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Optics Express

Optics Express

  • Editor: Andrew M. Weiner
  • Vol. 22, Iss. 1 — Jan. 13, 2014
  • pp: 283–288

Pure optical nano-writing on light- switchable spiropyrans/merocyanine thin film

C. Triolo, S. Patanè, M. Mazzeo, S. Gambino, G. Gigli, and M. Allegrini  »View Author Affiliations


Optics Express, Vol. 22, Issue 1, pp. 283-288 (2014)
http://dx.doi.org/10.1364/OE.22.000283


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Abstract

We report optical writing at the nanometer scale of spin coated PMMA-spiropyran films. By using a near-field optical microscope, pure optical nano-writing with a resolution of 160 nm and writing speed of 0.4µm/s was achieved. Simultaneous topographic and optical writing was also obtained by simply coupling to the near-field few more mW of laser power. Due to the fast optical response of the spiropyran molecule, nano-lithography on PMMA-spyropyran thin films appears to be very attractive for future photonics applications.

© 2014 Optical Society of America

OCIS Codes
(180.0180) Microscopy : Microscopy
(180.4243) Microscopy : Near-field microscopy

ToC Category:
Microscopy

History
Original Manuscript: September 30, 2013
Revised Manuscript: November 10, 2013
Manuscript Accepted: November 12, 2013
Published: January 2, 2014

Virtual Issues
Vol. 9, Iss. 3 Virtual Journal for Biomedical Optics

Citation
C. Triolo, S. Patanè, M. Mazzeo, S. Gambino, G. Gigli, and M. Allegrini, "Pure optical nano-writing on light- switchable spiropyrans/merocyanine thin film," Opt. Express 22, 283-288 (2014)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-22-1-283


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References

  1. A. A. Argun, P. H. Aubert, B. C. Thompson, I. Schwendeman, C. L. Gaupp, J. Hwang, N. J. Pinto, D. B. Tanner, A. G. MacDiarmid, J. R. Reynolds, “Multicolored electrochromism in polymers: Structures and devices,” Chem. Mater. 16(23), 4401–4412 (2004). [CrossRef]
  2. V. Subramanian, J. M. J. Frechet, P. C. Chang, D. C. Huang, J. B. Lee, S. E. Molesa, A. R. Murphy, D. R. Redinger, S. K. Volkman, “Progress toward development of all-printed RFID tags: Materials, processes and devices,” Proc. IEEE 93(7), 1330–1338 (2005). [CrossRef]
  3. P. M. Beaujuge, J. R. Reynolds, “Color control in π-conjugated organic polymers for use in electrochromic devices,” Chem. Rev. 110(1), 268–320 (2010). [CrossRef] [PubMed]
  4. M. Campbell, D. N. Sharp, M. T. Harrison, R. G. Denning, A. J. Turberfield, “Fabrication of photonic crystals for the visible spectrum by holographic lithography,” Nature 404(6773), 53–56 (2000). [CrossRef] [PubMed]
  5. D. Credgington, O. Fenwick, A. Charas, J. Morgado, K. Suhling, F. Cacialli, “High-resolution scanning near-field optical lithography of conjugated polymers,” Adv. Funct. Mater. 20(17), 2842–2847 (2010). [CrossRef]
  6. S. Hosaka, A. Kikukawa, H. Koyanagi, T. Shintani, M. Miyamoto, K. Nakamura, K. Etoh, “SPM-based data storage for ultrahigh density recording,” Nanotechnology 8(3A), A58–A62 (1997). [CrossRef]
  7. G. J. Leggett, “Scanning near-field photolithography--surface photochemistry with nanoscale spatial resolution,” Chem. Soc. Rev. 35(11), 1150–1161 (2006). [CrossRef] [PubMed]
  8. S. Patanè, A. Arena, M. Allegrini, L. Andreozzi, M. Faetti, M. Giordano, “Near-field optical writing on azo-polymethacrylate spin-coated films,” Opt. Commun. 210(1–2), 37–41 (2002). [CrossRef]
  9. A. Ambrosio, A. Camposeo, P. Maddalena, S. Patanè, M. Allegrini, “Real-time monitoring of the surface relief formation on azo-polymer films upon near-field excitation,” J. Microsc. 229(2), 307–312 (2008). [CrossRef] [PubMed]
  10. A. Ambrosio, S. Girardo, A. Camposeo, D. Pisignano, P. Maddalena, “Controlling spontaneous surface structuring of azobenzene-containing polymers for large-scale nano-lithography of functional substrates,” Appl. Phys. Lett. 102(9), 093102 (2013). [CrossRef]
  11. A. Ambrosio, P. Maddalena, L. Marrucci, “Molecular model for light-driven spiral mass transport in azopolymer films,” Phys. Rev. Lett. 110(14), 146102 (2013). [CrossRef]
  12. V. Likodimos, M. Labardi, L. Pardi, M. Allegrini, M. Giordano, A. Arena, S. Patanè, “Optical nanowriting on azobenzene side-chain polymethacrylate thin films by near-field scanning optical microscopy,” Appl. Phys. Lett. 82(19), 3313–3316 (2003). [CrossRef]
  13. F. Tantussi, S. Menghetti, E. Caldi, F. Fuso, M. Allegrini, G. Galli, “Pure optical and reversible optically driven nanowriting of azobenzene block copolymers,” Appl. Phys. Lett. 100(8), 083103 (2012). [CrossRef]
  14. R. D. Macuil, M. R. Lopez, A. O. Diaz, V. C. Pernas, “Spectroscopy analysis of spiropyran-merocyanine molecular transformation,” J. Phys. Conf. Ser. 167, 012038 (2009). [CrossRef]
  15. M. Tomasulo, E. Deniz, R. J. Alvarado, F. M. Raymo, “Photoswitchable fluorescent assemblies based on hydrophilic BODIPY-spiropyran conjugates,” J. Phys. Chem. C 112(21), 8038–8045 (2008). [CrossRef]
  16. Y. Song and D. Zhu, High Density Data Storage: Principle, Technology and Materials (World Scientific, 2009).
  17. I. S. Park, Y.-S. Jung, K.-J. Lee, J.-M. Kim, “Photoswitching and sensor applications of a spiropyran-polythiophene conjugate,” Chem. Commun. 46(16), 2859–2861 (2010). [CrossRef] [PubMed]
  18. G. Berkovic, V. Krongauz, V. Weiss, “Spiropyrans and spirooxazines for memories and switches,” Chem. Rev. 100(5), 1741–1754 (2000). [CrossRef] [PubMed]
  19. T. Schwartz, J. A. Hutchison, C. Genet, T. W. Ebbesen, “Reversible switching of ultrastrong light-molecule coupling,” Phys. Rev. Lett. 106(19), 196405 (2011). [CrossRef] [PubMed]
  20. E. Cefalì, S. Patanè, P. G. Gucciardi, M. Labardi, M. Allegrini, “A versatile multipurpose scanning probe microscope,” J. Microsc. 210(3), 262–268 (2003). [CrossRef] [PubMed]
  21. M. Stähelin, M. A. Bopp, G. Tarrach, A. J. Meixner, I. Zschokke-Gränacher, “Temperature profile of fiber tips used in scanning near-field optical microscopy,” Appl. Phys. Lett. 68(19), 2603–2606 (1996). [CrossRef]
  22. P. G. Gucciardi, S. Patanè, A. Ambrosio, M. Allegrini, A. D. Downes, G. Latini, O. Fenwick, F. Cacialli, “Observation of tip-to-sample heat transfer in near-field optical microscopy using metal-coated fiber probes,” Appl. Phys. Lett. 86(20), 203109 (2005). [CrossRef]
  23. C. B. Roth, J. R. Dutcher, “Glass transition temperature of freely-standing films of atactic poly(methyl methacrylate),” Eur Phys J E Soft Matter 12(S1), S103–S107 (2003). [CrossRef] [PubMed]

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