Abstract

By using continuum methods to describe dipole-dipole interactions, a quantitative interpretation is given of the regularities of the shift and broadening of the powerful IR absorption band of the antisymmetric valence vibration of the CS2 molecule that accompanies the vapor-liquid phase transition. It is confirmed that the predominant contribution to the formation of the experimentally observed spectrum of the absorption index kappa (nu) of liquid CS2 in the 1450-1550-cm -1 region comes from intermolecular forces of a resonance nature. It is established that the Brownian broadening mechanism is the main molecular mechanism that determines the contour of the nu3 band in the spectrum of the Einstein coefficient for absorption, B(nu). © 2003 Optical Society of America

Measurements of air-, N₂-, and O₂-broadened halfwidths and pressure-induced line shifts in the ν₃ band of ¹³CH₄

V. Malathy Devi, D. Chris Benner, Mary Ann H. Smith, and Curtis P. Rinsland
Appl. Opt. 30(3) 287-304 (1991)

Phase conjugation in liquid CS₂ by using a pulsed CO₂ laser

P. E. Dyer and J. S. Leggatt
Opt. Lett. 13(7) 583-585 (1988)

Mid-IR supercontinuum generation in an integrated liquid-core optical fiber filled with CS₂

D. Churin, T.N. Nguyen, K. Kieu, R. A. Norwood, and N. Peyghambarian
Opt. Mater. Express 3(9) 1358-1364 (2013)

Hyperpolarizability dispersion measured for CS₂ vapor

Rodrigo N. Fernandez and David P. Shelton
J. Opt. Soc. Am. B 37(6) 1769-1774 (2020)

Dipole-dipole interaction between molecules mediated by a chain of silver nanoparticles

J. Lindberg, K. Lindfors, T. Setälä, and M. Kaivola
J. Opt. Soc. Am. A 24(11) 3427-3431 (2007)