Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group

Composition and spectral manifestations of molecular complexes formed in solutions of hydrogen fluoride in methanol

Not Accessible

Your library or personal account may give you access

Abstract

The IR spectra of solutions of HF in methanol have been measured as the molar ratio of the components is varied from 1:12 to 7:1. The features of the absorption of HF-CH<sub>3</sub>OH binary mixtures of various concentrations are analyzed, and the spectral attributes of the molecular heterocomplexes present in them are explained. It is established by analyzing the concentration dependence of the optical density of the test solutions, normalized to the total number of moles per liter, that associates of molecules are formed in them with stoichiometric HF:CH<sub>3</sub>OH ratios equal to 2:1 and about 6:1. These results are compared with analogous data obtained from the concentration dependence of the excess density of solutions of HF in methanol.

© 2008 Optical Society of America

PDF Article
More Like This
Molecular dynamic investigation of ethanol-water mixture by terahertz-induced Kerr effect

Hang Zhao, Yong Tan, Rui Zhang, Yuejin Zhao, Cunlin Zhang, Xi-Cheng Zhang, and Liangliang Zhang
Opt. Express 29(22) 36379-36388 (2021)

Rotational Spectrum of Hydrogen Fluoride: Frequencies and Linewidths*

Arthur A. Mason and Alvin H. Nielsen
J. Opt. Soc. Am. 57(12) 1464-1470 (1967)

Investigation of a Raman scattering spectral model for seawater containing a composite salt solute

Dong Bao, Dengxin Hua, Hao Qi, and Jun Wang
Opt. Express 30(5) 6713-6725 (2022)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Select as filters


Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All Rights Reserved