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Spontaneous buckling in flexible organic light-emitting devices for enhanced light extractionByoungchoo Park and Hong Goo Jeon »View Author Affiliations
Byoungchoo Park*
and Hong Goo Jeon
Department of Electrophysics, Kwangwoon Univ., Wolgye-Dong, Nowon-gu, Seoul 139-701, Korea *Corresponding author: bcpark@kw.ac.kr |
Optics Express, Vol. 19, Issue S5, pp. A1117-A1125 (2011)
http://dx.doi.org/10.1364/OE.19.0A1117
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Abstract
We herein present the results of a study of the direct fabrication of buckled patterns in flexible organic light-emitting devices (FOLEDs) that had a conducting polymer anode on a polyethersulfone substrate. These patterns were produced spontaneously by the thermal deposition of an aluminum cathode on an electroluminescent (EL) composite layer. The polymer used for the anode was modified poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) and the EL layer was composed of a solution-processable small molecular composite including phosphorescent Iridium complex mixed with a poly(vinylcarbazole) host. It is shown that FOLEDs produced with buckled patterns can exhibit a luminance as high as ca. 14,900 cd/m2 with a peak efficiency of 50.5 cd/A. The patterned structure formed by the buckling of the EL layer allows FOLEDs to be produced with a high peak external quantum efficiency of 15% with an increase in light extraction by a factor of ca. 3.1. These results show that spontaneous buckling yields patterned structures that offer considerable promise for the production of high performance, reproducible and reliable FOLEDs.
© 2011 OSA
OCIS Codes
(250.3680) Optoelectronics : Light-emitting polymers
(260.3800) Physical optics : Luminescence
(310.1860) Thin films : Deposition and fabrication
(310.6845) Thin films : Thin film devices and applications
ToC Category:
Optoelectronics
History
Original Manuscript: June 10, 2011
Revised Manuscript: July 25, 2011
Manuscript Accepted: July 25, 2011
Published: August 4, 2011
Virtual Issues
March 14, 2012 Spotlight on Optics
Citation
Byoungchoo Park and Hong Goo Jeon, "Spontaneous buckling in flexible organic light-emitting devices for enhanced light extraction," Opt. Express 19, A1117-A1125 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-S5-A1117
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References
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- J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, and A. B. Holmes, “Light-emitting diodes based on conjugated polymers,” Nature 347(6293), 539–541 (1990). [CrossRef]
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- W. H. Koo, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Simultaneous Extraction of Indium Tin Oxide/Organic and Substrate Waveguide Modes from Buckled Organic Light Emitting Diodes,” Appl. Phys. Express 4(3), 032101-1-032101-3 (2011). [CrossRef]
- W. H. Koo, S. M. Jeong, S. Nishimura, F. Araoka, K. Ishikawa, T. Toyooka, and H. Takezoe, “Polarization Conversion in Surface-Plasmon-Coupled Emission from Organic Light-Emitting Diodes Using Spontaneously Formed Buckles,” Adv. Mater. (Deerfield Beach Fla.) 23(8), 1003–1007 (2011). [CrossRef] [PubMed]
- W. H. Koo, H. J. Yun, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Spontaneously Buckled Microlens for Improving Outcoupled Organic Electroluminescence,” Appl. Phys. Express 3(8), 082501-1-082501-3 (2010). [CrossRef]
- W. H. Koo, S. M. Jeong, F. Araoka, K. Ishikawa, S. Nishimura, T. Toyooka, and H. Takezoe, “Light extraction from organic light-emitting diodes enhanced by spontaneously formed buckles,” Nat. Photonics 4(4), 222–226 (2010). [CrossRef]
- S. M. Jeong, F. Araoka, Y. Machida, K. Ishikawa, H. Takezoe, S. Nishimura, and G. Suzaki, “Enhancement of normally directed light outcoupling from organic light-emitting diodes,” Appl. Phys. Lett. 92(8), 083307-1-083307-3 (2008). [CrossRef]
- S. Okamoto, K. Tanaka, Y. Izumi, H. Adachi, T. Yamaji, and T. Suzuki, “Simple Measurement of Quantum Efficiency in Organic Electroluminescent Devices,” Jpn. J. Appl. Phys. 40(Part 2, No. 7B), L783–L784 (2001). [CrossRef]
- W. H. Koo, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Simultaneous Extraction of Indium Tin Oxide/Organic and Substrate Waveguide Modes from Buckled Organic Light Emitting Diodes,” Appl. Phys. Express 4(3), 032101-1-032101-3 (2011). [CrossRef]
- W. H. Koo, S. M. Jeong, S. Nishimura, F. Araoka, K. Ishikawa, T. Toyooka, and H. Takezoe, “Polarization Conversion in Surface-Plasmon-Coupled Emission from Organic Light-Emitting Diodes Using Spontaneously Formed Buckles,” Adv. Mater. (Deerfield Beach Fla.) 23(8), 1003–1007 (2011). [CrossRef] [PubMed]
- W. H. Koo, H. J. Yun, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Spontaneously Buckled Microlens for Improving Outcoupled Organic Electroluminescence,” Appl. Phys. Express 3(8), 082501-1-082501-3 (2010). [CrossRef]
- W. H. Koo, S. M. Jeong, F. Araoka, K. Ishikawa, S. Nishimura, T. Toyooka, and H. Takezoe, “Light extraction from organic light-emitting diodes enhanced by spontaneously formed buckles,” Nat. Photonics 4(4), 222–226 (2010). [CrossRef]
- S. M. Jeong, F. Araoka, Y. Machida, K. Ishikawa, H. Takezoe, S. Nishimura, and G. Suzaki, “Enhancement of normally directed light outcoupling from organic light-emitting diodes,” Appl. Phys. Lett. 92(8), 083307-1-083307-3 (2008). [CrossRef]
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Adv. Funct. Mater.
- J. M. Ziebarth, A. K. Saafir, S. Fan, and M. D. McGehee, “Extracting Light from Polymer Light-Emitting Diodes Using Stamped Bragg Grating,” Adv. Funct. Mater. 14(5), 451–456 (2004). [CrossRef]
- J. Huang, P. F. Miller, J. S. Wilson, A. J. de Mello, J. C. de Mello, and D. D. C. Bradley, “Investigation of the Effects of Dopong,” Adv. Funct. Mater. 15(2), 290–296 (2005). [CrossRef]
Adv. Mater. (Deerfield Beach Fla.)
- S.-I. Na, S.-S. Kim, J. Jo, and D.-Y. Kim, “Efficient and Flexible ITO-Free Organic Solar Cells Using Highly Conductive Polymer Anodes,” Adv. Mater. (Deerfield Beach Fla.) 20(21), 4061–4067 (2008). [CrossRef]
- W. H. Koo, S. M. Jeong, S. Nishimura, F. Araoka, K. Ishikawa, T. Toyooka, and H. Takezoe, “Polarization Conversion in Surface-Plasmon-Coupled Emission from Organic Light-Emitting Diodes Using Spontaneously Formed Buckles,” Adv. Mater. (Deerfield Beach Fla.) 23(8), 1003–1007 (2011). [CrossRef] [PubMed]
- B. J. Matterson, J. M. Lupton, A. F. Safonov, M. G. Salt, W. L. Barnes, and I. D. W. Samuel, “Increased Efficiency and Controlled Light Output from a Microstructured Light-Emitting Diode,” Adv. Mater. (Deerfield Beach Fla.) 13(2), 123–127 (2001). [CrossRef]
- K. Fehse, K. Walzer, K. Leo, W. Lövenich, and A. Elschner, “Highly Conductive Polymer Anodes as Replacements for Inorganic Materials in High-Efficiency Organic Light-Emitting Diodes,” Adv. Mater. (Deerfield Beach Fla.) 19(3), 441–444 (2007). [CrossRef]
Appl. Phys. Express
- W. H. Koo, H. J. Yun, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Spontaneously Buckled Microlens for Improving Outcoupled Organic Electroluminescence,” Appl. Phys. Express 3(8), 082501-1-082501-3 (2010). [CrossRef]
- W. H. Koo, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Simultaneous Extraction of Indium Tin Oxide/Organic and Substrate Waveguide Modes from Buckled Organic Light Emitting Diodes,” Appl. Phys. Express 4(3), 032101-1-032101-3 (2011). [CrossRef]
Appl. Phys. Lett.
- S. M. Jeong, F. Araoka, Y. Machida, K. Ishikawa, H. Takezoe, S. Nishimura, and G. Suzaki, “Enhancement of normally directed light outcoupling from organic light-emitting diodes,” Appl. Phys. Lett. 92(8), 083307-1-083307-3 (2008). [CrossRef]
- K. Ishihara, M. Fujita, I. Matsubara, T. Asano, S. Noda, H. Ohata, A. Hirasawa, H. Nakada, and N. Shimoji, “Organic light-emitting diodes with photonic crystals on glass substrate fabricated by nanoimprint lithography,” Appl. Phys. Lett. 90(11), 111114-1-111114-3 (2007). [CrossRef]
- C. W. Tang and S. A. VanSlyke, “Organic electroluminescent diodes,” Appl. Phys. Lett. 51(12), 913–915 (1987). [CrossRef]
- M. Fujita, T. Ueno, K. Ishihara, T. Asano, S. Noda, H. Ohata, T. Tsuji, H. Nakada, and N. Shimoji, “Reduction of operating voltage in organic light-emitting diode by corrugated photonic crystal structure,” Appl. Phys. Lett. 85(23), 5769–5771 (2004). [CrossRef]
- M. A. Baldo, S. Lamansky, P. E. Burrows, M. E. Thomspon, and S. R. Forrest, “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett. 75(1), 4–6 (1999). [CrossRef]
- X. H. Yang and D. Neher, “Polymer electrophosphorescence devices with high power conversion efficiencies,” Appl. Phys. Lett. 84(14), 2476–2478 (2004). [CrossRef]
Appl. Phys., A Mater. Sci. Process.
- L. Ke, R. S. Kumar, S. J. Chua, and A. P. Burden, “Degradation study in flexible substrate organic light-emitting diodes,” Appl. Phys., A Mater. Sci. Process. 81(5), 969–974 (2005). [CrossRef]
IEEE J. Sel. Top. Quantum Electron.
- C. Adachi, M. E. Thompson, and S. R. Forrest, “Architectures for efficient electrophosphorescent organic light-emitting devices,” IEEE J. Sel. Top. Quantum Electron. 8(2), 372–377 (2002). [CrossRef]
J. Appl. Phys.
- T. Ashida, A. Miyamura, N. Oka, Y. Sato, T. Yagi, N. Taketoshi, T. Baba, and Y. Shigesato, “Thermal transport properties of polycrystalline tin-doped indium oxide films,” J. Appl. Phys. 105(7), 073709-1-073709-4 (2009). [CrossRef]
- B. Park, C. H. Park, Y. Yim, and J. Park, “Electrical annealing for flexible organic light-emitting diodes,” J. Appl. Phys. 108(8), 084508-1-084508-6 (2010). [CrossRef]
- Y. Sun and S. R. Forrest, “Organic light emitting devices with enhanced outcoupling via microlenses fabricated by imprint lithography,” J. Appl. Phys. 100(7), 073106-1-073106-6 (2006). [CrossRef]
- T. Nakamura, N. Tsutsumi, N. Juni, and H. Fujii, “Improvement of coupling-out efficiency in organic electroluminescent devices by addition of a diffusive layer,” J. Appl. Phys. 96(11), 6016–6022 (2004). [CrossRef]
J. Fluid Mech.
- R. A. Pearson, “On convection cells induced by surface tension,” J. Fluid Mech. 4(05), 489–500 (1958). [CrossRef]
Jpn. J. Appl. Phys.
- S. Okamoto, K. Tanaka, Y. Izumi, H. Adachi, T. Yamaji, and T. Suzuki, “Simple Measurement of Quantum Efficiency in Organic Electroluminescent Devices,” Jpn. J. Appl. Phys. 40(Part 2, No. 7B), L783–L784 (2001). [CrossRef]
Nat. Photonics
- Y. Sun and S. R. Forrest, “Enhanced light out-coupling of organic light-emitting devices using embedded low-index grids,” Nat. Photonics 2(8), 483–487 (2008). [CrossRef]
- W. H. Koo, S. M. Jeong, F. Araoka, K. Ishikawa, S. Nishimura, T. Toyooka, and H. Takezoe, “Light extraction from organic light-emitting diodes enhanced by spontaneously formed buckles,” Nat. Photonics 4(4), 222–226 (2010). [CrossRef]
Nature
- N. Bowden, S. Brittain, A. G. Evans, J. W. Hutchinson, and G. M. Whitesides, “Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer,” Nature 393(6681), 146–149 (1998). [CrossRef]
- J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, and A. B. Holmes, “Light-emitting diodes based on conjugated polymers,” Nature 347(6293), 539–541 (1990). [CrossRef]
- M. A. Baldo, D. F. O’Brien, Y. You, A. Shoustikov, S. Sibley, M. E. Thompson, and S. R. Forrest, “Highly efficient phosphorescent emission fromorganic electroluminescent devices,” Nature 395(6698), 151–154 (1998). [CrossRef]
- S. Reineke, F. Lindner, G. Schwartz, N. Seidler, K. Walzer, B. Lüssem, and K. Leo, “White organic light-emitting diodes with fluorescent tube efficiency,” Nature 459(7244), 234–238 (2009). [CrossRef] [PubMed]
Polym. Compos.
- A. Saleem, L. Frormann, and A. Iqbal, “High performance thermoplastic composites: Study on the mechanical,” Polym. Compos. 28(6), 785–796 (2007). [CrossRef]
Other
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2011, Koo, Appl. Phys. Express
- W. H. Koo, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Simultaneous Extraction of Indium Tin Oxide/Organic and Substrate Waveguide Modes from Buckled Organic Light Emitting Diodes,” Appl. Phys. Express 4(3), 032101-1-032101-3 (2011). [CrossRef]
- W. H. Koo, S. M. Jeong, S. Nishimura, F. Araoka, K. Ishikawa, T. Toyooka, and H. Takezoe, “Polarization Conversion in Surface-Plasmon-Coupled Emission from Organic Light-Emitting Diodes Using Spontaneously Formed Buckles,” Adv. Mater. (Deerfield Beach Fla.) 23(8), 1003–1007 (2011). [CrossRef] [PubMed]
- W. H. Koo, S. M. Jeong, F. Araoka, K. Ishikawa, S. Nishimura, T. Toyooka, and H. Takezoe, “Light extraction from organic light-emitting diodes enhanced by spontaneously formed buckles,” Nat. Photonics 4(4), 222–226 (2010). [CrossRef]
- W. H. Koo, H. J. Yun, F. Araoka, K. Ishikawa, S. M. Jeong, S. Nishimura, T. Toyooka, and H. Takezoe, “Spontaneously Buckled Microlens for Improving Outcoupled Organic Electroluminescence,” Appl. Phys. Express 3(8), 082501-1-082501-3 (2010). [CrossRef]
- B. Zhang, J. Sun, H. E. Katz, F. Fang, and R. L. Opila, “Promising thermoelectric properties of commercial PEDOT:PSS materials and their bi2Te3 powder composites,” ACS Appl. Mater. Interfaces 2(11), 3170–3178 (2010). [CrossRef] [PubMed]
- B. Park, C. H. Park, Y. Yim, and J. Park, “Electrical annealing for flexible organic light-emitting diodes,” J. Appl. Phys. 108(8), 084508-1-084508-6 (2010). [CrossRef]
- T. Ashida, A. Miyamura, N. Oka, Y. Sato, T. Yagi, N. Taketoshi, T. Baba, and Y. Shigesato, “Thermal transport properties of polycrystalline tin-doped indium oxide films,” J. Appl. Phys. 105(7), 073709-1-073709-4 (2009). [CrossRef]
- S. Reineke, F. Lindner, G. Schwartz, N. Seidler, K. Walzer, B. Lüssem, and K. Leo, “White organic light-emitting diodes with fluorescent tube efficiency,” Nature 459(7244), 234–238 (2009). [CrossRef] [PubMed]
- S. M. Jeong, F. Araoka, Y. Machida, K. Ishikawa, H. Takezoe, S. Nishimura, and G. Suzaki, “Enhancement of normally directed light outcoupling from organic light-emitting diodes,” Appl. Phys. Lett. 92(8), 083307-1-083307-3 (2008). [CrossRef]
- Y. Sun and S. R. Forrest, “Enhanced light out-coupling of organic light-emitting devices using embedded low-index grids,” Nat. Photonics 2(8), 483–487 (2008). [CrossRef]
- S.-I. Na, S.-S. Kim, J. Jo, and D.-Y. Kim, “Efficient and Flexible ITO-Free Organic Solar Cells Using Highly Conductive Polymer Anodes,” Adv. Mater. (Deerfield Beach Fla.) 20(21), 4061–4067 (2008). [CrossRef]
- A. Saleem, L. Frormann, and A. Iqbal, “High performance thermoplastic composites: Study on the mechanical,” Polym. Compos. 28(6), 785–796 (2007). [CrossRef]
- K. Fehse, K. Walzer, K. Leo, W. Lövenich, and A. Elschner, “Highly Conductive Polymer Anodes as Replacements for Inorganic Materials in High-Efficiency Organic Light-Emitting Diodes,” Adv. Mater. (Deerfield Beach Fla.) 19(3), 441–444 (2007). [CrossRef]
- K. Ishihara, M. Fujita, I. Matsubara, T. Asano, S. Noda, H. Ohata, A. Hirasawa, H. Nakada, and N. Shimoji, “Organic light-emitting diodes with photonic crystals on glass substrate fabricated by nanoimprint lithography,” Appl. Phys. Lett. 90(11), 111114-1-111114-3 (2007). [CrossRef]
- Y. Sun and S. R. Forrest, “Organic light emitting devices with enhanced outcoupling via microlenses fabricated by imprint lithography,” J. Appl. Phys. 100(7), 073106-1-073106-6 (2006). [CrossRef]
- L. Ke, R. S. Kumar, S. J. Chua, and A. P. Burden, “Degradation study in flexible substrate organic light-emitting diodes,” Appl. Phys., A Mater. Sci. Process. 81(5), 969–974 (2005). [CrossRef]
- J. Huang, P. F. Miller, J. S. Wilson, A. J. de Mello, J. C. de Mello, and D. D. C. Bradley, “Investigation of the Effects of Dopong,” Adv. Funct. Mater. 15(2), 290–296 (2005). [CrossRef]
- T. Nakamura, N. Tsutsumi, N. Juni, and H. Fujii, “Improvement of coupling-out efficiency in organic electroluminescent devices by addition of a diffusive layer,” J. Appl. Phys. 96(11), 6016–6022 (2004). [CrossRef]
- J. M. Ziebarth, A. K. Saafir, S. Fan, and M. D. McGehee, “Extracting Light from Polymer Light-Emitting Diodes Using Stamped Bragg Grating,” Adv. Funct. Mater. 14(5), 451–456 (2004). [CrossRef]
- X. H. Yang and D. Neher, “Polymer electrophosphorescence devices with high power conversion efficiencies,” Appl. Phys. Lett. 84(14), 2476–2478 (2004). [CrossRef]
- M. Fujita, T. Ueno, K. Ishihara, T. Asano, S. Noda, H. Ohata, T. Tsuji, H. Nakada, and N. Shimoji, “Reduction of operating voltage in organic light-emitting diode by corrugated photonic crystal structure,” Appl. Phys. Lett. 85(23), 5769–5771 (2004). [CrossRef]
- C. Adachi, M. E. Thompson, and S. R. Forrest, “Architectures for efficient electrophosphorescent organic light-emitting devices,” IEEE J. Sel. Top. Quantum Electron. 8(2), 372–377 (2002). [CrossRef]
- S. Okamoto, K. Tanaka, Y. Izumi, H. Adachi, T. Yamaji, and T. Suzuki, “Simple Measurement of Quantum Efficiency in Organic Electroluminescent Devices,” Jpn. J. Appl. Phys. 40(Part 2, No. 7B), L783–L784 (2001). [CrossRef]
- B. J. Matterson, J. M. Lupton, A. F. Safonov, M. G. Salt, W. L. Barnes, and I. D. W. Samuel, “Increased Efficiency and Controlled Light Output from a Microstructured Light-Emitting Diode,” Adv. Mater. (Deerfield Beach Fla.) 13(2), 123–127 (2001). [CrossRef]
- M. A. Baldo, S. Lamansky, P. E. Burrows, M. E. Thomspon, and S. R. Forrest, “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett. 75(1), 4–6 (1999). [CrossRef]
- N. Bowden, S. Brittain, A. G. Evans, J. W. Hutchinson, and G. M. Whitesides, “Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer,” Nature 393(6681), 146–149 (1998). [CrossRef]
- M. A. Baldo, D. F. O’Brien, Y. You, A. Shoustikov, S. Sibley, M. E. Thompson, and S. R. Forrest, “Highly efficient phosphorescent emission fromorganic electroluminescent devices,” Nature 395(6698), 151–154 (1998). [CrossRef]
- J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, and A. B. Holmes, “Light-emitting diodes based on conjugated polymers,” Nature 347(6293), 539–541 (1990). [CrossRef]
- C. W. Tang and S. A. VanSlyke, “Organic electroluminescent diodes,” Appl. Phys. Lett. 51(12), 913–915 (1987). [CrossRef]
- R. A. Pearson, “On convection cells induced by surface tension,” J. Fluid Mech. 4(05), 489–500 (1958). [CrossRef]
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