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Journal of Optical Technology

Journal of Optical Technology


  • Vol. 77, Iss. 1 — Jan. 1, 2010
  • pp: 1–5

Nonlinear optical properties of fullerene-porphyrin complexes

I. B. Zakharova, O. E. Kvyatkovskiĭ, G. M. Ermolaeva, N. G. Spitsyna, and V. B. Shilov  »View Author Affiliations

Journal of Optical Technology, Vol. 77, Issue 1, pp. 1-5 (2010)

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The nonlinear optical properties, optical limitation, and second- and third-order nonlinearity in a new class of noncovalently bonded fullerene-porphyrin complexes are investigated. Quantum-chemical calculations of the optimal geometry, binding energy, electronic structure, and nonlinear optical properties of donor-acceptor fullerene-prophyrin complexes are performed. As a result of the formation of a complex, the second-order molecular polarizability is higher than in porphyrins by two to three orders of magnitude, depending on the orientation of the molecule, and the third-order molecular susceptibility two orders of magnitude higher. The nonlinear absorption in thin films and solutions of the complexes is measured. In picosecond regimes, absorption saturation at 560nm wavelength is observed for pulse energy density above 0.01J/cm2. A model is proposed for the increase of the optical nonlinearity in complexes as compared with the molecular components.

© 2010 Optical Society of America

I. B. Zakharova, O. E. Kvyatkovskiĭ, G. M. Ermolaeva, N. G. Spitsyna, and V. B. Shilov, "Nonlinear optical properties of fullerene-porphyrin complexes," J. Opt. Technol. 77, 1-5 (2010)

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  1. L. Geng and J. C. Wright , “Measurement of the resonant third-order nonlinear susceptibility of C60 by nondegenerate four-wave mixing,” Chem. Lett. 249, No. 1-2, 105 (1996). [CrossRef]
  2. N. Tang , J. J. Partanen , R. W. Hellwarth , and R. J. Knize , “Third-order optical nonlinearity of C60, C70, and CS2 in benzene at 1.06μm,” Phys. Rev. B 48, No. 11, 8404 (1993). [CrossRef]
  3. M. O. Senge , M. Fazekas , E. G. A. Notaras , W. J. Blau , M. Zawadzka , O. B. Locos , and E. M. Ni Mhuircheartaigh , “Nonlinear optical properties of porphyrins,” Adv. Mater. 19, No. 19, 2737 (2007). [CrossRef]
  4. E. Xenogiannopoulou , M. Medved , K. Iliopoulos , S. Courts , M. G. Papadopoulos , D. Bonifazi , C. Sooam-bar , A. Mateo-Alonso , and M. Prato , “Nonlinear optical properties of ferrocene- and porphyrin-[60] fullerene dyads,” Adv. Photochem. 7, No. 8, 1056 (2007).
  5. R. Signorini , R. Bozio , and M. Prato , Fullerenes: From Synthesis to Optoelectronic Properties, Kluwer, Dordrecht (2002).
  6. P. P. Kiran , D. R. Reddy , B. G. Maiya , A. K. Dharmadhikar , G. R. Kumar , and N. R. Desai , “Enhanced optical limiting and nonlinear absorption properties of azoarene-appended phosphorus (V) tetratolylporphyrins,” Appl. Opt. 41, No. 6, 7631 (2002). [CrossRef]
  7. H. Rath , J. Sankar , V. PrabhuRaja , T. K. Chandrashekar , A. Nag , and D. Goswami , “Coremodified expanded porphyrins with large third-order nonlinear optical response,” J. Am. Chem. Soc. 127, No. 33, 11608 (2005). [CrossRef]
  8. Z.-B. Liu , J.-G. Tian , J.-Yu. Zheng , Z.-Yu. Li , S.-Q. Chen , and Y. Zhu , “Active tuning of nonlinear absorption in a supramolecular zinc diphenylporphyrin-pyridine system,” Opt. Express 14, No. 7, 2770 (2006). [CrossRef]
  9. K. Sendhil , C. Vijayan , and M. P. Kothiyal , “Nonlinear optical properties of a porphyrin derivative incorporated in Nafion polymer,” Opt. Mater. 27, No. 10, 1606 (2005). [CrossRef]
  10. E. Collini , C. Ferrante , R. Bozzio , A. Lodib , and G. Ponterinib , “Large third-order nonlinear optical response of porphyrin J-aggregates oriented in self-assembled thin films,” J. Mater. Chem. 16, No. 16, 1573 (2006). [CrossRef]
  11. G. Brusatin and R. Signorini , “Linear and nonlinear optical properties of fullerenes in solid state materials,” J. Mater. Chem. 12, No. 7, 1964 (2002). [CrossRef]
  12. A. A. Granovsky , http://classic.chem.msu.su/gran/gamess/index.html.
  13. M. W. Schmidt , K. K. Baldridge , J. A. Boatz , S. T. Elbert , M. S. Gordon , J. J. Jensen , S. Koseki , N. Matsunaga , K. A. Nguyen , S. Su , T. X. Windus , M. Dupuis , and J. A. Montgomery , “General atomic and molecular electronic structure system,” J. Comput. Chem. 14, No. 11, 1347 (1993). [CrossRef]
  14. I. B. Zakharova , T. L. Makarova , I. T. Serenkov , and D. A. Virki , “Preparation and optical characterization of C60Brx thin films,” Mol. Mater. 13, 335 (2000).
  15. I. B. Zakharova , I. V. Makarenko , T. X. Makarova , A. V. Nashchekin , V. N. Petrov , B. S. Razbirin , A. N. Starukhin , and L. V. Belyakov , “Initial stage of condensation of C60 films on semiconducting substrates of different chemical nature,” Fullerenes, Nanotubes, Carbon Nanostruct. 12, No. 1-2, 537 (2004). [CrossRef]
  16. I. B. Zakharova , E. A. Donenko , Yu. F. Birylin , L. V. Sharonova , and T. X. Makarova , “Optical and vibrational properties of thin film fullerene-zinc(II) tetraphenylporphyrin complexes,” Fullerenes, Nanotubes, Carbon Nanostruct. 16, No. 5-6, 424 (2008). [CrossRef]

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