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Optics Express

Optics Express

  • Editor: C. Martijin de Sterke
  • Vol. 15, Iss. 9 — Apr. 30, 2007
  • pp: 5730–5741

A quantum chemical approach to the design of chiral negative index materials

Alexander Baev, Marek Samoc, Paras N. Prasad, Mykhaylo Krykunov, and Jochen Autschbach  »View Author Affiliations

Optics Express, Vol. 15, Issue 9, pp. 5730-5741 (2007)

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This paper presents methodology developed for the computational modeling and design of negative refractive index materials (NIMs) based on molecular chirality. An application of the methodology is illustrated by ab initio computations on two organometallic molecules which constitute the monomer units of a chiral polymer. Comparisons with experimental data for the polymer are made. Even though the resulting chirality parameter for the pristine material is small, it is shown that negative index can be achieved by introducing sharp plasmonic resonances with metal nanoparticle inclusions.

© 2007 Optical Society of America

OCIS Codes
(160.5470) Materials : Polymers

ToC Category:

Original Manuscript: January 5, 2007
Revised Manuscript: April 17, 2007
Manuscript Accepted: April 17, 2007
Published: April 25, 2007

Alexander Baev, Marek Samoc, Paras N. Prasad, Mykhaylo Krykunov, and Jochen Autschbach, "A quantum chemical approach to the design of chiral negative index materials," Opt. Express 15, 5730-5741 (2007)

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