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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 20, Iss. 12 — Jun. 4, 2012
  • pp: 13457–13469

High-order nonlinear optical response of a polymer nanocomposite film incorporating semiconducotor CdSe quantum dots

Xiangming Liu, Yusuke Adachi, Yasuo Tomita, Juro Oshima, Takuya Nakashima, and Tsuyoshi Kawai  »View Author Affiliations


Optics Express, Vol. 20, Issue 12, pp. 13457-13469 (2012)
http://dx.doi.org/10.1364/OE.20.013457


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Abstract

We report on observation of high-order optical nonlinearities in our recently developed photopolymerizable semiconductor CdSe quantum dot (QD)-polymer nanocomposite films at various volume fractions of CdSe QDs as high as 0.91 vol.% (3.6 wt.%). We performed Z-scan and degenerate multi-wave mixing (DMWM) measurements using a 532-nm picosecond laser delivering single 35 ps pulses at a repetition rate of 10 Hz. Using the uniformly cured polymer nanocomposite films, we observed the third- and fifth-order nonlinear optical effects in closed-aperture Z-scan measurements by which it was found that saturable nonlinear absorption (light-induced transparency) and large negative nonlinear refraction were induced. We also measured dependences of the effective third- and fifth-order nonlinear refraction constants on CdSe QD volume fraction. Based on the Maxwell-Garnett model, we estimated the third- and fifth-order nonlinear optical susceptibilities of CdSe QD and discussed a contribution of the third-order effect to the fifth-order one due to the cascaded (local-field) effect. Coexistence of the third- and fifth-order nonlinear refraction was also confirmed by DMWM.

© 2012 OSA

OCIS Codes
(160.4330) Materials : Nonlinear optical materials
(160.5470) Materials : Polymers
(160.6000) Materials : Semiconductor materials
(190.4400) Nonlinear optics : Nonlinear optics, materials
(190.5970) Nonlinear optics : Semiconductor nonlinear optics including MQW
(190.4223) Nonlinear optics : Nonlinear wave mixing
(160.4236) Materials : Nanomaterials
(160.5335) Materials : Photosensitive materials

ToC Category:
Nonlinear Optics

History
Original Manuscript: April 3, 2012
Revised Manuscript: April 30, 2012
Manuscript Accepted: April 30, 2012
Published: May 31, 2012

Citation
Xiangming Liu, Yusuke Adachi, Yasuo Tomita, Juro Oshima, Takuya Nakashima, and Tsuyoshi Kawai, "High-order nonlinear optical response of a polymer nanocomposite film incorporating semiconducotor CdSe quantum dots," Opt. Express 20, 13457-13469 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-12-13457


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