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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 21, Iss. 4 — Feb. 25, 2013
  • pp: 4167–4173

Broadband downshifting luminescence in Cr3+-Yb3+ codoped garnet for efficient photovoltaic generation

Song Ye, Jiajia Zhou, Shiting Wang, Rongxuan Hu, Deping Wang, and Jianrong Qiu  »View Author Affiliations


Optics Express, Vol. 21, Issue 4, pp. 4167-4173 (2013)
http://dx.doi.org/10.1364/OE.21.004167


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Abstract

The Cr3+-Yb3+ codoped YAG crystals were synthesized by the solid state reaction method, in which the intense near-infrared emission around 1000 nm originated from Yb3+ 2F5/22F7/2 transition was obtained due to the efficient energy transfer from Cr3+ to Yb3+. The stable and transient spectral measurements revealed that the phonon assistant energy transfer process is responsible for the energy transfer from Cr3+ to Yb3+ upon both the excitations of Cr3+: 4T1 and 4T2 energy levels. Due to the effective absorption of Cr3+ in the visible region in YAG and the efficient energy transfer to Yb3+, this material can be developed as spectral convertors to improve silicon solar cell photovoltaic conversion efficiency.

© 2013 OSA

OCIS Codes
(160.2540) Materials : Fluorescent and luminescent materials
(300.6340) Spectroscopy : Spectroscopy, infrared

ToC Category:
Solar Energy

History
Original Manuscript: December 4, 2012
Revised Manuscript: January 18, 2013
Manuscript Accepted: January 19, 2013
Published: February 11, 2013

Virtual Issues
European Conference on Optical Communication 2012 (2012) Optics Express

Citation
Song Ye, Jiajia Zhou, Shiting Wang, Rongxuan Hu, Deping Wang, and Jianrong Qiu, "Broadband downshifting luminescence in Cr3+-Yb3+ codoped garnet for efficient photovoltaic generation," Opt. Express 21, 4167-4173 (2013)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-21-4-4167


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