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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 19, Iss. 12 — Jun. 6, 2011
  • pp: 11052–11058

Application of linear Raman spectroscopy for the determination of acetone decomposition

Simone Christine Eichmann, Johannes Trost, Thomas Seeger, Lars Zigan, and Alfred Leipertz  »View Author Affiliations


Optics Express, Vol. 19, Issue 12, pp. 11052-11058 (2011)
http://dx.doi.org/10.1364/OE.19.011052


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Abstract

Acetone (CH3)2CO is a common tracer for laser-induced fluorescence (LIF) to investigate mixture formation processes and temperature fields in combustion applications. Since the fluorescence signal is a function of temperature and pressure, calibration measurements in high pressure and high temperature cells are necessary. However, there is a lack of reliable data of tracer stability at these harsh conditions for technical application. A new method based on the effect of spontaneous Raman scattering is proposed to analyze the thermal stability of the tracer directly in the LIF calibration cell. This is done by analyzing the gas composition regarding educts and products of the reaction. First measurements at IC engine relevant conditions up to 750 K and 30 bar are presented.

© 2011 OSA

OCIS Codes
(300.0300) Spectroscopy : Spectroscopy
(300.6330) Spectroscopy : Spectroscopy, inelastic scattering including Raman

ToC Category:
Spectroscopy

History
Original Manuscript: March 7, 2011
Revised Manuscript: April 19, 2011
Manuscript Accepted: April 20, 2011
Published: May 23, 2011

Citation
Simone Christine Eichmann, Johannes Trost, Thomas Seeger, Lars Zigan, and Alfred Leipertz, "Application of linear Raman spectroscopy for the determination of acetone decomposition," Opt. Express 19, 11052-11058 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-12-11052


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