Characterization of the molecular iodine electronic wave functions and potential energy curves through hyperfine interactions in the B0+_u(3Pi_u) state
JOSA B, Vol. 22, Issue 5, pp. 951-961 (2005)
http://dx.doi.org/10.1364/JOSAB.22.000951
Acrobat PDF (283 KB)
Abstract
We present a high-resolution analysis of the six electronic states that share the same dissociation limit with the second excited electronic state B in molecular iodine. These six states are coupled to the B state via hyperfine interactions. The four hyperfine parameters, C_B, delta_B, d_B, and eqQ_B, are calculated with the available potential energy curves and wave functions constructed from the separated-atom basis set. We obtain a maximum separation of the respective contributions from all six electronic states and compare each individual contribution with high-precision spectroscopic data, providing an independent verification of the relevant electronic structure.
© 2005 Optical Society of America
OCIS Codes
(020.2930) Atomic and molecular physics : Hyperfine structure
(300.6190) Spectroscopy : Spectrometers
(300.6390) Spectroscopy : Spectroscopy, molecular
(300.6460) Spectroscopy : Spectroscopy, saturation
Citation
Lisheng Chen, Wibe A. de Jong, and Jun Ye, "Characterization of the molecular iodine electronic wave functions and potential energy curves through hyperfine interactions in the B0+_u(3Pi_u) state," J. Opt. Soc. Am. B 22, 951-961 (2005)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-22-5-951
You do not have subscription access to this journal. Citation lists with outbound citation links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Log in to access OSA Member Subscription
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Log in to access OSA Member Subscription
You do not have subscription access to this journal. Article level metrics are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Log in to access OSA Member Subscription
Related Journal Articles 
- Sub-Doppler spectroscopy of the C—O stretching fundamental band of methanol by use of microwave sidebands of CO2 laser lines (JOSAB)
- Rotation dependence of electric quadrupole hyperfine interaction in the ground state of molecular iodine by high-resolution laser spectroscopy (JOSAB)
- High-stability diode-laser-based frequency reference at 1083 nm with iodine lines at 541.5 nm (JOSAB)
- Rotation dependence of the excited-state electric quadrupole hyperfine interaction by high-resolution laser spectroscopy of 127I2 (JOSAB)
- Hyperfine interactions and perturbation effects in the B0u+(3Πu) state of 127I2 (JOSAB)
Related Conference Papers
- Saturated Absorption Signals from Acetylene Gas Inside Photonic Bandgap Fiber
- Difference-frequency radiation around 4.3 μm for high sensitivity and sub-Doppler spectroscopy of CO2
- Linking Molecular- and Atomic-Frequency Standards with Cavity Ring-Down Spectroscopy
- Saturated-Absorption Cavity Ring-Down Spectroscopy
- Photoassociation spectroscopy of the A1Σ - b3Π complex in ultracold polar NaCs molecules
« Previous Article | Next Article »
OSA is a member of 