropy of polymethine and squarylium dyes in liquid and polymeric media," Chem. Phys. 273, 235-248 (2001). [CrossRef]
  11. R. S. Lepkowicz, O. V. Przhonska, J. M. Hales, D. J. Hagan, E. W. Van Stryland, M. V. Bondar, Yu. L. Slominsky, and A. D. Kachkovski, "Excited-state absorption dynamics in polymethine dyes detected by polarization-resolved pump-probe measurements," Chem. Phys. 286, 277-291 (2003). [CrossRef]
  12. G. R. Fleming, Chemical Applications of Ultrafast Spectroscopy (Oxford U. Press, 1986).
  13. F. Perrin, "Mouvement brownien d'un ellipsoide (I). Dispersion dielectrique pour des molecules ellipsoidales," J. Phys. Radium 5, 497-511 (1934). [CrossRef]
  14. M. Maroncelli, "Continuum estimates of rotational dielectric friction and polar solvation," J. Chem. Phys. 106, 1545-1555 (1997). [CrossRef]
  15. G. B. Dutt, S. Doraiswamy, N. Periasamy, and B. Venkataraman, "Rotational reorientation dynamics of polar dye molecular probes by picosecond laser spectroscopic technique," J. Chem. Phys. 93, 8498-8513 (1990). [CrossRef]
  16. M. Sheik-Bahae, A. A. Said, T. H. Wei, D. J. Hagan, and E. W. Van Stryland, "Sensitive measurement of optical nonlinearities using a single beam," IEEE J. Quantum Electron. 26, 760-769 (1990). [CrossRef]
  17. M. Hamer, The Cyanine Dyes and Related Compounds (Interscience, 1964).
  18. A. I. Tolmachev, Yu. L. Slominsky, and A. A. Ischenko, "New cyanine dyes absorbing in the NIR region," in Near-Infrared Dyes for High Technology Applications, S.Daehne, U.Resh-Genger, and O.S.Wolfbeis, eds., Vol. 52 of NATO Advanced Study Institute Series (Kluger Academic, 1998), pp. 385-415. [CrossRef]
  19. J. R. Lakowicz, Principles of Fluorescence Spectroscopy, 2nd ed. (Kluwer Academic/Plenum, 1999). [CrossRef]
  20. R. L. Fork, C. V. Shank, C. Hirlimann, R. Yen, and W. J. Tomlinson, "Femtosecond white-light continuum pulses," Opt. Lett. 8, 1-4 (1983). [CrossRef] [PubMed]
  21. S. N. R. Swatton, K. R. Welford, S. J. Till, and J. R. Sambles, "Nonlinear absorption of a carbocyanine dye 1,1',3,3,3',3'-hexamethylindotricarbocyanine iodide using a z-scan technique," Appl. Phys. Lett. 66, 1868-1870 (1995). [CrossRef]
  22. R. S. Lepkowicz, A. Kobyakov, D. J. Hagan, and E. W. Van Stryland, "Picosecond optical limiting in reverse saturable absorbers: a theoretical and experimental study," J. Opt. Soc. Am. B 19, 94-101 (2002). [CrossRef]
  23. S. Hughes and B. Wherrett, "Multilevel rate-equation analysis to explain the recent observations of limitations to optical limiting dyes," Phys. Rev. A 54, 3546-3552 (1996). [CrossRef] [PubMed]
  24. X. Deng, X. Zhang, Y. Wang, Y. Song, S. Liu, and C. Li, "Intensity threshold in the conversion from reverse saturable absorption to saturable absorption and its application in optical limiting," Opt. Commun. 168, 207-212 (1999). [CrossRef]
  25. A. Kobyakov, D. J. Hagan, and E. W. Van Stryland, "Analytical approach to dynamics of reverse saturable absorbers," J. Opt. Soc. Am. B 17, 1884-1893 (2000). [CrossRef]
  26. T. Xia, D. J. Hagan, A. Dogariu, A. Said, and E. W. Van Stryland, "Optimization of optical limiting devices based on excited-state absorption," Appl. Opt. 36, 4110-4122 (1997). [CrossRef] [PubMed]
  27. A. Sanchez-Galvez, P. Hunt, M. A. Robb, M. Olivucci, T. Vreven, and H. B. Schlegel, "Ultrafast radiationless deactivation of organic dyes: evidence for a two-state two-mode pathway in polymethine cyanines," J. Am. Chem. Soc. 122, 2911-2924 (2000). [CrossRef]
  28. M. Levitus, R. M. Negri, and P. F. Aramdenia, "Rotational relaxation of carbocyanines. Comparative study with the isomerization dynamics," J. Phys. Chem. 99, 14231-14239 (1995). [CrossRef]
  29. F. Momicchioli, I. Baraldi, and G. Berthier, "Theoretical study of trans-cis photoisomerism in polymethine cyanines," Chem. Phys. 123, 103-112 (1988). [CrossRef]
  30. P. Brochard, V. Grolier-Mazza, and R. Cabanel, "Thermal nonlinear refraction in dye solutions: a study of the transient regime," J. Opt. Soc. Am. B 14, 405-411 (1997). [CrossRef]
  31. J. Robertson, P. Milsom, J. Duignan, and G. Bourhill, "Spatial redistribution of energy in a nanosecond laser pulse by an organic optical limiter," Opt. Lett. 25, 1258-1260 (2000). [CrossRef]
  32. D. I. Kovsh, D. J. Hagan, and E. W. Van Stryland, "Numerical modeling of thermal refraction in liquids in the transient regime," Opt. Express 4, 315-327 (1999). [CrossRef] [PubMed]
  33. B. Valuer, Molecular Fluorescence: Principles and Applications (Wiley-VCH, 2002).
  34. C. Hu and R. Zwanzig, "Rotational friction coefficients for spheroids with the slipping boundary condition," J. Chem. Phys. 60, 4354-4357 (1974). [CrossRef]

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