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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 20, Iss. 27 — Dec. 17, 2012
  • pp: 28969–28980

Enhanced emission of Mn2+ via Ce3+→Mn2+ energy transfer in α-Sr2P2O7

Dejian Hou, Chunmeng Liu, Xiaojun Kuang, and Hongbin Liang  »View Author Affiliations


Optics Express, Vol. 20, Issue 27, pp. 28969-28980 (2012)
http://dx.doi.org/10.1364/OE.20.028969


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Abstract

Mn2+ doped and Ce3+-Mn2+ co-doped α-Sr2P2O7 phosphors were prepared by a traditional high-temperature solid-state reaction route. The UV-vis excitation and emission spectra for all samples were investigated. Luminescence of Mn2+ is assigned to from two different sites, which is similar to that of Ce3+. Energy transfer from Ce3+ to Mn2+ in co-doped phosphors α-Sr2P2O7: 0.03Ce3+, xMn2+ and α-Sr2P2O7: xCe3+, 0.1Mn2+ was investigated by the excitation and emission spectra as well as the luminescence decays. Both Ce3+(1) and Ce3+(2) can transfer energy to two types of Mn2+ ions.

© 2012 OSA

OCIS Codes
(160.2540) Materials : Fluorescent and luminescent materials
(250.5230) Optoelectronics : Photoluminescence
(300.6280) Spectroscopy : Spectroscopy, fluorescence and luminescence

ToC Category:
Materials

History
Original Manuscript: October 1, 2012
Revised Manuscript: November 19, 2012
Manuscript Accepted: November 20, 2012
Published: December 13, 2012

Citation
Dejian Hou, Chunmeng Liu, Xiaojun Kuang, and Hongbin Liang, "Enhanced emission of Mn2+ via Ce3+→Mn2+ energy transfer in α-Sr2P2O7," Opt. Express 20, 28969-28980 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-27-28969


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References

  1. X. J. Wang, D. D. Jia, and W. M. Yen, “Mn2+ activated green, yellow, and red long persistent phosphors,” J. Lumin.102–103, 34–37 (2003). [CrossRef]
  2. W. D. Wang, F. Q. Huang, Y. J. Xia, and A. B. Wang, “Photophysical and photoluminescence properties of co-activated ZnS: Cu, Mn phosphors,” J. Lumin.128(4), 610–614 (2008). [CrossRef]
  3. S. Ye, J. H. Zhang, X. Zhang, S. Z. Lu, X. G. Ren, and X. J. Wang, “Mn2+ activated red phosphorescence in BaMg2Si2O7: Mn2+, Eu2+, Dy3+ through persistent energy transfer,” J. Appl. Phys.101, 063545 (2007). [CrossRef]
  4. Y. Shuanglong, C. Xianlin, Z. Chaofeng, Y. Yunxia, and C. Guorong, “Eu2+, Mn2+ Co-doped (Sr, Ba)6BP5O20 - a novel phosphor for white-LED,” Opt. Mater.30(1), 192–194 (2007). [CrossRef]
  5. Y. H. Won, H. S. Jang, W. B. Im, D. Y. Jeon, and J. S. Lee, “Tunable full-color-emitting La0.827Al11.9O19.09: Eu2+, Mn2+ phosphor for application to warm white-light-emitting diodes,” Appl. Phys. Lett.89(23), 231909 (2006). [CrossRef]
  6. S. Ye, J. H. Zhang, X. Zhang, S. Z. Lu, X. G. Ren, and X. J. Wang, “Mn2+ concentration manipulated red emission in BaMg2Si2O7: Eu2+, Mn2+,” J. Appl. Phys.101, 033513 (2007). [CrossRef]
  7. Z. F. Mu, Y. H. Hu, H. Y. Wu, C. J. Fu, and F. W. Kang, “Luminescence and energy transfer of Mn2+ and Tb3+ in Y3Al5O12 phosphors,” J. Alloy. Comp.509(22), 6476–6480 (2011). [CrossRef]
  8. W. Liang and Y. H. Wang, “Energy transfer between Pr3+ and Mn2+ in K2YZr(PO4)3: Pr, Mn phosphor,” Mater. Chem. Phys.127(1-2), 170–173 (2011). [CrossRef]
  9. I. G. Valais, I. S. Kandarakis, D. N. Nikolopoulos, C. M. Michail, S. L. David, G. K. Loudos, D. A. Cavouras, and G. S. Panayiotakis, “Luminescence properties of (Lu; Y)2SiO5: Ce and Gd2SiO5: Ce single crystal scintillators under x-ray excitation for use in medical imaging systems,” IEEE Trans. Nucl. Sci.54(1), 11–18 (2007). [CrossRef]
  10. P. D. Rack, J. D. Peak, C. L. Melcher, and J. M. Fitz-Gerald, “Scanning electron and cathodoluminescence imaging of thin film Lu2SiO5: Ce scintillating materials,” Appl. Phys. Lett.91(24), 244102 (2007). [CrossRef]
  11. H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12: Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin.126(2), 371–377 (2007). [CrossRef]
  12. V. A. Bolchouchine, E. T. Goldburt, B. N. Levonovitch, V. N. Litchmanova, and N. P. Sochtine, “Designed, highly-efficient FED phosphors and screens,” J. Lumin.87–89, 1277–1279 (2000). [CrossRef]
  13. H. He, R. L. Fu, Y. G. Cao, X. F. Song, Z. W. Pan, X. R. Zhao, Q. B. Xiao, and R. Li, “Ce3+-Eu2+ energy transfer mechanism in the Li2SrSiO4: Eu2+, Ce3+ phosphor,” Opt. Mater.32(5), 632–636 (2010). [CrossRef]
  14. L. Wang, X. Zhang, Z. D. Hao, Y. S. Luo, J. H. Zhang, and X. J. Wang, “Interionic energy transfer in Y3Al5O12: Ce3+, Pr3+ phosphor,” J. Appl. Phys.108(9), 093515 (2010). [CrossRef]
  15. V. Pankratov, A. I. Popov, L. Shirmane, A. Kotlov, and C. Feldmann, “LaPO4: Ce, Tb and YVO4: Eu nanophosphors: luminescence studies in the vacuum ultraviolet spectral range,” J. Appl. Phys.110(5), 053522 (2011). [CrossRef]
  16. R. Pang, C. Y. Li, L. L. Shi, and Q. Su, “A novel blue-emitting long-lasting proyphosphate phosphor Sr2P2O7: Eu2+, Y3+,” J. Phys. Chem. Solids70(2), 303–306 (2009). [CrossRef]
  17. S. Ye, Z. S. Liu, J. G. Wang, and X. P. Jing, “Luminescent properties of Sr2P2O7: Eu, Mn phosphor under near UV excitation,” Mater. Res. Bull.43(5), 1057–1065 (2008). [CrossRef]
  18. D. J. Hou, B. Han, W. P. Chen, H. B. Liang, Q. Su, P. Dorenbos, Y. Huang, Z. H. Gao, and Y. Tao, “Luminescence of Ce3+ at two different sites in α-Sr2P2O7 under vacuum ultraviolet-UV and x-ray excitation,” J. Appl. Phys.108(8), 083527 (2010). [CrossRef]
  19. A. A. Coelho, TOPAS ACADEMIC, version 4, Brisbane, Australia, 2005.
  20. L. Hagman, I. Jansson, C. Magneli, O. Tolboe, and J. Paasivirta, “The crystal structure of α-Sr2P2O7,” Acta Chem. Scand.22, 1419–1429 (1968). [CrossRef]
  21. J. Barbier and J. P. Echard, “A new refinement of α-Sr2P2O7,” Acta Crystallogr. C54(12), IUC9800070 (1998). [CrossRef]
  22. C. M. Zhang, S. S. Huang, D. M. Yang, X. J. Kang, M. M. Shang, C. Peng, and J. Lin, “Tunable luminescence in Ce3+, Mn2+-codoped calcium fluorapatite through combining emissions and modulation of excitation: a novel strategy to white light emission,” J. Mater. Chem.20(32), 6674–6680 (2010). [CrossRef]
  23. G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+-coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011). [CrossRef]
  24. G. G. Li, D. L. Geng, M. M. Shang, Y. Zhang, C. Peng, Z. Y. Cheng, and J. Lin, “Color tuning luminescence of Ce3+/Mn2+/Tb3+-triactivated Mg2Y8(SiO4)6O2 via energy transfer: potential single-phase white-light-emitting phosphors,” J. Phys. Chem. C115(44), 21882–21892 (2011). [CrossRef]

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