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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 16, Iss. 23 — Nov. 10, 2008
  • pp: 19232–19243

High-resolution Fourier-transform cavity-enhanced absorption spectroscopy in the near-infrared using an incoherent broad-band light source

Johannes Orphal and Albert A. Ruth  »View Author Affiliations


Optics Express, Vol. 16, Issue 23, pp. 19232-19243 (2008)
http://dx.doi.org/10.1364/OE.16.019232


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Abstract

An incoherent broad-band cavity-enhanced absorption (IBB-CEA) set-up was used in combination with a Fourier-transform (FT) spectrometer in order to explore the potential of this technique for high-resolution molecular spectroscopy in the near-infrared region. Absorption spectra of overtone bands of CO2, OCS, and HD18O were measured between 5800 and 7000 cm−1 using a small sampling volume (1100 cm3, based on a 90 cm cavity length). The quality of the spectra in this study is comparable to that obtained with Fourier transform spectrometers employing standard multi-pass reflection cells, which require substantially larger sampling volumes. High-resolution methods such as FT-IBB-CEAS also provide an elegant way to determine effective mirror reflectivities (Reff, i.e. a measure of the inherent overall cavity loss) by using a calibration gas with well-known line strengths. For narrow absorption features and non-congested spectra this approach does not even require a zero-absorption measurement with the empty cavity. Absolute cross-sections or line strengths of a target species can also be determined in one single measurement, if gas mixtures with known partial pressures are used. This feature of FT-IBB-CEAS reduces systematic errors significantly; it is illustrated based on CO2 as calibration gas.

© 2008 Optical Society of America

OCIS Codes
(010.1280) Atmospheric and oceanic optics : Atmospheric composition
(120.6200) Instrumentation, measurement, and metrology : Spectrometers and spectroscopic instrumentation
(300.1030) Spectroscopy : Absorption
(300.6300) Spectroscopy : Spectroscopy, Fourier transforms
(300.6390) Spectroscopy : Spectroscopy, molecular
(350.5730) Other areas of optics : Resolution

ToC Category:
Spectroscopy

History
Original Manuscript: September 19, 2008
Revised Manuscript: November 1, 2008
Manuscript Accepted: November 3, 2008
Published: November 5, 2008

Citation
Johannes Orphal and Albert A. Ruth, "High-resolution Fourier-transform cavity-enhanced absorption spectroscopy in the near-infrared using an incoherent broad-band light source," Opt. Express 16, 19232-19243 (2008)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-16-23-19232


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