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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 19, Iss. 3 — Jan. 31, 2011
  • pp: 2493–2501

Sensitive and selective detection of OH radicals using Faraday rotation spectroscopy at 2.8 µm

Weixiong Zhao, Gerard Wysocki, Weidong Chen, Eric Fertein, David Le Coq, Denis Petitprez, and Weijun Zhang  »View Author Affiliations


Optics Express, Vol. 19, Issue 3, pp. 2493-2501 (2011)
http://dx.doi.org/10.1364/OE.19.002493


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Abstract

We report on the development of a Faraday rotation spectroscopy (FRS) instrument using a DFB diode laser operating at 2.8 µm for the hydroxyl (OH) free radical detection. The highest absorption line intensity and the largest gJ value make the Q (1.5) double lines of the 2Π3/2 state (υ = 1← 0) at 2.8 µm clearly the best choice for sensitive detection in the infrared region by FRS. The prototype instrument shows shot-noise dominated performance and, with an active optical pathlength of only 25 cm and a lock-in time constant of 100 ms, achieves a 1σ detection limit of 8.2 × 108 OH radicals/cm3.

© 2011 OSA

OCIS Codes
(120.6200) Instrumentation, measurement, and metrology : Spectrometers and spectroscopic instrumentation
(300.6380) Spectroscopy : Spectroscopy, modulation
(010.0280) Atmospheric and oceanic optics : Remote sensing and sensors

ToC Category:
Spectroscopy

History
Original Manuscript: August 27, 2010
Revised Manuscript: October 23, 2010
Manuscript Accepted: October 25, 2010
Published: January 26, 2011

Citation
Weixiong Zhao, Gerard Wysocki, Weidong Chen, Eric Fertein, David Le Coq, Denis Petitprez, and Weijun Zhang, "Sensitive and selective detection of OH radicals using Faraday rotation spectroscopy at 2.8 µm," Opt. Express 19, 2493-2501 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-3-2493


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