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Optical and electronic properties of undoped La2Be2O5 single crystals in the far ultraviolet energy range

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Abstract

The optical and electronic properties of undoped La2Be2O5 single crystals were determined using low-temperature (T=10K) far ultraviolet (4.9–33 eV) synchrotron radiation spectroscopy, optical absorption spectroscopy (T=80 and 320 K), and calculations for the dispersions of the optical functions. On the basis of the obtained data we determined the Urbach’s formula parameters and the cut-off energy Ec=5.49eV at 80 K for the low-energy tail of the host absorption, the bandgap Eg=6.78eV at 10 K, the energy threshold for the creation of unrelaxed excitons Eex=6.28eV, and other electronic properties.

© 2015 Optical Society of America

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