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Optics Express

Optics Express

  • Editor: Michael Duncan
  • Vol. 11, Iss. 13 — Jun. 30, 2003
  • pp: 1566–1576

Isotope analysis of water by means of near-infrared dual-wavelength diode laser spectroscopy

L. Gianfrani , G. Gagliardi , M. van Burgel, and E. R. Th. Kerstel  »View Author Affiliations


Optics Express, Vol. 11, Issue 13, pp. 1566-1576 (2003)
http://dx.doi.org/10.1364/OE.11.001566


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Abstract

A novel diode laser spectrometer was developed using dual-wavelength multiplexing, ensuring ideal conditions for high-precision and simultaneous measurements of the 2H/1H, 17O/16O, and 18O/16O isotope ratios in water. A 1.4-µm diode laser probed a H16OH / HO2H line pair near 7198 cm-1, while a similar laser observed H16OH, H17OH, and H18OH ro-vibrational lines around 7183 cm-1, or a H16OH / H18OH line pair near 7200 cm-1. The 1-σ standard deviation is 0.2‰ for 18O/16O, and 0.5‰ for the 2H/1H and 17O/16O isotope ratios. Preliminary experiments with repeated injections of a natural abundance sample point to an accuracy of about 1‰ for all three isotope ratios in natural samples.

© 2003 Optical Society of America

OCIS Codes
(300.1030) Spectroscopy : Absorption
(300.6260) Spectroscopy : Spectroscopy, diode lasers

ToC Category:
Research Papers

History
Original Manuscript: May 7, 2003
Revised Manuscript: June 4, 2003
Published: June 30, 2003

Citation
L. Gianfrani, G. Gagliardi, M. van Burgel, and Erik Kerstel, "Isotope analysis of water by means of near infrared dual-wavelength diode laser spectroscopy," Opt. Express 11, 1566-1576 (2003)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-11-13-1566


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References

  1. E. R. Th. Kerstel: Isotope Ratio Infrared Spectrometry, in Handbook of Stable Isotope Analytical Techniques, ed. P.A. de Groot, Elsevier, accepted for publication.
  2. G. Gagliardi, R. Restieri, G. De Biasio, P. De Natale, F. Cotrufo, and L. Gianfrani, �??Quantitative diode laser absorption spectroscopy near 2 m with high precision measurements of CO2 concentration,�?? Rev. Sci. Instr. 72, 4228-4233 (2001). [CrossRef]
  3. M. P. Arroyo and R. K. Hanson, �??Absorption measurements of water-vapor concentration, temperature, and line-shape parameters using tunable InGaAsP diode laser,�?? Appl. Opt. 32, 6104-6116 (1993). [CrossRef] [PubMed]
  4. I. Linnerud, P. Kaspersen, and T. Jaeger, �??Gas monitoring in the process industry using diode laser spectroscopy,�?? Appl. Phys. B 67, 297-305 (1998). [CrossRef]
  5. D. S. Baer, R. K. Hanson, M. E. Newfield, and N. K. J. M. Gopaul, �??Multiplexed diode-laser sensor system for simultaneous H2O, O2, and temperature measurements�??, Opt. Lett. 19, 1900-1902 (1994). [CrossRef] [PubMed]
  6. L. Gianfrani, P. De Natale, and G. De Natale, �??Remote sensing of volcanic gases with a DFB-laser-based fiber spectrometer,�?? Appl. Phys. B 70, 467-470 (2000).
  7. M. P. Arroyo, T. P. Birbeck, D. S. Baer, and R. K. Hanson, "Dual diode-Laser fiber-optic diagnostic for water vapor measurements," Opt. Lett. 19, 1091-1093 (1994). [CrossRef] [PubMed]
  8. G. Totschnig, D. S. Baer, J. Wang, F. Winter, H. Hofbauer, and R. K. Hanson, "Multiplexed continuouswave diode-laser cavity ringdown measurements of multiple species," Appl. Opt. 39, 2009-2016, (2000). [CrossRef]
  9. D. B. Oh, M. E. Paige, and D. S. Bomse, �??Frequency modulation multiplexing for simultaneous detection of multiple gases by use of wavelength modulation spectroscopy with diode laers,�?? Appl. Opt. 37, 2499-2501 (1998). [CrossRef]
  10. E. R. Th. Kerstel, R. van Trigt, N. Dam, J. Reuss, and H. A. J. Meijer, �??Simultaneous determination of the 2H/1H, 17O/16O, and 18O/16O isotope abundance ratios in water by means of laser spectrometry,�?? Anal. Chem. 71, 5297-5303 (1999). [CrossRef] [PubMed]
  11. R. van Trigt, H. A. J. Meijer, A. E. Sveinbjornsdottir, S. J. Johnsen, and E. R. Th. Kerstel, �?? Measuring stable isotopes of hydrogen and oxygen in ice: the Bølling transition in the Dye�??3 (south Greenland) ice core,�?? Ann. Glaciol. 35, 125-130 (2002). [CrossRef]
  12. R. van Trigt, E. R. Th. Kerstel, R. E. M. Neubert, H. A. J. Meijer, M. McLean, and G. H. Visser, �??Validation of the doubly labeled water method in japanese quail at different water fluxes,�?? J. Appl. Physiol. 93, 2147-2154 (2002). [PubMed]
  13. E. R. Th. Kerstel, G. Gagliardi, L. Gianfrani, H. A. J. Meijer, R. van Trigt, and R. Ramaker, �??Determination of the 2H/1H, 17O/16O, and 18O/16O isotope ratios in water by means of tunable diode laser spectroscopy at 1.39 m,�?? Spectrochim. Acta 58, 2389-2396 (2002). [CrossRef]
  14. R. A. Toth, �??Extensive measurements of H2 16O line frequencies and strengths: 5750 to 7965 cm-1,�?? Appl. Opt. 33, 4851-4867 (1994). [CrossRef] [PubMed]
  15. R. A. Toth, �??Transition frequencies and strengths of H2 17O and H2 18O: 6600 to 7640 cm-1,�?? Appl. Opt. 33, 4868-4879 (1994). [CrossRef] [PubMed]
  16. R. A. Toth: private communication (2000).

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