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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 21, Iss. 1 — Jan. 14, 2013
  • pp: 1008–1019

QEPAS based ppb-level detection of CO and N2O using a high power CW DFB-QCL

Yufei Ma, Rafał Lewicki, Manijeh Razeghi, and Frank K. Tittel  »View Author Affiliations


Optics Express, Vol. 21, Issue 1, pp. 1008-1019 (2013)
http://dx.doi.org/10.1364/OE.21.001008


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Abstract

An ultra-sensitive and selective quartz-enhanced photoacoustic spectroscopy (QEPAS) sensor platform was demonstrated for detection of carbon monoxide (CO) and nitrous oxide (N2O). This sensor used a state-of-the art 4.61 μm high power, continuous wave (CW), distributed feedback quantum cascade laser (DFB-QCL) operating at 10°C as the excitation source. For the R(6) CO absorption line, located at 2169.2 cm−1, a minimum detection limit (MDL) of 1.5 parts per billion by volume (ppbv) at atmospheric pressure was achieved with a 1 sec acquisition time and the addition of 2.6% water vapor concentration in the analyzed gas mixture. For the N2O detection, a MDL of 23 ppbv was obtained at an optimum gas pressure of 100 Torr and with the same water vapor content of 2.6%. In both cases the presence of water vapor increases the detected CO and N2O QEPAS signal levels as a result of enhancing the vibrational-translational relaxation rate of both target gases. Allan deviation analyses were performed to investigate the long term performance of the CO and N2O QEPAS sensor systems. For the optimum data acquisition time of 500 sec a MDL of 340 pptv and 4 ppbv was obtained for CO and N2O detection, respectively. To demonstrate reliable and robust operation of the QEPAS sensor a continuous monitoring of atmospheric CO and N2O concentration levels for a period of 5 hours were performed.

© 2013 OSA

OCIS Codes
(280.3420) Remote sensing and sensors : Laser sensors
(300.6340) Spectroscopy : Spectroscopy, infrared
(110.5125) Imaging systems : Photoacoustics
(140.5965) Lasers and laser optics : Semiconductor lasers, quantum cascade

ToC Category:
Remote Sensing

History
Original Manuscript: November 13, 2012
Revised Manuscript: December 29, 2012
Manuscript Accepted: December 29, 2012
Published: January 9, 2013

Citation
Yufei Ma, Rafał Lewicki, Manijeh Razeghi, and Frank K. Tittel, "QEPAS based ppb-level detection of CO and N2O using a high power CW DFB-QCL," Opt. Express 21, 1008-1019 (2013)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-21-1-1008


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