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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Editor: Henry M. Van Driel
  • Vol. 24, Iss. 9 — Sep. 1, 2007
  • pp: 2136–2140

Influence of stabilizing agents on the nonlinear susceptibility of silver nanoparticles

Luis A. Gómez, Cid B. de Araújo, A. M. Brito Silva, and André Galembeck  »View Author Affiliations


JOSA B, Vol. 24, Issue 9, pp. 2136-2140 (2007)
http://dx.doi.org/10.1364/JOSAB.24.002136


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Abstract

The nonlinear (NL) optical properties of silver nanoparticles (NPs) colloids stabilized using sodium citrate, poly(N-vinylpyrrolidone), and polyvinyl alcohol in aqueous solutions were investigated. The characterization of the colloids was made through linear absorption, transmission electron microscopy, and the Z-scan technique at 532 nm . Changes in the NL optical response of the samples were observed due to different molecules adsorbed on the NPs’ surface. The third-order nonlinearity of the silver NPs with different stabilizers is discussed, and the results are associated with the scattering parameter A, which is related to the shift and broadening of the NPs’ surface plasmon resonance. The NL susceptibility of the NPs was determined for each colloid, and from the results the influence of the stabilizing agents on the NPs’ susceptibility is clear.

© 2007 Optical Society of America

OCIS Codes
(160.4760) Materials : Optical properties
(190.4400) Nonlinear optics : Nonlinear optics, materials
(240.6680) Optics at surfaces : Surface plasmons
(300.6420) Spectroscopy : Spectroscopy, nonlinear

ToC Category:
Nonlinear Optics

History
Original Manuscript: November 16, 2006
Revised Manuscript: March 26, 2007
Manuscript Accepted: May 17, 2007
Published: August 6, 2007

Virtual Issues
Vol. 2, Iss. 10 Virtual Journal for Biomedical Optics

Citation
Luis A. Gómez, Cid B. de Araújo, A. M. Brito Silva, and André Galembeck, "Influence of stabilizing agents on the nonlinear susceptibility of silver nanoparticles," J. Opt. Soc. Am. B 24, 2136-2140 (2007)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-24-9-2136


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References

  1. See, for example, S. Link and M. A. El-Sayed, "Optical properties and ultrafast dynamics of metallic nanocrystals," Annu. Rev. Phys. Chem. 54, 331-366 (2003). [CrossRef] [PubMed]
  2. S. Link and M. A. El-Sayed, "Spectral properties and relaxation dynamics of surface plasmon electronics oscillations in gold and silver nanodots and nanorods," J. Phys. Chem. B 103, 8410-8426 (1999), and references therein. [CrossRef]
  3. U. Kreibig, "Electronic properties of small silver particles: the optical constants and their temperature dependence," J. Phys. F: Met. Phys. 4, 999-1014 (1974). [CrossRef]
  4. H. Hövel, S. Fritz, A. Hilger, and U. Kreibig, "Width of cluster plasmon resonances: bulk dielectric functions and chemical interface damping," Phys. Rev. B 48, 18178-18188 (1993). [CrossRef]
  5. A. Pinchuck, U. Kreibig, and A. Hilger, "Optical properties of metallic nanoparticles: influence of interface effects and interband transitions," Surf. Sci. 557, 269-280 (2004). [CrossRef]
  6. U. Kreibig, G. Bour, A. Hilger, and M. Gartz, "Optical properties of cluster-matter: influences of interfaces," Phys. Status Solidi A 175, 351-366 (1999). [CrossRef]
  7. K. Uchida, S. Kaneko, S. Omi, C. Hata, H. Tanji, Y. Asahara, A. J. Ikushima, T. Tokisaki, and A. Nakamura, "Optical nonlinearities of high concentration of small metal particles dispersed in glass: copper and silver particles," J. Opt. Soc. Am. B 11, 1236-1243 (1994). [CrossRef]
  8. R. A. Ganeev, A. I. Ryasnyansky, S. R. Kamalov, M. K. Kodirov, and T. Usmanov, "Nonlinear susceptibilities, absorption coefficients and refractive indices of colloidal metals," J. Phys. D 34, 1602-1611 (2001). [CrossRef]
  9. F. Hache, D. Ricard, C. Flytzanis, and U. Kreibig, "The optical Kerr effect in small metal particles and metal colloids: the case of gold," Appl. Phys. A 47, 347-357 (1998). [CrossRef]
  10. J. W. Sipe and R. W. Boyd, "Nonlinear susceptibility of composite optical materials in the Maxwell Garnett model," Phys. Rev. A 46, 1614-1629 (1992). [CrossRef] [PubMed]
  11. P. C. Lee and D. Meisel, "Adsorption and surface-enhanced Raman of dyes on silver and gold sols," J. Phys. Chem. 86, 3391-3395 (1982). [CrossRef]
  12. P. V. Kamat, M. Flumiani, and G. V. Hartland, "Picosecond dynamics of silver nanoclusters. Photoejection of electrons and fragmentation," J. Phys. Chem. B 102, 3123-3128 (1998). [CrossRef]
  13. W. C. Bell and M. L. Myrick, "Preparation and characterization of nanoscale silver colloids by two novel synthetic routes," J. Colloid Interface Sci. 242, 300-305 (2001). [CrossRef]
  14. M. H. G. Miranda, E. L. Falcão-Filho, J. J. Rodrigues, Jr., C. B. de Araújo, and L. H. Acioli, "Ultrafast light-induced dichroism in silver nanoparticles," Phys. Rev. B 70, 161401(R) (2004). [CrossRef]
  15. E. D. Palik, Handbook of Optical Constants of Solids (Academic, 1985).
  16. M. Sheik-Bahae, A. A. Said, T. Wei, D. J. Hagan, and E. W. Van Stryland, "Sensitive measurement of optical nonlinearities using a single beam," IEEE J. Quantum Electron. 26, 760-769 (1990). [CrossRef]
  17. H. Ma, A. S. Gomes, and C. B. de Araújo, "Measurement of nondegenerate optical nonlinearity using a two-color single beam method," Appl. Phys. Lett. 59, 2666-2668 (1991). [CrossRef]
  18. E. L. Falcão-Filho, C. B. de Araújo, A. Galembeck, M. M. Oliveira, and A. J. G. Zarbin, "Nonlinear susceptibility of colloids consisting of silver nanoparticles in carbon disulfide," J. Opt. Soc. Am. B 22, 2444-2449 (2005). [CrossRef]
  19. D. D. Smith, G. Fischer, R. W. Boyd, and D. A. Gregory, "Cancellation of photoinduced absorption in metal nanoparticle composites through a counterintuitive consequence of local field effects," J. Opt. Soc. Am. B 14, 1625-1631 (1997). [CrossRef]
  20. C. G. Blatchford, O. Sliman, and M. Kerker, "Potential dependence of surface-enhanced Raman scattering from citrate on colloidal silver," J. Phys. Chem. 87, 2503-2508 (1983). [CrossRef]
  21. G. Carotenuto, G. P. Pepe, and L. Nicolais, "Preparation and characterization of nanosized Ag/PVP composites for optical applications," Eur. Phys. J. B 16, 11-17 (2000). [CrossRef]
  22. M. K. Temgire and S. S. Joshi, "Optical and structural studies of silver nanoparticles," Radiat. Phys. Chem. 71, 1039-1044 (2004). [CrossRef]
  23. P. Mulvaney, "Surface plasmon spectroscopy of nanosized metal particles," Langmuir 12, 788-800 (1996). [CrossRef]
  24. C. R. Berry and D. C. Skillman, "Optical absorption of small silver spheres in water," J. Appl. Phys. 42, 2818-2822 (1971). [CrossRef]
  25. M. D. Malinsky, K. L. Kelly, G. C. Schatz, and R. P. Van Duyne, "Chain length dependence and sensing capabilities of the localized surface plasmon resonance of silver nanoparticles chemically modified with alkanethiol self-assembled monolayers," J. Am. Chem. Soc. 123, 1471-1482 (2001). [CrossRef]
  26. S. Kapoor, "Preparation, characterization, and surface modification of silver particles," Langmuir 14, 1021-1025 (1998). [CrossRef]
  27. H. H. Huang, X. P. Ni, G. L. Loy, C. H. Chew, K. L. Tan, F. C. Loh, J. F. Deng, and G. Q. Xu, "Photochemical formation of silver nanoparticles in poly(N-vinylpyrolidone)," Langmuir 12, 909-912 (1996). [CrossRef]
  28. V. A. Karavanskii, A. V. Simakin, V. I. Krasovskii, and P. V. Ivanchenko, "Nonlinear optical properties of colloidal silver nanoparticles produced by laser ablation in liquids," Quantum Electron. 34, 644-648 (2004). [CrossRef]

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