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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 3, Iss. 4 — Apr. 1, 1986
  • pp: 488–492

There were no pi pulses in iodine vapor: crafted pulses to compensate for Rabi-frequency inhomogeneities

W. S. Warren, J. L. Bates, M. A. McCoy, M. Navratil, and L. Mueller  »View Author Affiliations


JOSA B, Vol. 3, Issue 4, pp. 488-492 (1986)
http://dx.doi.org/10.1364/JOSAB.3.000488


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Abstract

In molecular iodine, and most other gas-phase molecules as well, generation of a π/2 or π pulse is theoretically impossible. This result can be understood by analogy with microwave spectroscopy, since the rotational contribution to the transition dipole moment is an explicit function of the projection of the total angular momentum F = J + I along the electric-field axis. The only solution is the generation of phase-modulated pulses that inherently compensate for Rabi-frequency inhomogeneity. We present theoretical and experimental evidence that crafted phase- and amplitude-modulated pulse shapes can excite a uniform, localized, and nearly complete inversion in nuclear magnetic resonance and laser spectroscopy.

© 1986 Optical Society of America

History
Original Manuscript: November 18, 1985
Manuscript Accepted: December 13, 1985
Published: April 1, 1986

Citation
W. S. Warren, L. Mueller, J. L. Bates, M. A. McCoy, and M. Navratil, "There were no pi pulses in iodine vapor: crafted pulses to compensate for Rabi-frequency inhomogeneities," J. Opt. Soc. Am. B 3, 488-492 (1986)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-3-4-488


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References

  1. For a general review of work before 1982 see M. Burns, W. K. Liu, A. H. Zewail, in Spectroscopy and Excitation Dynamics of Condensed Matter Systems, V. M. Agranovich, R. M. Hochstrasser, eds. (North-Holland, Amsterdam, 1983), p. 301.
  2. W. S. Warren, A. H. Zewail, J. Chem. Phys. 75, 5986 (1981); J. Chem. Phys. 78, 2279, 78, 2298 (1983). [CrossRef]
  3. E. Sleva, A. H. Zewail, Chem. Phys. Lett. 110, 582 (1984). [CrossRef]
  4. W. S. Warren, M. A. Banash, in Coherence and Quantum Optics V, L. Mandel, E. Wolf, eds. (Plenum, New York, 1984) p. 959.
  5. M. A. Banash, J. Gutow, W. S. Warren, J. Luminescence 31–32, 855 (1984). [CrossRef]
  6. M. A. Banash, W. S. Warren, Laser Chem. (to be published).
  7. A. Z. Genack, in Proceedings of the International Laser Science Conference (American Institute of Physics, New York, 1985).
  8. R. G. Brewer, S. S. Kano, in Laser Induced Processes in Molecules, K. L. Kompa, S. D. Smith, eds. (Springer-Verlag, New York, 1979), p. 54. [CrossRef]
  9. J. Vigue, M. Broyer, J. C. Lehmann, J. Phys. (Paris) 42, 949 (1981). [CrossRef]
  10. L. Brewer, J. Tellinghuisen, J. Chem. Phys. 56, 3929 (1972). [CrossRef]
  11. C. H. Townes, A. L. Schawlow, Microwave Spectroscopy (McGraw-Hill, New York, 1955); G. Herzberg, Spectra of Diatomic Molecules (Van Nostrand Reinhold, New York, 1950).
  12. W. S. Warren, A. H. Zewail, Laser Chem. 2, 37 (1983); E. Sleva, A. H. Zewail, J. Opt. Soc. Am. B 3, 483–487 (1986); Y. S. Bai, A. G. Yoth, T. W. Mossberg, Phys. Rev. Lett 55, 1277 (1985). [CrossRef] [PubMed]
  13. C. P. Slichter, Principles of Magnetic Resonance (Springer-Verlag, Berlin, 1980).
  14. R. Beach, S. R. Hartmann, Phys. Rev. Lett. 53, 663 (1984). [CrossRef]
  15. N. W. Carlson, W. R. Babbitt, Y. S. Bai, T. W. Mossberg, J. Opt. Soc. Am. B 2908 (1985); Y. S. Bai, T. W. Mossberg, Appl. Phys. Lett. 45, 1269 (1984). [CrossRef]
  16. D. Hoult, M. Silver, J. Magn. Reson. 59, 347 (1985); M. Silver, R. I. Joseph, Phys. Rev. A 312753 (1984). [CrossRef]
  17. M. H. Levitt, Progress in NMR Spectroscopy (Pergamon, New York, to be published); R. Freeman, S. P. Kempsall, M. H. Levitt, J. Mag. Reson. 38, 453 (1980).
  18. W. S. Warren, J. Chem. Phys. 81, 5437 (1984). [CrossRef]
  19. M. McCoy, W. S. Warren, J. Mag. Reson. 65, 178 (1985).

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