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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 16, Iss. 15 — Jul. 21, 2008
  • pp: 11193–11202

Particle size-dependent giant nonlinear absorption in nanostructured Ni-Ti alloys

John Kiran Anthony, Hee Cheoul Kim, Hwang Woon Lee, S. Kumar Mahapatra, Hae Min Lee, Chang Koo Kim, Kihong Kim, Hanjo Lim, and Fabian Rotermu  »View Author Affiliations


Optics Express, Vol. 16, Issue 15, pp. 11193-11202 (2008)
http://dx.doi.org/10.1364/OE.16.011193


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Abstract

The nonlinear absorption in nanostructured Ni-Ti alloys, fabricated by electrochemical deposition, was investigated at 532 and 1064 nm. The type of nonlinear absorption (saturable or reverse saturable absorption) was observed to depend on the laser intensity as well as on the nanoparticle size. The nanostructured Ni-Ti alloys comprising particle mean diameters of 20 and 30 nm exhibited large three-photon absorption (3PA coefficient ~ 106 cm3/GW2) and large two-photon absorption (2PA coefficient ~ 105 cm/GW) at 532 nm, respectively. The observed change over from reverse saturable absorption to saturable absorption at high peak intensities has qualitatively been analyzed by the excited-state theory of conduction electrons.

© 2008 Optical Society of America

OCIS Codes
(160.4330) Materials : Nonlinear optical materials
(190.4180) Nonlinear optics : Multiphoton processes
(190.4720) Nonlinear optics : Optical nonlinearities of condensed matter
(160.4236) Materials : Nanomaterials

ToC Category:
Nonlinear Optics

History
Original Manuscript: June 5, 2008
Revised Manuscript: July 7, 2008
Manuscript Accepted: July 8, 2008
Published: July 10, 2008

Citation
John Kiran Anthony, Hee Cheoul Kim, Hwang Woon Lee, S. Kumar Mahapatra, Hae Min Lee, Chang Koo Kim, Kihong Kim, Hanjo Lim, and Fabian Rotermund, "Particle size-dependent giant nonlinear absorption in nanostructured Ni-Ti alloys," Opt. Express 16, 11193-11202 (2008)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-16-15-11193


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References

  1. R. W. Boyd, R. J. Gehry, G. L. Fischery, and J. E. Sipe, "Nonlinear optical properties of nanocomposite materials," Pure Appl. Opt. 5, 505�??512 (1996). [CrossRef]
  2. R. West, Y. Wang, and T. Goodson, "Nonlinear Absorption Properties in Novel Gold Nanostructured Topologies," J. Phys. Chem. B 107, 3419�??3426 (2003). [CrossRef]
  3. N. D. Fatti and F. Vallee, "Ultrafast optical nonlinear properties of metal nanoparticles," Appl. Phys. B 73, 383�??390 (2001). [CrossRef]
  4. N. Venkatram, R. Sathyavathi, and D. Narayana Rao, "Size dependent multiphoton absorption and refraction of CdSe nanoparticles," Opt. Express,  15, 12258�??12263 (2007). [CrossRef]
  5. J.-B. Han, D.-J. Chen, S. Ding, H.-J. Zhou, Y.-B. Han, G.-G. Xiong, and Q.-Q. Wang, "Plasmon resonant absorption and third-order optical nonlinearity in Ag-Ti cosputtered composite films," J. Appl. Phys.  99, 023526-1�??023526-4 (2006). [CrossRef]
  6. H. Pan, W. Chen, Y. P. Feng, W. Jia, and J. Linb, "Optical limiting properties of metal nanowires," Appl. Phys. Lett.  88, 223106-1�??223106-3 (2006). [CrossRef]
  7. J. P. Costes, J. F. Lame`re, C. Lepetit, P. G. Lacroix, and F. Dahan "Synthesis, Crystal Structures, and Nonlinear Optical (NLO) Properties of New Schiff-Base Nickel (II) Complexes. Toward a New Type of Molecular Switch," Inorg. Chem. 44, 1973�??1982 (2005). [CrossRef] [PubMed]
  8. A. Sugita, K. Yokoi, S. Aoshim, and S. Tasaka, "Electrical and optical properties of organic-titanium hybrid polymer, poly (2,3-dicyanophenyl bis-2,4-pentanedionate titanium alkoxide)," Chem. Phys. Lett. 416, 79�??82 (2005). [CrossRef]
  9. Z. Tian, W. Huang, D. Xiao, S. Wang, Y. Wu, Q. Gong, W. Yang, and J. Yao, "Enhanced and size-tunable third-order nonlinearity of nanoparticles from an azo metal chelate," Chem. Phys. Lett. 391, 283-287 (2004). [CrossRef]
  10. B. Sutapun, M. Tabib-Azar, and M. A. Huff, "Applications of shape memory alloys in optics" Appl. Opt. 37, 6811�??6815 (1998). [CrossRef]
  11. Y. Fu, H. Du, W. Huang, S. Zhang, and M. Hu, "TiNi-based thin films in MEMS applications: a review" Sensors Actuat. A 112, 395�??408 (2004). [CrossRef]
  12. S. K. Mahapatra, Hae Min Lee, and C. K. Kim, Division of Energy Systems Research, Ajou University, Suwon 443 749, Korea, are preparing a manuscript to be called "Size-control of nanostructured Ni-Ti alloy by variation of the electrolyte concentration."
  13. M. Sheik-Bahae, A. A. Said, T. H. Wei, D. J. Hagan, and E. W. Van Stryland, "Sensitive measurement of optical nonlinearities using a single beam," IEEE J. Quantum Electron. 26, 760�??769 (1990). [CrossRef]
  14. R. L. Sutherland with contributions by D. G. McLean and S. Kirkpatrick, Handbook of Nonlinear Optics, Second Edition, Revised and Expanded (New York, NY: Marcel Dekker, 2003). [CrossRef]
  15. S. Hughes, and B. Wherrett, "Multilevel rate-equation analysis to explain the recent observations of limitations to optical limiting dyes," Phys. Rev. A 54, 3546�??3552 (1996). [CrossRef] [PubMed]
  16. K. P. Unnikrishnan, V. P. N. Nampoori, V. Ramakrishnan, M. Umadevi, and C. P. G. Vallabhan, "Nonlinear optical absorption in silver nanosol," J. Phys. D 36, 1242�??1245 (2003). [CrossRef]
  17. S. Hughes, G. Spruce, B. S. Wherrett, K. R. Welford, and A.D. Lloyd, "The saturation limit to picosecond, induced absorption in dyes," Opt. Commun. 100, 113�??117 (1993). [CrossRef]
  18. S. Qu, C. Zhao, X. Jiang, G. Fang, Y. Gao, H. Zeng, Y. Song, J. Qiu, C. Zhu, and K. Hirao, "Optical nonlinearities of space selectively precipitated Au nanoparticles inside glasses," Chem. Phys. Lett. 368, 352�??358 (2003). [CrossRef]
  19. D. D. Smith, Y. Yoon, R. W. Boyd, J. K. Campbell, L. A. Baker, R. M. Crooks, and M. George, "Z-scan measurement of the nonlinear absorption of a thin gold film," J. Appl. Phys. 86, 6200�??6205 (1999). [CrossRef]

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