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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 20, Iss. 25 — Dec. 3, 2012
  • pp: 27319–27326

Correlation between emission property and concentration of Sn2+ center in the SnO-ZnO-P2O5 glass

Hirokazu Masai, Toshiro Tanimoto, Takumi Fujiwara, Syuji Matsumoto, Yomei Tokuda, and Toshinobu Yoko  »View Author Affiliations


Optics Express, Vol. 20, Issue 25, pp. 27319-27326 (2012)
http://dx.doi.org/10.1364/OE.20.027319


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Abstract

The authors report on the correlation between the photoluminescence (PL) property and the SnO amount in SnO-ZnO-P2O5 (SZP) glass. In the PL excitation (PLE) spectra of the SZP glass containing Sn2+ emission center, two S1 states, one of which is strongly affected by SnO amount, are assumed to exist. The PLE band closely correlates with the optical band edge originating from Sn2+ species, and they both largely red-shifts with increasing amount of SnO. The emission decay time of the SZP glass decreased with increasing amount of SnO and the internal quantum efficiencies of the SZP glasses containing 1~5 mol% of SnO are comparable to that of MgWO4. It is expected that the composition-dependent S1 state (the lower energy excitation band) governs the quantum efficiency of the SZP glasses.

© 2012 OSA

OCIS Codes
(160.2750) Materials : Glass and other amorphous materials
(250.5230) Optoelectronics : Photoluminescence
(300.2140) Spectroscopy : Emission

ToC Category:
Materials

History
Original Manuscript: October 11, 2012
Revised Manuscript: November 6, 2012
Manuscript Accepted: November 13, 2012
Published: November 20, 2012

Citation
Hirokazu Masai, Toshiro Tanimoto, Takumi Fujiwara, Syuji Matsumoto, Yomei Tokuda, and Toshinobu Yoko, "Correlation between emission property and concentration of Sn2+ center in the SnO-ZnO-P2O5 glass," Opt. Express 20, 27319-27326 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-25-27319


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References

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