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Efficiency enhancement of silicon solar cells using a nano-scale honeycomb broadband anti-reflection structureC.K. Huang, K.W. Sun, and W.-L. Chang »View Author Affiliations
C.K. Huang,1
K.W. Sun,1,*
and W.-L. Chang2
1Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan 2Green Energy & Environment Research Laboratories (GEL), Industrial Technology Research Institute (ITRI), Hsinchu, Taiwan *Corresponding author: kwsun@mail.nctu.edu.tw |
Optics Express, Vol. 20, Issue S1, pp. A85-A93 (2012)
http://dx.doi.org/10.1364/OE.20.000A85
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Abstract
This experiment demonstrates the process for manufacturing a ZnO honeycomb sub-wavelength structure using nanosphere lithography technology exhibiting excellent anti-reflection properties from the UV to NIR wavelength regions. This honeycomb nanostructure, combined with commercially available crystalline Si solar cells, show substantially improved conversion efficiency from 15.6% to 16.6% using optimized honeycomb sizes and precursor concentrations of ZnO. The present work develops an unsophisticated and economical technique suitable for industrial applications in producing a uniform and low-reflective texture.
© 2011 OSA
OCIS Codes
(040.5350) Detectors : Photovoltaic
(310.1210) Thin films : Antireflection coatings
(310.6628) Thin films : Subwavelength structures, nanostructures
ToC Category:
Photovoltaics
History
Original Manuscript: October 19, 2011
Revised Manuscript: November 24, 2011
Manuscript Accepted: December 8, 2011
Published: December 20, 2011
Citation
C.K. Huang, K.W. Sun, and W.-L. Chang, "Efficiency enhancement of silicon solar cells using a nano-scale honeycomb broadband anti-reflection structure," Opt. Express 20, A85-A93 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-S1-A85
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References
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- H. Zhou, T. Fan, T. Han, X. Li, J. Ding, D. Zhang, Q. Guo, and H. Ogawa, “Bacteria-based controlled assembly of metal chalcogenide hollow nanostructures with enhanced light-harvesting and photocatalytic properties,” Nanotechnology20(8), 085603 (2009). [CrossRef] [PubMed]
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- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
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- S. Pillai, K. R. Catchpole, T. Trupke, and M. A. Green, “Surface plasmon enhanced silicon solar cells,” J. Appl. Phys.101(9), 093105 (2007). [CrossRef]
- J. H. Zhao, A. H. Wang, M. A. Green, and F. Ferrazza, “19.8% efficient “honeycomb” textured multicrystalline and 24.4% monocrystalline silicon solar cells,” Appl. Phys. Lett.73(14), 1991–1993 (1998). [CrossRef]
- J. Zhao, A. Wang, P. Altermatt, and M. A. Green, “Twenty-four percent efficient silicon solar cells with double layer antireflection coatings and reduced resistance loss,” Appl. Phys. Lett.66(26), 3636 (1995). [CrossRef]
- L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. Zhang, R. J. Saykally, and P. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl.42(26), 3031–3034 (2003). [CrossRef] [PubMed]
- H. Zhou, T. Fan, T. Han, X. Li, J. Ding, D. Zhang, Q. Guo, and H. Ogawa, “Bacteria-based controlled assembly of metal chalcogenide hollow nanostructures with enhanced light-harvesting and photocatalytic properties,” Nanotechnology20(8), 085603 (2009). [CrossRef] [PubMed]
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- H. Zhou, T. Fan, T. Han, X. Li, J. Ding, D. Zhang, Q. Guo, and H. Ogawa, “Bacteria-based controlled assembly of metal chalcogenide hollow nanostructures with enhanced light-harvesting and photocatalytic properties,” Nanotechnology20(8), 085603 (2009). [CrossRef] [PubMed]
- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
- Y.-F. Huang, S. Chattopadhyay, Y.-J. Jen, C.-Y. Peng, T.-A. Liu, Y.-K. Hsu, C.-L. Pan, H.-C. Lo, C.-H. Hsu, Y.-H. Chang, C.-S. Lee, K.-H. Chen, and L.-C. Chen, “Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures,” Nat. Nanotechnol.2(12), 770–774 (2007). [CrossRef] [PubMed]
- Y.-F. Huang, S. Chattopadhyay, Y.-J. Jen, C.-Y. Peng, T.-A. Liu, Y.-K. Hsu, C.-L. Pan, H.-C. Lo, C.-H. Hsu, Y.-H. Chang, C.-S. Lee, K.-H. Chen, and L.-C. Chen, “Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures,” Nat. Nanotechnol.2(12), 770–774 (2007). [CrossRef] [PubMed]
- J. Y. Chen, W. L. Chang, C. K. Huang, and K. W. Sun, “Biomimetic nanostructured antireflection coating and its application on crystalline silicon solar cells,” Opt. Express19(15), 14411–14419 (2011). [CrossRef] [PubMed]
- C. K. Huang, H. H. Lin, J. Y. Chen, K. W. Sun, and W. L. Chang, “Efficiency enhancement of the poly-silicon solar cell using self-assembled dielectric nanoparticles,” Sol. Energy Mater. Sol. Cells95(8), 2540–2544 (2011). [CrossRef]
- S. Chattopadhyay, Y. F. Huang, Y. J. Jen, A. Ganguly, K. H. Chen, and L. C. Chen, “Anti-reflecting and photonic nanostructures,” Mater. Sci. Eng. Rep.69(1-3), 1–35 (2010). [CrossRef]
- Y.-F. Huang, S. Chattopadhyay, Y.-J. Jen, C.-Y. Peng, T.-A. Liu, Y.-K. Hsu, C.-L. Pan, H.-C. Lo, C.-H. Hsu, Y.-H. Chang, C.-S. Lee, K.-H. Chen, and L.-C. Chen, “Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures,” Nat. Nanotechnol.2(12), 770–774 (2007). [CrossRef] [PubMed]
- P. B. Clapham and M. C. Hutley, “Reduction of lens reflexion by the ‘Moth Eye’ principle,” Nature244(5414), 281–282 (1973). [CrossRef]
- B. Kim, J. Bang, S. Jang, D. Kim, and J. Kim, “Surface texturing of GaAs using a nanosphere lithography technique for solar cell applications,” Thin Solid Films518(22), 6583–6586 (2010). [CrossRef]
- S. Chattopadhyay, Y. F. Huang, Y. J. Jen, A. Ganguly, K. H. Chen, and L. C. Chen, “Anti-reflecting and photonic nanostructures,” Mater. Sci. Eng. Rep.69(1-3), 1–35 (2010). [CrossRef]
- Y.-F. Huang, S. Chattopadhyay, Y.-J. Jen, C.-Y. Peng, T.-A. Liu, Y.-K. Hsu, C.-L. Pan, H.-C. Lo, C.-H. Hsu, Y.-H. Chang, C.-S. Lee, K.-H. Chen, and L.-C. Chen, “Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures,” Nat. Nanotechnol.2(12), 770–774 (2007). [CrossRef] [PubMed]
- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
- L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. Zhang, R. J. Saykally, and P. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl.42(26), 3031–3034 (2003). [CrossRef] [PubMed]
- W. Joo, H. J. Kim, and J. K. Kim, “Broadband antireflection coating covering from visible to near infrared wavelengths by using multilayered nanoporous block copolymer films,” Langmuir26(7), 5110–5114 (2010). [CrossRef] [PubMed]
- B. Kim, J. Bang, S. Jang, D. Kim, and J. Kim, “Surface texturing of GaAs using a nanosphere lithography technique for solar cell applications,” Thin Solid Films518(22), 6583–6586 (2010). [CrossRef]
- B. Kim, J. Bang, S. Jang, D. Kim, and J. Kim, “Surface texturing of GaAs using a nanosphere lithography technique for solar cell applications,” Thin Solid Films518(22), 6583–6586 (2010). [CrossRef]
- L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. Zhang, R. J. Saykally, and P. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl.42(26), 3031–3034 (2003). [CrossRef] [PubMed]
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- Y. Lalatonne, J. Richardi, and M. P. Pileni, “Van der Waals versus dipolar forces controlling mesoscopic organizations of magnetic nanocrystals,” Nat. Mater.3(2), 121–125 (2004). [CrossRef] [PubMed]
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- H. Morikawa, D. Niinobe, K. Nishimura, S. Matsuno, and S. Arimoto, “Processes for over 18.5% high-efficiency multi-crystalline silicon solar cell,” Curr. Appl. Phys.10(2), S210–S214 (2010). [CrossRef]
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- Y.-F. Huang, S. Chattopadhyay, Y.-J. Jen, C.-Y. Peng, T.-A. Liu, Y.-K. Hsu, C.-L. Pan, H.-C. Lo, C.-H. Hsu, Y.-H. Chang, C.-S. Lee, K.-H. Chen, and L.-C. Chen, “Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures,” Nat. Nanotechnol.2(12), 770–774 (2007). [CrossRef] [PubMed]
- Y. Lalatonne, J. Richardi, and M. P. Pileni, “Van der Waals versus dipolar forces controlling mesoscopic organizations of magnetic nanocrystals,” Nat. Mater.3(2), 121–125 (2004). [CrossRef] [PubMed]
- S. Pillai, K. R. Catchpole, T. Trupke, and M. A. Green, “Surface plasmon enhanced silicon solar cells,” J. Appl. Phys.101(9), 093105 (2007). [CrossRef]
- E. Manea, E. Budianu, M. Purica, C. Podaru, A. Popescu, I. Cernica, F. Babarada, and C. C. Parvulescu, “SnO2 thin films prepared by sol gel method for ‘Honeycomb’ textured silicon solar cells,” Rom. J. Inform. Sci. Technol10, 25–33 (2007).
- E. Manea, E. Budianu, M. Purica, C. Podaru, A. Popescu, I. Cernica, F. Babarada, and C. C. Parvulescu, “SnO2 thin films prepared by sol gel method for ‘Honeycomb’ textured silicon solar cells,” Rom. J. Inform. Sci. Technol10, 25–33 (2007).
- E. Manea, E. Budianu, M. Purica, C. Podaru, A. Popescu, I. Cernica, F. Babarada, and C. C. Parvulescu, “SnO2 thin films prepared by sol gel method for ‘Honeycomb’ textured silicon solar cells,” Rom. J. Inform. Sci. Technol10, 25–33 (2007).
- Y. Lalatonne, J. Richardi, and M. P. Pileni, “Van der Waals versus dipolar forces controlling mesoscopic organizations of magnetic nanocrystals,” Nat. Mater.3(2), 121–125 (2004). [CrossRef] [PubMed]
- A. Parretta, A. Sarno, P. Tortora, H. Yakubu, P. Maddalena, J. H. Zhao, and A. H. Wang, “Angle-dependent reflectance measurements on photovoltaic materials and solar cells,” Opt. Commun.172(1-6), 139–151 (1999). [CrossRef]
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- L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. Zhang, R. J. Saykally, and P. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl.42(26), 3031–3034 (2003). [CrossRef] [PubMed]
- D. M. Schaadt, B. Feng, and E. T. Yu, “Enhanced semiconductor optical absorption via surface plasmon excitation in metal nanoparticles,” Appl. Phys. Lett.86(6), 063106 (2005). [CrossRef]
- S. Walheim, E. Schaffer, J. Mlynek, and U. Steiner, “Nanophase-separated polymer films as high-performance antireflection coatings,” Science283(5401), 520–522 (1999). [CrossRef] [PubMed]
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- K.-S. Han, J.-H. Shin, W.-Y. Yoon, and H. Lee, “Enhanced performance of solar cells with anti-reflection layer fabricated by nano-imprint lithography,” Sol. Energy Mater. Sol. Cells95(1), 288–291 (2011). [CrossRef]
- S. Walheim, E. Schaffer, J. Mlynek, and U. Steiner, “Nanophase-separated polymer films as high-performance antireflection coatings,” Science283(5401), 520–522 (1999). [CrossRef] [PubMed]
- H. R. Stuart and D. G. Hall, “Absorption enhancement in silicon-on-insulator waveguides using metal island films,” Appl. Phys. Lett.69(16), 2327–2329 (1996). [CrossRef]
- C. K. Huang, H. H. Lin, J. Y. Chen, K. W. Sun, and W. L. Chang, “Efficiency enhancement of the poly-silicon solar cell using self-assembled dielectric nanoparticles,” Sol. Energy Mater. Sol. Cells95(8), 2540–2544 (2011). [CrossRef]
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- X.-T. Zhang, O. Sato, M. Taguchi, Y. Einaga, T. Murakami, and A. Fujishima, “Self-cleaning particle coating with antireflection properties,” Chem. Mater.17(3), 696–700 (2005). [CrossRef]
- A. Parretta, A. Sarno, P. Tortora, H. Yakubu, P. Maddalena, J. H. Zhao, and A. H. Wang, “Angle-dependent reflectance measurements on photovoltaic materials and solar cells,” Opt. Commun.172(1-6), 139–151 (1999). [CrossRef]
- S. Pillai, K. R. Catchpole, T. Trupke, and M. A. Green, “Surface plasmon enhanced silicon solar cells,” J. Appl. Phys.101(9), 093105 (2007). [CrossRef]
- S. Walheim, E. Schaffer, J. Mlynek, and U. Steiner, “Nanophase-separated polymer films as high-performance antireflection coatings,” Science283(5401), 520–522 (1999). [CrossRef] [PubMed]
- J. Zhao, A. Wang, P. Altermatt, and M. A. Green, “Twenty-four percent efficient silicon solar cells with double layer antireflection coatings and reduced resistance loss,” Appl. Phys. Lett.66(26), 3636 (1995). [CrossRef]
- A. Parretta, A. Sarno, P. Tortora, H. Yakubu, P. Maddalena, J. H. Zhao, and A. H. Wang, “Angle-dependent reflectance measurements on photovoltaic materials and solar cells,” Opt. Commun.172(1-6), 139–151 (1999). [CrossRef]
- J. H. Zhao, A. H. Wang, M. A. Green, and F. Ferrazza, “19.8% efficient “honeycomb” textured multicrystalline and 24.4% monocrystalline silicon solar cells,” Appl. Phys. Lett.73(14), 1991–1993 (1998). [CrossRef]
- J. Li, H. Yu, S. M. Wong, G. Zhang, X. Sun, P. G.-Q. Lo, and D.-L. Kwong, “Si nanopillar array optimization on Si thin films for solar energy harvesting,” Appl. Phys. Lett.95(3), 033102 (2009). [CrossRef]
- D. Li, Y. H. Leung, A. B. Djurišić, Z. T. Liu, M. H. Xie, S. L. Shi, S. J. Xu, and W. K. Chan, “Different origins of visible luminescence in ZnO nanostructures fabricated by the chemical and evaporation methods,” Appl. Phys. Lett.85(9), 1601–1603 (2004). [CrossRef]
- D. Li, Y. H. Leung, A. B. Djurišić, Z. T. Liu, M. H. Xie, S. L. Shi, S. J. Xu, and W. K. Chan, “Different origins of visible luminescence in ZnO nanostructures fabricated by the chemical and evaporation methods,” Appl. Phys. Lett.85(9), 1601–1603 (2004). [CrossRef]
- A. Parretta, A. Sarno, P. Tortora, H. Yakubu, P. Maddalena, J. H. Zhao, and A. H. Wang, “Angle-dependent reflectance measurements on photovoltaic materials and solar cells,” Opt. Commun.172(1-6), 139–151 (1999). [CrossRef]
- Y. Li, J. Zhang, and B. Yang, “Antireflective surfaces based on biomimetic nanopillared arrays,” Nano Today5(2), 117–127 (2010). [CrossRef]
- L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. Zhang, R. J. Saykally, and P. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl.42(26), 3031–3034 (2003). [CrossRef] [PubMed]
- K.-S. Han, J.-H. Shin, W.-Y. Yoon, and H. Lee, “Enhanced performance of solar cells with anti-reflection layer fabricated by nano-imprint lithography,” Sol. Energy Mater. Sol. Cells95(1), 288–291 (2011). [CrossRef]
- S. H. Lim, W. Mar, P. Matheu, D. Derkacs, and E. T. Yu, “Photocurrent spectroscopy of optical absorption enhancement in silicon photodiodes via scattering from surface plasmon polaritons in gold nanoparticles,” J. Appl. Phys.101(10), 104309 (2007). [CrossRef]
- D. Derkacs, S. H. Lim, P. Matheu, W. Mar, and E. T. Yu, “Improved performance of amorphous silicon solar cells via scattering from surface plasmon polaritons in nearby metallic nanoparticles,” Appl. Phys. Lett.89(9), 093103 (2006). [CrossRef]
- D. M. Schaadt, B. Feng, and E. T. Yu, “Enhanced semiconductor optical absorption via surface plasmon excitation in metal nanoparticles,” Appl. Phys. Lett.86(6), 063106 (2005). [CrossRef]
- J. Li, H. Yu, S. M. Wong, G. Zhang, X. Sun, P. G.-Q. Lo, and D.-L. Kwong, “Si nanopillar array optimization on Si thin films for solar energy harvesting,” Appl. Phys. Lett.95(3), 033102 (2009). [CrossRef]
- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
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- J. Li, H. Yu, S. M. Wong, G. Zhang, X. Sun, P. G.-Q. Lo, and D.-L. Kwong, “Si nanopillar array optimization on Si thin films for solar energy harvesting,” Appl. Phys. Lett.95(3), 033102 (2009). [CrossRef]
- Y. Li, J. Zhang, and B. Yang, “Antireflective surfaces based on biomimetic nanopillared arrays,” Nano Today5(2), 117–127 (2010). [CrossRef]
- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
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- J. Zhao, A. Wang, P. Altermatt, and M. A. Green, “Twenty-four percent efficient silicon solar cells with double layer antireflection coatings and reduced resistance loss,” Appl. Phys. Lett.66(26), 3636 (1995). [CrossRef]
- A. Parretta, A. Sarno, P. Tortora, H. Yakubu, P. Maddalena, J. H. Zhao, and A. H. Wang, “Angle-dependent reflectance measurements on photovoltaic materials and solar cells,” Opt. Commun.172(1-6), 139–151 (1999). [CrossRef]
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- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
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Angew. Chem. Int. Ed. Engl.
- L. E. Greene, M. Law, J. Goldberger, F. Kim, J. C. Johnson, Y. Zhang, R. J. Saykally, and P. Yang, “Low-temperature wafer-scale production of ZnO nanowire arrays,” Angew. Chem. Int. Ed. Engl.42(26), 3031–3034 (2003). [CrossRef] [PubMed]
Appl. Catal. B
- Y. Zhao, X. T. Zhang, J. Zhai, J. L. He, L. Jiang, Z. Y. Liu, S. Nishimoto, T. Murakami, A. Fujishima, and D. B. Zhu, “Enhanced photocatalytic activity of hierarchically micro-/nano-porous TiO2 films,” Appl. Catal. B83(1-2), 24–29 (2008). [CrossRef]
Appl. Phys. Lett.
- D. Li, Y. H. Leung, A. B. Djurišić, Z. T. Liu, M. H. Xie, S. L. Shi, S. J. Xu, and W. K. Chan, “Different origins of visible luminescence in ZnO nanostructures fabricated by the chemical and evaporation methods,” Appl. Phys. Lett.85(9), 1601–1603 (2004). [CrossRef]
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- J. H. Zhao, A. H. Wang, M. A. Green, and F. Ferrazza, “19.8% efficient “honeycomb” textured multicrystalline and 24.4% monocrystalline silicon solar cells,” Appl. Phys. Lett.73(14), 1991–1993 (1998). [CrossRef]
- D. Derkacs, S. H. Lim, P. Matheu, W. Mar, and E. T. Yu, “Improved performance of amorphous silicon solar cells via scattering from surface plasmon polaritons in nearby metallic nanoparticles,” Appl. Phys. Lett.89(9), 093103 (2006). [CrossRef]
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Chem. Mater.
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