OSA's Digital Library

Energy Express

Energy Express

  • Editor: Christian Seassal
  • Vol. 20, Iss. S6 — Nov. 5, 2012
  • pp: A977–A983

Photoluminescence of Bi2+-doped BaSO4 as a red phosphor for white LEDs

Renping Cao, Mingying Peng, and Jianrong Qiu  »View Author Affiliations


Optics Express, Vol. 20, Issue S6, pp. A977-A983 (2012)
http://dx.doi.org/10.1364/OE.20.00A977


View Full Text Article

Acrobat PDF (2921 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations

Abstract

Bi2+-doped BaSO4 phosphor was synthesized in air via solid state reaction method. Three excitation bands and one emission band were observed at 260 nm (2P1/22S1/2), 452 nm (2P1/22P3/2(2)), 592 nm (2P1/22P3/2(1)), and 627 nm (2P3/2(1) → 2P1/2), respectively. W-LEDs were demonstrated by using a blend composition of BaSO4:Bi2+ and YAG:Ce3+ phosphors pumped with a 455 nm blue LEDs chip. The results indicate that BaSO4:Bi2+ phosphor is suitable as potential red phosphor for application in W-LEDs excited with blue LEDs chip.

© 2012 OSA

OCIS Codes
(160.2540) Materials : Fluorescent and luminescent materials
(160.4670) Materials : Optical materials

ToC Category:
Fluorescent and Luminescent Materials

History
Original Manuscript: September 11, 2012
Revised Manuscript: October 22, 2012
Manuscript Accepted: October 23, 2012
Published: November 1, 2012

Citation
Renping Cao, Mingying Peng, and Jianrong Qiu, "Photoluminescence of Bi2+-doped BaSO4 as a red phosphor for white LEDs," Opt. Express 20, A977-A983 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-S6-A977


Sort:  Author  |  Year  |  Journal  |  Reset

References

  1. J. Wang, Z. Liu, W. Ding, and Q. Su, “Luminescent Properties of (Ca1-xSrx)3SiO4(Cl1-yFy)2:Eu2+ Phosphors and Their Application for White LED,” J. Appl. Ceram. Technol.6(4), 447–452 (2009). [CrossRef]
  2. C. Lin, Y. Luo, H. You, Z. Quan, J. Zhang, J. Fang, and J. Lin, “Sol-gel-derived BPO4/Ba2+ as a new efficient and environmentally-friendly bluish white luminescent material,” Chem. Mater.18(2), 458–464 (2006). [CrossRef]
  3. H. Guo, H. Zhang, J. Li, and F. Li, “Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light,” Opt. Express18(26), 27257–27262 (2010). [CrossRef] [PubMed]
  4. C. H. Huang and T. M. Chen, “Ca9La(PO4)7:Eu2+,Mn2+: an emission-tunable phosphor through efficient energy transfer for white light-emitting diodes,” Opt. Express18(5), 5089–5099 (2010). [CrossRef] [PubMed]
  5. S. Zhou, N. Jiang, B. Zhu, H. Yang, S. Ye, G. Lakshminarayana, J. Hao, and J. Qiu, “Multifunctional Bismuth- Doped Nanoporous Silica Glass: From Blue-Green, Orange, Red, and White Light Sources to Ultra-Broadband Infrared Amplifiers,” Adv. Funct. Mater.18(9), 1407–1413 (2008). [CrossRef]
  6. R. Cao, M. Peng, E. Song, and J. Qiu, “High Efficiency Mn4+ Doped Sr2MgAl22O36 Red Emitting Phosphor for White LED,” ECS J. Solid State. Sci. Technol.1(4), R123–R126 (2012).
  7. J. Lü, F. Du, R. Zhu, Y. Huang, and H. Seo, “Phase formations and tunable red luminescence of Na2CaMg1-xMnx(PO4)2 (x = 0.05–1.0),” J. Mater. Chem.21(41), 16398–16405 (2011). [CrossRef]
  8. H. Guo, R. Wei, and X. Liu, “Tunable white luminescence and energy transfer in (Cu+)2, Eu3+ codoped sodium silicate glasses,” Opt. Lett.37(10), 1670–1672 (2012). [CrossRef] [PubMed]
  9. Y. Huang, Y. Nakai, T. Tsuboi, and H. J. Seo, “The new red-emitting phosphor of oxyfluoride Ca2RF4PO4:Eu3+ (R=Gd, Y) for solid state lighting applications,” Opt. Express19(7), 6303–6311 (2011). [CrossRef] [PubMed]
  10. W. R. Liu, C. C. Lin, Y. C. Chiu, Y. T. Yeh, S. M. Jang, and R. S. Liu, “ZnB2O4:Bi3+,Eu3+:a highly efficient, red-emitting phosphor,” Opt. Express18(3), 2946–2951 (2010). [CrossRef] [PubMed]
  11. H. Guo, X. Wang, J. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express18(18), 18900–18905 (2010). [CrossRef] [PubMed]
  12. Y. Chen, J. Wang, C. Liu, X. Kuang, and Q. Su, “A host sensitized reddish-orange Gd2MoO6:Sm3+ phosphor for light emitting diodes,” Appl. Phys. Lett.98(8), 081917 (2011). [CrossRef]
  13. C. de Mello Donegá, M. Crombag, A. Meijerink, and G. Blasse, “Vibronic transitions in the luminescence spectra of Pr3+ in Na5La(MoO4)4,” J. Lumin.60–61, 74–77 (1994). [CrossRef]
  14. Y. X. Pan and G. K. Liu, “Enhancement of phosphor efficiency via composition modification,” Opt. Lett.33(16), 1816–1818 (2008). [CrossRef] [PubMed]
  15. C. Kulshreshtha, J. H. Kwak, Y. J. Park, and K. S. Sohn, “Photoluminescent and Decay Behaviors of Mn2+ and Ce3+ Coactivated MgSiN2 Phosphors for Use in Light-Emitting-Diode Applications,” Opt. Lett.34(6), 794–796 (2009). [CrossRef] [PubMed]
  16. K. Murata, Y. Fujimoto, T. Kanabe, H. Fujita, and M. Nakatsuka, “Bi-doped SiO2 as a new laser material for an intense laser,” Fusion Eng. Des.44(1-4), 437–439 (1999). [CrossRef]
  17. R. Cao, M. Peng, L. Wondraczek, and J. Qiu, “Superbroad near-to-mid-infrared luminescence from Bi53+ in Bi5(AlCl4)3.,” Opt. Express20(3), 2562–2571 (2012). [CrossRef] [PubMed]
  18. A. N. Romanov, Z. T. Fattakhova, A. A. Veber, O. V. Usovich, E. V. Haula, V. N. Korchak, V. B. Tsvetkov, L. A. Trusov, P. E. Kazin, and V. B. Sulimov, “On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi⁺ and cluster Bi₅³⁺ luminescence in AlCl₃/ZnCl₂/BiCl₃ chloride glass,” Opt. Express20(7), 7212–7220 (2012). [CrossRef] [PubMed]
  19. R. Cao, M. Peng, J. Zheng, J. Qiu, and Q. Zhang, “Superbroad near to mid infrared luminescence from closo-deltahedral Bi53+ cluster in Bi5(GaCl4)3,” Opt. Express20(16), 18505–18514 (2012). [CrossRef] [PubMed]
  20. J. Ruan, L. Su, J. Qiu, D. Chen, and J. Xu, “Bi-doped BaF2 crystal for broadband near-infrared light source,” Opt. Express17(7), 5163–5169 (2009). [CrossRef] [PubMed]
  21. G. Blasse and A. Bril, “Investigations on Bi3 +-activated phosphors,” J. Chem. Phys.48(1), 217–222 (1968). [CrossRef]
  22. M. Peng, N. Da, S. Krolikowski, A. Stiegelschmitt, and L. Wondraczek, “Luminescence from Bi2+-activated alkali earth borophosphates for white LEDs,” Opt. Express17(23), 21169–21178 (2009). [CrossRef] [PubMed]
  23. M. Hamstra, H. Folkerts, and G. Blasse, “Materials chemistry communications. Red bismuth emission in alkaline-earth-metal sulfates,” J. Mater. Chem.4(8), 1349–1350 (1994). [CrossRef]
  24. G. Blasse, A. Meijerink, M. Nomes, and J. Zuidema, “Unusual bismuth luminescence in strontium tetraborate (SrB4O7:Bi),” J. Phys. Chem. Solids55(2), 171–174 (1994). [CrossRef]
  25. M. Peng and L. Wondraczek, “Orange-to-red emission from Bi2+ and alkaline earth codoped strontium borate phosphors for white light emitting diodes,” J. Am. Ceram. Soc.93, 1437–1442 (2010).
  26. A. Srivastava, “Luminescence of divalent bismuth in M2+BPO5 (M2+=Ba2+, Sr2+ and Ca2+),” J. Lumin.78(4), 239–243 (1998). [CrossRef]
  27. JCPDS Card No. 76–213.
  28. Z. Xia, J. Zhuang, and L. Liao, “Novel Red-Emitting Ba2Tb(BO3)2Cl:Eu Phosphor with Efficient Energy Transfer for Potential Application in White Light-Emitting Diodes,” Inorg. Chem.51(13), 7202–7209 (2012). [CrossRef] [PubMed]

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.


« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited