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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 15, Iss. 25 — Dec. 10, 2007
  • pp: 16681–16689

Facile collection of two-dimensional electronic spectra using femtosecond pulse-shaping technology

Erik M. Grumstrup, Sang-Hee Shim, Matthew A. Montgomery, Niels H. Damrauer, and Martin T. Zanni  »View Author Affiliations

Optics Express, Vol. 15, Issue 25, pp. 16681-16689 (2007)

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This letter reports a straightforward means of collecting two-dimensional electronic (2D-E) spectra using optical tools common to many research groups involved in ultrafast spectroscopy and quantum control. In our method a femtosecond pulse shaper is used to generate a pair of phase stable collinear laser pulses which are then incident on a gas or liquid sample. The pulse pair is followed by an ultrashort probe pulse that is spectrally resolved. The delay between the collinear pulses is incremented using phase and amplitude shaping and a 2D-E spectrum is generated following Fourier transformation. The partially collinear beam geometry results in perfectly phased absorptive spectra without phase twist. Our approach is much simpler to implement than standard non-collinear beam geometries, which are challenging to phase stabilize and require complicated calibrations. Using pulse shaping, many new experiments are now also possible in both 2D-E spectroscopy and coherent control.

© 2007 Optical Society of America

OCIS Codes
(300.6530) Spectroscopy : Spectroscopy, ultrafast
(320.5540) Ultrafast optics : Pulse shaping

ToC Category:

Original Manuscript: October 22, 2007
Revised Manuscript: November 21, 2007
Manuscript Accepted: November 21, 2007
Published: November 30, 2007

Erik M. Grumstrup, Sang-Hee Shim, Matthew A. Montgomery, Niels H. Damrauer, and Martin T. Zanni, "Facile collection of two-dimensional electronic spectra using femtosecond pulse-shaping Technology," Opt. Express 15, 16681-16689 (2007)

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