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Optics Express

Optics Express

  • Editor: Michael Duncan
  • Vol. 14, Iss. 9 — May. 1, 2006
  • pp: 3993–4004

Infrared to visible upconversion of Nd3+ ions in KPb2Br5 low phonon crystal

Rolindes Balda, Joaquín Fernändez, Ei Ei Nyein, and Uwe Hömmerich  »View Author Affiliations


Optics Express, Vol. 14, Issue 9, pp. 3993-4004 (2006)
http://dx.doi.org/10.1364/OE.14.003993


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Abstract

In this work we present a detailed analysis of the infrared to visible upconversion in Nd3+-doped KPb2Br5 low phonon crystal by using both steady-state and time-resolved luminescence spectroscopy. Efficient blue, green, orange, and red emissions have been observed under excitation into the 4F5/2 and 4F3/2 states. The low phonon energy of this crystal leads to a significant reduction of the multiphonon relaxation rates which allows most of the excited states to relax radiatively. To investigate the nature of the upconversion processes, emission spectroscopy and lifetime measurements for the visible fluorescence, performed by using one photon excitation, have been compared to the upconverted emissions and lifetimes obtained under infrared pulsed excitation. The analysis of the experimental results indicates that the upconverted emissions occur via energy-transfer upconversion.

© 2006 Optical Society of America

OCIS Codes
(140.3380) Lasers and laser optics : Laser materials
(160.5690) Materials : Rare-earth-doped materials
(190.7220) Nonlinear optics : Upconversion

ToC Category:
Nonlinear Optics

History
Original Manuscript: February 28, 2006
Revised Manuscript: April 12, 2006
Manuscript Accepted: April 17, 2006
Published: May 1, 2006

Citation
Rolindes Balda, Joaquín Fernández, Ei Ei Nyein, and Uwe Hömmerich, "Infrared to visible upconversion of Nd3+ ions in KPb2Br5 low phonon crystal," Opt. Express 14, 3993-4004 (2006)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-14-9-3993


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References

  1. F. E. Auzel, "Upconversion and anti-stokes processes with f and d Ions in Solids," Chem. Rev. (Washington D.C.) 104, 139-174 (2004). [CrossRef] [PubMed]
  2. A. A. Kaminskii, in Laser Crystals, 2nd ed., D. L. MacAdam, ed. Springer series in Optical Sciences Vol. 14 (Springer-Verlag, Berlin, 1990).
  3. M. J. Weber, "Science and technology of laser glass," J. Non-Cryst. Solids 123, 208-222 (1990) [CrossRef]
  4. S. Guy, M. F. Joubert, B. Jacquier, and M. Bouazaoui, "Excited-state absorption in BaY2F8:Nd3+," Phys. Rev. B 4711001-11006 (1993). [CrossRef]
  5. Y. Guyot, H. Manaa, J. Y. Rivoire, R. Moncorgé, N. Garnier, E. Descroix, M. Bon, and P. Laporte, "Excited-state-absorption and upconversion studies of Nd3+-doped single crystals Y3Al5O12, YLiF4, and LaMgAl11O19," Phys. Rev. B 51, 784-799 (1995). [CrossRef]
  6. T. Chuang and H. R. Verdún, "Energy-transfer up-conversion and excited state absorption of laser radiation in Nd-YLF crystals," IEEE J. Quantum Electron. 32, 79-91 (1996). [CrossRef]
  7. R. M. McFarlane, F. Fong, A. J. Silversmith, and W. Lenth, "Violet cw neodymium upconversion laser," Appl. Phys. Lett. 521300-1302 (1988) [CrossRef]
  8. R. Balda, M. Sanz, A. Mendioroz, J. Fernández, L. S. Griscom, and J. L. Adam, "Infrared-to-visible upconversion in Nd3+-doped chalcohalide glasses," Phys. Rev. B 64,14410111-1441018 (2001). [CrossRef]
  9. M. C. Nostrand, R. H. Page, S. A. Payne, W. F. Krupke, P. G. Schunemann, and L. I. Isaenko, "Spectroscopic data for infrared transitions in CaGa2S4:Dy3+ and KPb2Cl5: Dy3+," OSA TOPS 19, 524-528, 1998.
  10. L. I. Isaenko, A. P. Yelisseyev, V. A. Nadolinny, V. I. Pashkov, M. C. Nostrand, R. H. Page, S. A. Payne, and R. Solarz, "Spectroscopic investigation of rare-earth doped chloride single crystals for telecommunication amplifiers," in Solid State Lasers VII, R. Scheps, ed, Proc. SPIE 3265, 242-249 (1998). [CrossRef]
  11. M. C. Nostrand, R. H. Page, S.A. Payne, W. F. Krupke, P. G. Schunemann, and L. I. Isaenko," Room temperature CaGa2S4:Dy3+ laser action at 2.43 and 4.31 μm and KPb2Cl5: Dy3+ laser action at 2.43 μm," OSA TOPS 26, 441-449, 1999.
  12. R. Balda, J. Fernández, A. Mendioroz, M. Voda, and M. Al-Saleh, "Infrared-to-visible upconversion processes in Pr3+/Yb3+-codoped KPb2Cl5," Phys. Rev. B 68,1651011-16510172003. [CrossRef]
  13. R. Balda, A. J. Garcia-Adeva, M. Voda, and J. Fernández, "Upconversion processes in Er3+-doped KPb2Cl5," Phys. Rev. B 69, 2052031-2052038 (2004). [CrossRef]
  14. A. Mendioroz, R. Balda, M. Voda, M. Al-Saleh, J. Fernández, "Origin of the infrared to visible upconversion mechanisms in Nd3+-doped potassium lead chloride crystal," Opt. Mater 27, 1704-1710 (2005). [CrossRef]
  15. K. Rademaker, W. F. Krupke, R. H. Page, S. A. Payne, K. Petermann, G. Huber, A. P. Yelisseyev, L. I. Isaenko, U. N. Roy, A. Burger, K. C. Mandal, and K. Nitsch, "Optical properties of Nd3+ and Tb3+-doped KPb2Br5 and RbPb2Br5 with low nonradiative decay," J. Opt. Soc. Am. B 21, 2117-2129 (2004). [CrossRef]
  16. H. P. Beck, G. Clicqué, and H. Nau, "A Study on AB2X5 Compounds (A: K, In, Tl; B: Sr, Sn, Pb; X: Cl, Br, I)," Z. Anorg. Allg. Chem 536, 35-44 (1986). [CrossRef]
  17. A. J. García-Adeva, R. Balda, J. Fernández, E. E. Nyein, and U. Hömmerich, "Dynamics of the infrared-to-visible upconversion in an Er3+-doped KPb2Br5 crystal," Phys. Rev. B 72, 1651161-16511611 (2005). [CrossRef]
  18. C. Cascales, R. Balda, and J. Fernández, "Investigation of site-selective symmetries of Eu3+ ions in KPb2Cl5 by using optical spectroscopy," Opt. Express 13, 2141-2152 (2005). [CrossRef] [PubMed]
  19. K. Rademaker, E. Heumann, G. Huber, S. A. Payne, W. Krupke, L.I. Isaenko, and A. Burger, "Laser activity at 1.18, 1.07, and 0.97 μm in the low-phonon-energy hosts KPb2Br5 and RbPb2Br5 doped with Nd3+," Opt. Lett. 30, 729-731 (2005). [CrossRef] [PubMed]
  20. F. Auzel, "Materials and devices using double-pumped phosphors with energy transfer," Proc. IEEE 61,758-7861973. [CrossRef]
  21. J. C. Wright, "Up-conversion and excited state energy transfer in rare earth doped materials," in Radiationless processes in molecules and condensed phases, F. K. Fong, ed. (Springer-Verlag, Heidelberg, 1976), pp. 239-295.

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