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Optical characteristics of silicon nanowires grown from tin catalyst layers on silicon coated glassJeremy Ball, Anthony Centeno, Budhika G. Mendis, H. S. Reehal, and Neil Alford »View Author Affiliations
Jeremy Ball,1,*
Anthony Centeno,2
Budhika G. Mendis,3
H. S. Reehal,1
and Neil Alford4
1Department of Engineering and Design, London South Bank University, 103 Borough Road, London SE1 0AA, UK 2Malaysia Japan International Institute of Technology, UTM International Campus, Jalan Semarak, 54100 Kuala Lumpur, Malaysia 3Department of Physics, Rochester Building Science Laboratories, Durham University, South road Durham, DH1 3LE, UK 4Department of Materials, Imperial College London, Exhibition Road, London, SW7, UK *Corresponding author: ballj6@lsbu.ac.uk |
Optics Express, Vol. 20, Issue 18, pp. 20266-20275 (2012)
http://dx.doi.org/10.1364/OE.20.020266
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Abstract
The optical characteristics of silicon nanowires grown on Si layers on glass have been modeled using the FDTD (Finite Difference Time Domain) technique and compared with experimental results. The wires were grown by the VLS (vapour-liquid-solid) method using Sn catalyst layers and exhibit a conical shape. The resulting measured and modeled absorption, reflectance and transmittance spectra have been investigated as a function of the thickness of the underlying Si layer and the initial catalyst layer, the latter having a strong influence on wire density. High levels of absorption (>90% in the visible wavelength range) and good agreement between the modeling and experiment have been observed when the nanowires have a relatively high density of ~4 wires/µm2. The experimental and modeled results diverge for samples with a lower density of wire growth. The results are discussed along with some implications for solar cell fabrication.
© 2012 OSA
OCIS Codes
(160.6000) Materials : Semiconductor materials
(310.6860) Thin films : Thin films, optical properties
(310.6628) Thin films : Subwavelength structures, nanostructures
ToC Category:
Thin Films
History
Original Manuscript: April 24, 2012
Revised Manuscript: June 29, 2012
Manuscript Accepted: July 6, 2012
Published: August 20, 2012
Citation
Jeremy Ball, Anthony Centeno, Budhika G. Mendis, H. S. Reehal, and Neil Alford, "Optical characteristics of silicon nanowires grown from tin catalyst layers on silicon coated glass," Opt. Express 20, 20266-20275 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-18-20266
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- O. Gunawan and S. Guha, “Characteristics of vapor-liquid-solid grown silicon nanowire solar cells,” Sol. Energy Sol. Cell.93(8), 1388–1393 (2009). [CrossRef]
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- B. K. Nayak, V. V. Iyengar, and M. C. Gupta, “Efficient light trapping in silicon solar cells by ultrafast-laser-induced self assembled micro/nano structures,” Prog. Photovolt. Res. Appl.19(6), 631–639 (2011). [CrossRef]
- Z. Pei, S. Thiyagu, M.-S. Jhong, W.-S. Hsieh, S.-J. Cheng, M.-W. Ho, Y.-H. Chen, J.-C. Liu, and C.-M. Yeh, “An amorphous silicon random nanocone/polymer hybrid solar cell,” Sol. Energy Mater. Sol. Cells95(8), 2431–2436 (2011). [CrossRef]
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- J. Zhu, C.-M. Hsu, Z. Yu, S. Fan, and Y. Cui, “Nanodome solar cells with efficient light management and self-cleaning,” Nano Lett.10(6), 1979–1984 (2010). [CrossRef] [PubMed]
- L. Hu and G. Chen, “Analysis of optical absorption in silicon nanowire arrays for photovoltaic applications,” Nano Lett.7(11), 3249–3252 (2007). [CrossRef] [PubMed]
- D. Kumar, S. K. Srivastava, P. K. Singh, M. Husain, and V. Kumar, “Fabrication of silicon nanowire arrays based solar cell with improved performance,” Sol. Energy Mater. Sol. Cells95(1), 215–218 (2011). [CrossRef]
- A. F. Oskooi, D. Roundy, M. Ibanescu, P. Bermel, J. D. Joannopoulos, and S. G. Johnson, “Meep: a flexible free-software package for electromagnetic simulations by the FDTD method,” Comput. Phys. Commun.181(3), 687–702 (2010). [CrossRef]
- B. K. Nayak, V. V. Iyengar, and M. C. Gupta, “Efficient light trapping in silicon solar cells by ultrafast-laser-induced self assembled micro/nano structures,” Prog. Photovolt. Res. Appl.19(6), 631–639 (2011). [CrossRef]
- S. Rathi, B. N. Jariwala, J. D. Beach, P. Stradins, P. C. Taylor, X. Weng, Y. Ke, J. M. Redwing, S. Argarwal, and R. T. Collins, “Tin catalyzed plasma-assisted growth of silicon nanowires,” J. Phys. Chem.115, 3833–3839 (2011).
- M. Jeon and K. Kamisako, “Synthesis and characterization of silicon nanowires using tin catalyst for solar cells application,” Mater. Lett.63(9-10), 777–779 (2009). [CrossRef]
- M. Jeon and K. Kamisako, “Synthesis of silicon nanowires after hydrogen radical treatment,” Mater. Lett.62(23), 3903–3905 (2008). [CrossRef]
- Z. Pei, S. Thiyagu, M.-S. Jhong, W.-S. Hsieh, S.-J. Cheng, M.-W. Ho, Y.-H. Chen, J.-C. Liu, and C.-M. Yeh, “An amorphous silicon random nanocone/polymer hybrid solar cell,” Sol. Energy Mater. Sol. Cells95(8), 2431–2436 (2011). [CrossRef]
- G. Jia, M. Steglich, I. Sill, and F. Falk, “Core-shell heterojunction solar cells on silicon nanowires arrays,” Sol. Energy Mater. Sol. Cells96, 226–230 (2012). [CrossRef]
- H. Li, R. Jia, C. Chen, Z. Xing, W. Ding, Y. Meng, D. Wu, X. Liu, and T. Ye, “Influence of nanowires length on performance of crystalline silicon solar cell,” Appl. Phys. Lett.98(15), 151116 (2011). [CrossRef]
- A. F. Oskooi, D. Roundy, M. Ibanescu, P. Bermel, J. D. Joannopoulos, and S. G. Johnson, “Meep: a flexible free-software package for electromagnetic simulations by the FDTD method,” Comput. Phys. Commun.181(3), 687–702 (2010). [CrossRef]
- A. F. Oskooi, D. Roundy, M. Ibanescu, P. Bermel, J. D. Joannopoulos, and S. G. Johnson, “Meep: a flexible free-software package for electromagnetic simulations by the FDTD method,” Comput. Phys. Commun.181(3), 687–702 (2010). [CrossRef]
- M. Jeon and K. Kamisako, “Synthesis and characterization of silicon nanowires using tin catalyst for solar cells application,” Mater. Lett.63(9-10), 777–779 (2009). [CrossRef]
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Comput. Phys. Commun.
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J. Phys. Chem.
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Nano Lett.
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Nanotechnology
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2012, Jia, Sol. Energy Mater. Sol. Cells
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- H. Li, R. Jia, C. Chen, Z. Xing, W. Ding, Y. Meng, D. Wu, X. Liu, and T. Ye, “Influence of nanowires length on performance of crystalline silicon solar cell,” Appl. Phys. Lett.98(15), 151116 (2011). [CrossRef]
- D. R. Kim, C. H. Lee, P. M. Rao, I. S. Cho, and X. Zheng, “Hybrid Si microwire and planar solar cells: passivation and characterization,” Nano Lett.11(7), 2704–2708 (2011). [CrossRef] [PubMed]
- B. Eisenhawer, S. Sensfuss, V. Sivakov, M. Pietsch, G. Andrä, and F. Falk, “Increasing the efficiency of polymer solar cells by silicon nanowires,” Nanotechnology22(31), 315401 (2011). [CrossRef] [PubMed]
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- W. F. Liu, J. I. Oh, and W. Z. Shen, “Light absorption mechanism in single c-Si (core)/a-Si (shell) coaxial nanowires,” Nanotechnology22(12), 125705 (2011). [CrossRef] [PubMed]
- L. Yu, F. Fortuna, B. O’Donnell, G. Patriache, and P. Roca i Cabarrocas, “Stability and evolution of low surface-tension metal catalyzed growth of silicon nanowires,” Appl. Phys. Lett.98(12), 123113 (2011). [CrossRef]
- A. F. Oskooi, D. Roundy, M. Ibanescu, P. Bermel, J. D. Joannopoulos, and S. G. Johnson, “Meep: a flexible free-software package for electromagnetic simulations by the FDTD method,” Comput. Phys. Commun.181(3), 687–702 (2010). [CrossRef]
- J. Zhu, C.-M. Hsu, Z. Yu, S. Fan, and Y. Cui, “Nanodome solar cells with efficient light management and self-cleaning,” Nano Lett.10(6), 1979–1984 (2010). [CrossRef] [PubMed]
- L. Yu, B. O’Donnell, J. P. Alet, and P. Roca i Cabarrocas, “All-in-situ fabrication and characterization of silicon nanowires on TCO/glass substrates for photovoltaic application,” Sol. Energy Mater. Sol. Cells94(11), 1855–1859 (2010). [CrossRef]
- M. M. Adachi, M. P. Anantram, and K. S. Karim, “Optical properties of crystalline-amorphous core-shell silicon nanowires,” Nano Lett.10(10), 4093–4098 (2010). [CrossRef] [PubMed]
- E. Garnett and P. Yang, “Light trapping in silicon nanowire solar cells,” Nano Lett.10(3), 1082–1087 (2010). [CrossRef] [PubMed]
- V. Schmidt, J. V. Wittemann, and U. Gösele, “Growth, thermodynamics, and electrical properties of silicon nanowires,” Chem. Rev.110(1), 361–388 (2010). [CrossRef] [PubMed]
- M. C. Putnam, S. W. Boettcher, M. D. Kelzenberg, B. D. Turner-Evans, J. M. Spurgeon, E. L. Warren, R. M. Briggs, N. S. Lewis, and H. A. Atwater, “Si microwire-array solar cells,” Energy Environ. Sci.3(8), 1037–1041 (2010). [CrossRef]
- P. Y. Yoon, Y. A. Yuwen, C. E. Kendrick, G. D. Barber, N. J. Podraza, J. M. Redwing, T. E. Mallouk, C. R. Wronski, and T. S. Mayer, “Enhanced conversion efficiencies for pillar array solar cells fabricated from crystalline silicon with short minority carrier diffusion lengths,” Appl. Phys. Lett.96(21), 213503 (2010). [CrossRef]
- V. Schmidt, J. V. Wittemann, and U. Gösele, “Growth, thermodynamics, and electrical properties of silicon nanowires,” Chem. Rev.110(1), 361–388 (2010). [CrossRef] [PubMed]
- O. Gunawan and S. Guha, “Characteristics of vapor-liquid-solid grown silicon nanowire solar cells,” Sol. Energy Sol. Cell.93(8), 1388–1393 (2009). [CrossRef]
- M. Jeon and K. Kamisako, “Synthesis and characterization of silicon nanowires using tin catalyst for solar cells application,” Mater. Lett.63(9-10), 777–779 (2009). [CrossRef]
- J. Li, H. Yu, S. M. Wong, G. Zhang, X. Sun, P. G.-Q. Lo, and D.-L. Kwong, “Si nanopillar array optimization on Si thin films for solar energy harvesting,” Appl. Phys. Lett.95(3), 033102 (2009). [CrossRef]
- M. Jeon and K. Kamisako, “Synthesis of silicon nanowires after hydrogen radical treatment,” Mater. Lett.62(23), 3903–3905 (2008). [CrossRef]
- O. L. Muskens, J. G. Rivas, R. E. Algra, E. P. A. M. Bakkers, and A. Lagendijk, “Design of light scattering in nanowire materials for photovoltaic applications,” Nano Lett.8(9), 2638–2642 (2008). [CrossRef] [PubMed]
- Th. Stelzner, M. Pietsch, G. Andrä, F. Falk, E. Ose, and S. Christiansen, “Silicon nanowire-based solar cells,” Nanotechnology19(29), 295203 (2008). [CrossRef] [PubMed]
- L. Tsakalakos, “Nanostructures for photovoltaics,” Mater. Sci. Eng. Rep.62(6), 175–189 (2008). [CrossRef]
- B. Tian, T. J. Kempa, and C. M. Lieber, “Single nanowire photovoltaics,” Chem. Soc. Rev.38(1), 16–24 (2008). [CrossRef] [PubMed]
- K. A. Dick, “A review of nanowire growth promoted by alloys and non-alloying elements with emphasis on Au –assisted iii-v nanowires,” Prog. Cryst. Growth Charact. Mater.54(3-4), 138–173 (2008). [CrossRef]
- L. Tsakalakos, J. Balch, J. Fronheiser, B. A. Korevaar, O. Sulima, and J. Rand, “Silicon nanowire solar cells,” Appl. Phys. Lett.91(23), 233117 (2007). [CrossRef]
- L. Tsakalakos, J. Balch, J. Fronheiser, M.-Y. Shih, S. F. Leboeuf, M. Pietrzykowski, P. J. Codella, B. A. Korevaar, O. Sulima, J. Rand, A. Davuluru, and U. Rapol, “Strong broadband optical absorption in silicon nanowire films,” J. Nanophoton.1(1), 013552–013562 (2007). [CrossRef]
- L. Hu and G. Chen, “Analysis of optical absorption in silicon nanowire arrays for photovoltaic applications,” Nano Lett.7(11), 3249–3252 (2007). [CrossRef] [PubMed]
- C. L. Cheung, R. J. Nikolic, C. E. Reinhardt, and T. F. Wang, “Fabrication of nanopillars by nanosphere lithography,” Nanotechnology17(5), 1339–1343 (2006). [CrossRef]
- V. A. Nebol’sin and A. A. Shchetinin, “Role of surface energy in the vapor-liquid-solid growth of silicon,” Inorg. Mater.39(9), 899–903 (2003). [CrossRef]
- W. M. Bullis, “Properties of gold in silicon,” Solid-State Electron.9(2), 143–168 (1966). [CrossRef]
- R. S. Wagner and W. C. Ellis, “Vapor-liquid-solid mechanism of single crystal growth,” Appl. Phys. Lett.4(5), 89–90 (1964). [CrossRef]
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