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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 21, Iss. 1 — Jan. 14, 2013
  • pp: 1020–1029

Absolute spectroscopy of N2O near 4.5 μm with a comb-calibrated, frequency-swept quantum cascade laser spectrometer

Kevin Knabe, Paul A. Williams, Fabrizio R. Giorgetta, Michael B. Radunsky, Chris M. Armacost, Sam Crivello, and Nathan R. Newbury  »View Author Affiliations


Optics Express, Vol. 21, Issue 1, pp. 1020-1029 (2013)
http://dx.doi.org/10.1364/OE.21.001020


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Abstract

We present absolute line center frequencies for 24 fundamental ν3 ro-vibrational P-branch transitions near 4.5 μm in N2O with an absolute expanded (multiplied by 2) frequency uncertainty of 800 kHz. The spectra are acquired with a swept laser spectrometer consisting of an external-cavity quantum cascade laser whose instantaneous frequency is continuously tracked against a near-infrared frequency comb. The measured absorbance profiles have a well-calibrated frequency axis, and are fitted to determine absolute line center values. We discuss the main sources of uncertainty.

© 2013 OSA

OCIS Codes
(300.6320) Spectroscopy : Spectroscopy, high-resolution
(140.5965) Lasers and laser optics : Semiconductor lasers, quantum cascade

ToC Category:
Spectroscopy

History
Original Manuscript: November 15, 2012
Revised Manuscript: December 20, 2012
Manuscript Accepted: December 20, 2012
Published: January 9, 2013

Citation
Kevin Knabe, Paul A. Williams, Fabrizio R. Giorgetta, Michael B. Radunsky, Chris M. Armacost, Sam Crivello, and Nathan R. Newbury, "Absolute spectroscopy of N2O near 4.5 μm with a comb-calibrated, frequency-swept quantum cascade laser spectrometer," Opt. Express 21, 1020-1029 (2013)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-21-1-1020


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References

  1. R. F. Curl, F. Capasso, C. Gmachl, A. A. Kosterev, B. McManus, R. Lewicki, M. Pusharsky, G. Wysocki, and F. K. Tittel, “Quantum cascade lasers in chemical physics,” Chem. Phys. Lett.487(1–3), 1–18 (2010). [CrossRef]
  2. G. Wysocki, R. Lewicki, R. F. Curl, F. K. Tittel, L. Diehl, F. Capasso, M. Troccoli, G. Hofler, D. Bour, S. Corzine, R. Maulini, M. Giovannini, and J. Faist, “Widely tunable mode-hop free external cavity quantum cascade lasers for high resolution spectroscopy and chemical sensing,” Appl. Phys. B92(3), 305–311 (2008). [CrossRef]
  3. S. Welzel, F. Hempel, M. Hübner, N. Lang, P. B. Davies, and J. Röpcke, “Quantum cascade laser absorption spectroscopy as a plasma diagnostic tool: An overview,” Sensors (Basel)10(7), 6861–6900 (2010). [CrossRef] [PubMed]
  4. K. Knabe, P. A. Williams, F. R. Giorgetta, C. M. Armacost, S. Crivello, M. B. Radunsky, and N. R. Newbury, “Frequency characterization of a swept- and fixed-wavelength external-cavity quantum cascade laser by use of a frequency comb,” Opt. Express20(11), 12432–12442 (2012). [CrossRef] [PubMed]
  5. P. Malara, P. Maddaloni, G. Gagliardi, and P. De Natale, “Absolute frequency measurement of molecular transitions by a direct link to a comb generated around 3-microm,” Opt. Express16(11), 8242–8249 (2008). [CrossRef] [PubMed]
  6. D. Mazzotti, P. Cancio, G. Giusfredi, P. De Natale, and M. Prevedelli, “Frequency-comb-based absolute frequency measurements in the mid-infrared with a difference-frequency spectrometer,” Opt. Lett.30(9), 997–999 (2005). [CrossRef] [PubMed]
  7. D. Gatti, A. Gambetta, A. Castrillo, G. Galzerano, P. Laporta, L. Gianfrani, and M. Marangoni, “High-precision molecular interrogation by direct referencing of a quantum-cascade-laser to a near-infrared frequency comb,” Opt. Express19(18), 17520–17527 (2011). [CrossRef] [PubMed]
  8. S. Bartalini, P. Cancio, G. Giusfredi, D. Mazzotti, P. De Natale, S. Borri, I. Galli, T. Leveque, and L. Gianfrani, “Frequency-comb-referenced quantum-cascade laser at 4.4 microm,” Opt. Lett.32(8), 988–990 (2007). [CrossRef] [PubMed]
  9. A. Gambetta, D. Gatti, A. Castrillo, G. Galzerano, P. Laporta, L. Gianfrani, and M. Marangoni, “Mid-infrared quantitative spectroscopy by comb-referencing of a quantum-cascade-laser: Application to the CO2 spectrum at 4.3 μm,” Appl. Phys. Lett.99(25), 251107 (2011). [CrossRef]
  10. S. Borri, S. Bartalini, I. Galli, P. Cancio, G. Giusfredi, D. Mazzotti, A. Castrillo, L. Gianfrani, and P. De Natale, “Lamb-dip-locked quantum cascade laser for comb-referenced IR absolute frequency measurements,” Opt. Express16(15), 11637–11646 (2008). [CrossRef] [PubMed]
  11. A. Gambetta, D. Gatti, A. Castrillo, N. Coluccelli, G. Galzerano, P. Laporta, L. Gianfrani, and M. Marangoni, “Comb-assisted spectroscopy of CO2 absorption profiles in the near- and mid-infrared regions,” Appl. Phys. B109(3), 385–390 (2012). [CrossRef]
  12. E. Baumann, F. R. Giorgetta, W. C. Swann, A. M. Zolot, I. Coddington, and N. R. Newbury, “Spectroscopy of the methane ν3 band with an accurate mid-infrared coherent dual-comb spectrometer,” Phys. Rev. A84(6), 062513 (2011). [CrossRef]
  13. “MCT detector model number PV-2TE-8 from VIGO System S.A. Identification of the specific detector does not imply recommendation or endorsement by NIST, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose,”
  14. I. Coddington, F. R. Giorgetta, E. Baumann, W. C. Swann, and N. R. Newbury, “Characterizing fast arbitrary cw waveforms with 1500 THz/s instantaneous chirps,” IEEE J. Sel. Top. Quantum Electron.18(1), 228–238 (2012). [CrossRef]
  15. L. S. Rothman, I. E. Gordon, A. Barbe, D. C. Benner, P. E. Bernath, M. Birk, V. Boudon, L. R. Brown, A. Campargue, J. P. Champion, K. Chance, L. H. Coudert, V. Dana, V. M. Devi, S. Fally, J. M. Flaud, R. R. Gamache, A. Goldman, D. Jacquemart, I. Kleiner, N. Lacome, W. J. Lafferty, J. Y. Mandin, S. T. Massie, S. N. Mikhailenko, C. E. Miller, N. Moazzen-Ahmadi, O. V. Naumenko, A. V. Nikitin, J. Orphal, V. I. Perevalov, A. Perrin, A. Predoi-Cross, C. P. Rinsland, M. Rotger, M. Simeckova, M. A. H. Smith, K. Sung, S. A. Tashkun, J. Tennyson, R. A. Toth, A. C. Vandaele, and J. Vander Auwera, “The HITRAN 2008 molecular spectroscopic database,” J. Quant. Spectrosc. Radiat. Transf.110(9–10), 533–572 (2009). [CrossRef]
  16. R. A. Toth, “Line strengths (900-3600 cm-1), self-broadened linewidths, and frequency shifts (1800-2360 cm-1) of N2O,” Appl. Opt.32(36), 7326–7365 (1993). [CrossRef] [PubMed]
  17. M. Mack, R. Carman, J. Reintjes, and N. Bloembergen, “Transient stimulated rotational and vibrational Raman scattering in gases,” Appl. Phys. Lett.16(5), 209–211 (1970). [CrossRef]
  18. E. A. McCormack, H. S. Lowth, M. T. Bell, D. Weidmann, and G. A. D. Ritchie, “Population transfer and rapid passage effects in a low pressure gas using a continuous wave quantum cascade laser,” J. Chem. Phys.137(3), 034306 (2012). [CrossRef] [PubMed]
  19. G. Duxbury, N. Langford, M. T. McCulloch, and S. Wright, “Rapid passage induced population transfer and coherences in the 8 micron spectrum of nitrous oxide,” Mol. Phys.105(5–7), 741–754 (2007). [CrossRef]
  20. G. Duxbury, J. F. Kelly, T. A. Blake, and N. Langford, “Sub-Doppler spectra of infrared hyperfine transitions of nitric oxide using a pulse modulated quantum cascade laser: Rapid passage, free induction decay, and the ac Stark effect,” J. Chem. Phys.136(17), 174319 (2012). [CrossRef] [PubMed]
  21. I. Coddington, W. C. Swann, and N. R. Newbury, “Time-domain spectroscopy of molecular free-induction decay in the infrared,” Opt. Lett.35(9), 1395–1397 (2010). [CrossRef] [PubMed]
  22. R. G. Brewer and R. Shoemaker, “Photon echo and optical nutation in molecules,” Phys. Rev. Lett.27(10), 631–634 (1971). [CrossRef]
  23. L. S. Rothman, A. Barbe, D. C. Benner, L. R. Brown, C. Camy-Peyret, M. R. Carleer, K. Chance, C. Clerbaux, V. Dana, V. M. Devi, A. Fayt, J. M. Flaud, R. R. Gamache, A. Goldman, D. Jacquemart, K. W. Jucks, W. J. Lafferty, J. Y. Mandin, S. T. Massie, V. Nemtchinov, D. A. Newnham, A. Perrin, C. P. Rinsland, J. Schroeder, K. M. Smith, M. A. H. Smith, K. Tang, R. A. Toth, J. Vander Auwera, P. Varanasi, and K. Yoshino, “The HITRAN molecular spectroscopic database: edition of 2000 including updates through 2001,” J. Quant. Spectrosc. Radiat. Transf.82(1–4), 5–44 (2003). [CrossRef]
  24. R. A. Toth, “N2O vibration-rotation parameters derived from measurements in the 900-1090 cm−1 and 1580-2380 cm−1 regions,” J. Opt. Soc. Am. B4(3), 357–374 (1987). [CrossRef]
  25. G. Guelachvili, “Absolute N2O wavenumbers between 1118 and 1343 cm−1 by Fourier-transform spectroscopy,” Can. J. Phys.60(9), 1334–1347 (1982). [CrossRef]
  26. B. N. Taylor and C. E. Kuyatt, “NIST technical note 1297: Guidelines for evaluating and expressing the uncertainty of NIST measurement results,” Technical report, National Institute of Standards and Technology (1994).

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