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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 15, Iss. 4 — Feb. 19, 2007
  • pp: 1718–1731

Z-scan study of thermal nonlinearities in silicon naphthalocyanine-toluene solution with the excitations of the picosecond pulse train and nanosecond pulse

Sidney S. Yang, Tai-Huei Wei, Tzer-Hsiang Huang, and Yun-Ching Chang  »View Author Affiliations


Optics Express, Vol. 15, Issue 4, pp. 1718-1731 (2007)
http://dx.doi.org/10.1364/OE.15.001718


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Abstract

Using the Z-scan technique, we studied the nonlinear absorption and refraction behaviors of a dilute toluene solution of a silicon naphthalocyanine (Si(OSi(n-hexyl)3)2, SiNc) at 532 nanometer with both a 2.8-nanosecond pulse and a 21-nanosecond (HW1/eM) pulse train containing 11 18-picosecond pulses 7 nanosecond apart. A thermal acoustic model and its steady-state approximation account for the heat generated by the nonradiative relaxations subsequent to the absorption. We found that when the steady-state approximation satisfactorily explained the results obtained with a 21-nanosecond pulse train, only the thermal-acoustic model fit the 2.8-nanosecond experimental results, which supports the approximation criterion established by Kovsh et al.

© 2007 Optical Society of America

OCIS Codes
(000.6850) General : Thermodynamics
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials
(190.4870) Nonlinear optics : Photothermal effects

ToC Category:
Nonlinear Optics

History
Original Manuscript: November 21, 2006
Revised Manuscript: January 26, 2007
Manuscript Accepted: January 29, 2007
Published: February 19, 2007

Citation
Sidney S. Yang, Tai-Huei Wei, Tzer-Hsiang Huang, and Yun-Ching Chang, "Z-scan study of thermal nonlinearities in silicon naphthalocyanine-toluene solution with the excitations of the picosecond pulse train and nanosecond pulse," Opt. Express 15, 1718-1731 (2007)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-15-4-1718


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References

  1. J. W. Perry, L. R. Khundkar, D. L. Coulter, D. Alvarez, Jr., S. R. Marder, T. H. Wei, M. J. Sence, E. W. Van Stryland, and D. J. Hagan, in Organic Molecules for Nonlinear Optics and Photonics, NATO ASI Series E, J. Messier, F. Kajzar, and P. Prasad, eds, (Kluwer, Dordrecht, 1991), Vol. 194, pp. 369-382.
  2. J. S. Shirk, J. R. Lindle, F. J. Bartoli, C. A. Hoffman, A. H. Kafafi, and A. W. Snow, "Off-resonat third-order optical nonlinearities of meta-substituted phthalocyanines," Appl. Phys. Lett. 55, 1287-1288 (1989). [CrossRef]
  3. T. H. Wei, D. J. Hagan, M. J. Sence, E. W. V. Stryland, J. W. Perry, and D. R. Coulter, "Direct measurements of nonlinear absorption and refraction in solutions of phthalocyanines," Appl. Phys. B 54, 46-51 (1992). [CrossRef]
  4. A. A. Said, T. Xia, D. J. Hagan, A. Wajsgrus. S. Yang, D. Kovsh and E. W. Van Stryland, in Conference on Nonlinear Optical Liquids, Proc. SPIE-2853, (1996).
  5. J. W. Perry, K. Mansour, J. Y. S. Lee, X. L. Xu, P.V. Bedwhorth, C. T. Chen, D. Ng, S. R. Marder, P. Miles, T. Wada,M. Tian, and H. Sasabe, "Organic optical limiter with a strong nonlinear absorptive response," Science 23, 1533-1536 (1996). [CrossRef]
  6. S. R. Mishra, H. S. Rawat, M. P. Joshi and S. C. Mehendale, "The role of non-linear scattering in optical limiting in C60 solution," J. Phys. B:At. Mol. Phys. 27, 157-163, (1994). [CrossRef]
  7. T. Tomiyama, I. Watanabe, A. Kuwano,M. Habiro, N. Takane, andM. Yamada, "Rewritable optical-disk fabrication with an optical recording material made of naphthalocyanine and polythiophene," Appl. Opt. 34, 8201-8208 (1995). [CrossRef] [PubMed]
  8. J. Seto, S. Tamura, N. Asai, N. Kishii, Y. Kijima, and N. Matsuzawa, "Macrocyclic functional dyes: Applications to optical disk media, photochemical hole burning and non-linear optics," Pure and Appl. Chem. 68, 1429-1434 (1996). [CrossRef]
  9. D. I. Kovsh, S. Yang, D. J. Hagan, and E. W. Van Stryland, "Nonlinear optical beam propagation for optical limiting," Appl. Opt. 38, 5168-5180 (1999). [CrossRef]
  10. P. Brochard and V. Grolier-Mazza, "Thermal nonlinear refraction in dye solution: a study of the transient regime," J. Opt. Soc. Am. B 14, 405-414 (1997). [CrossRef]
  11. M. Sheik-Bahae, A. A. Said, T. H. Wei, D. J. Hagan, and E. W. Van Stryland, "Sensitive measurement of optical nonlinearities using a single beam," IEEE J. Quantum Electron. 26, 760-769 (1990). [CrossRef]
  12. D. G. Mclean, R. L. Sutherland, M. C. Brant, D. M. Brandelik, P. A. Fleitz, T. Pottenger. "Nonlinear absorption study of a C60-toluene solution," Opt. Lett. 18, 858-860 (1993). [CrossRef] [PubMed]
  13. T. H. Wei, T. H. Huang, S. Yang, D. Liu, J. K. Hu and C. W. Chen, "Z-scan study of optical nonlinearity in C60-toluene solution," Mol. Phys. 103, 1847-1857 (2005).
  14. T. H. Wei and T. H. Huang, "A study of photophysics using the Z-scan technique: lifetime determination for high-lying excited states," Opt. and Quantum Electron. 28, 1495-1508 (1996). [CrossRef]
  15. A. Seilmeier and W. Kaiser, in Ultrashort Laser Pulses 2nd ed., W. Kaiser, eds. (Springer-Verlag, Berlin, 1993), pp. 305.
  16. J. H. Brannon and D. Madge, "Picosecond laser Photophysics. group 3A phthalocyanines," J. Am. Chem. Soc. 102, 62-65 (1980). [CrossRef]
  17. C. Jensen, in High Power Dye Lasers, F. J. Durate, eds. (Springer-Verlag, Berlin, 1991), pp. 48.
  18. C. Li, L. Zhang, M. Yang, H. Wang, and Y. Wang, "Dynamic and steady-state behaviors of reverse satura absorption in metallophthalocyanines," Phys. Rev. A 49, 1149-1157 (1994). [CrossRef] [PubMed]
  19. T. H. Wei, T. H. Huang, and M. S. Lin, "Signs of nonlinear refraction in chloroaluminum phthalocyanine solution," Appl. Phys. Lett. 72, 2505-2507 (1998). [CrossRef]
  20. D. R. Lide. in CRC Handbook of Chemistry and Physics, 77th ed., D. R. Lide and et al, eds. (CRC Press, Boca Raton, 1996), pp. 6-128.
  21. D. I. Kovsh, D. J. Hagan, and E.W. Stryland, "Numerical modeling of thermal refraction in liquids in the transient regime," Opt. Express 4, 315-327 (1999). [CrossRef] [PubMed]
  22. D. Landau and E. M. Lifshitz, in Course of theoretical physics (Pergamon Press), Vol. 6.
  23. J. -M. Heritier, "Electrostrictive limit and focusing effects in pulsed photoacoustic detection," Opt. Comm. 44, 267-272 (1983). [CrossRef]
  24. C. W. Chang, M. S. thesis, National Chung Cheng University, pp. 28, (1999).

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