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Journal of the Optical Society of America B

Journal of the Optical Society of America B

| OPTICAL PHYSICS

  • Vol. 9, Iss. 5 — May. 1, 1992
  • pp: 816–818

Preparation and properties of sol-gel thin films with porphins

Hiroyuki Inoue, Takashi Iwamoto, Kazuyuki Horie, Akio Makishima, and Makoto Ikemoto  »View Author Affiliations


JOSA B, Vol. 9, Issue 5, pp. 816-818 (1992)
http://dx.doi.org/10.1364/JOSAB.9.000816


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Abstract

Amorphous silica films doped with porphine derivatives were prepared by the sol-gel method with a dip-coating technique. The films doped with tetrakis(1-methylpyridinium-4-yl)-porphine p-toluenesulfonate (TMPyP) or tetraphenylporphine tetrasulfonic acid (TPPS) were heat treated at various temperatures, and the changes in the optical spectra were observed as a function of temperature. It was found that the porphins in the films could be heat treated up to ˜.200°C. A photochemical hole was formed in the lowest transition of the Q band of TMPyP in the silica film at ˜20 K.

© 1992 Optical Society of America

Citation
Hiroyuki Inoue, Takashi Iwamoto, Kazuyuki Horie, Akio Makishima, and Makoto Ikemoto, "Preparation and properties of sol-gel thin films with porphins," J. Opt. Soc. Am. B 9, 816-818 (1992)
http://www.opticsinfobase.org/josab/abstract.cfm?URI=josab-9-5-816


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