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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 17, Iss. 24 — Nov. 23, 2009
  • pp: 21704–21711

Ultra-sensitive fluorescence spectroscopy of isolated surface-adsorbed molecules using an optical nanofiber

A. Stiebeiner, O. Rehband, R. Garcia-Fernandez, and A. Rauschenbeutel  »View Author Affiliations


Optics Express, Vol. 17, Issue 24, pp. 21704-21711 (2009)
http://dx.doi.org/10.1364/OE.17.021704


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Abstract

The strong radial confinement and the pronounced evanescent field of the guided light in optical nanofibers yield favorable conditions for ultra-sensitive surface spectroscopy of molecules deposited on the fiber. Using the guided mode of the nanofiber for both excitation and fluorescence collection, we present spectroscopic measurements on 3,4,9,10-perylene-tetracarboxylic dianhydride molecules (PTCDA) at ambient conditions. Surface coverages as small as 1 ‰ of a compact monolayer still give rise to fluorescence spectra with a good signal to noise ratio. Moreover, we analyze and quantify the self-absorption effects due to reabsorption of the emitted fluorescence light by circumjacent surface-adsorbed molecules distributed along the fiber waist.

© 2009 Optical Society of America

OCIS Codes
(060.2370) Fiber optics and optical communications : Fiber optics sensors
(170.6280) Medical optics and biotechnology : Spectroscopy, fluorescence and luminescence
(240.6490) Optics at surfaces : Spectroscopy, surface
(300.2530) Spectroscopy : Fluorescence, laser-induced
(310.6860) Thin films : Thin films, optical properties

ToC Category:
Spectroscopy

History
Original Manuscript: October 12, 2009
Revised Manuscript: November 5, 2009
Manuscript Accepted: November 5, 2009
Published: November 11, 2009

Citation
A. Stiebeiner, O. Rehband, R. Garcia-Fernandez, and A. Rauschenbeutel, "Ultra-sensitive fluorescence spectroscopy of isolated surface-adsorbed molecules using an optical nanofiber," Opt. Express 17, 21704-21711 (2009)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-17-24-21704


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