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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 16, Iss. 23 — Nov. 10, 2008
  • pp: 19244–19252

One photon nonresonant high-order nonlinear optical properties of silver nanoparticles in aqueous solution

Diego Rativa, R. E. de Araujo, and A. S. L. Gomes  »View Author Affiliations


Optics Express, Vol. 16, Issue 23, pp. 19244-19252 (2008)
http://dx.doi.org/10.1364/OE.16.019244


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Abstract

In this work we determine the third, fifth- and seventh-order nonresonant nonlinear optical properties of silver nanoparticles (9nm average diameter) colloids in aqueous solution under high intensity excitation. The nonlinear optical response and its dependence with the nanoparticles filling factor was measured and theoretically described. We show that for low inclusion concentration, the third order nonlinearity of the colloid can be described by the generalized Maxwell-Garnett model. With the increase of the nanoparticle concentration, changes in the medium nonlinearities was observed leading to high order effects. The fifth- and seventh- order susceptibilities were obtained for highly concentrated silver nanoparticle colloid and the data was supported by a theoretical model. The conventional Z-scan technique was employed, using 80 f s laser pulses at 800nm, in a regime of high pulse energy (µJ) and low repetition rate (1kHz).

© 2008 Optical Society of America

OCIS Codes
(190.4720) Nonlinear optics : Optical nonlinearities of condensed matter
(190.7110) Nonlinear optics : Ultrafast nonlinear optics

ToC Category:
Nonlinear Optics

History
Original Manuscript: October 2, 2008
Revised Manuscript: November 3, 2008
Manuscript Accepted: November 4, 2008
Published: November 5, 2008

Citation
Diego Rativa, R. E. de Araujo, and A. S. Gomes, "One photon nonresonant high-order nonlinear optical properties of silver nanoparticles in aqueous solution.," Opt. Express 16, 19244-19252 (2008)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-16-23-19244


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References

  1. J. R. Lakowicz, "Plasmonics in Biology and Plasmon-controlled Fluorescence," Plasmonics 1, 5-33 (2006). [CrossRef] [PubMed]
  2. D. Rativa, A. S. L. Gomes, S. Wachsmann-Hogiu, D. L. Farkas, and R. E. de Araujo, "Nonlinear Excitation of Tryptophan Emission Enhanced by Silver Nanoparticles," J. Fluoresc. DOI. 10.1007/s10895-008-0366-6, (2008).
  3. D. Yelin, D. Oron, S. Thiberge, E. Moses, and Y. Silberberg, "Multiphoton plasmon-resonance microscopy," Opt. Express 11, 1385-1391 (2003). [CrossRef] [PubMed]
  4. C. Wang, Y. Fu, Z. Zhou, Y. Cheng, and Z. Xu, "Femtosecond filamentation and supercontinuum generation in silver-nanoparticle-doped water,"Appl. Phys. Lett. 90, 181119, 1-4 (2007).
  5. E. L. Falcão-Filho, CidB. de Araújo, A. Galembeck, M. M. Oliveira, and A. J. G. Zarbin, "Nonlinear susceptibility of colloids consisting of silver nanoparticles in carbon dissulfide,"J. Opt. Soc. Am. B 22, 2444-2449 (2005). [CrossRef]
  6. M. H. G. Miranda, E. L. Falcão-Filho, J. J. RodriguesJr, CidB. de Araújo, and L. H. Acioli, "Ultrafast lightinduced dichroism in silver nanoparticles,"Phys. Rev. B 70, 161401-161404 (2006). [CrossRef]
  7. R. A. Ganeev, M. Baba, A. I. Ryasnyansky, M. Suzuki, and H. Kuroda,"Characterization of optical and nonlinear silver nanoparticles prepared by laser ablation in various liquids,"Opt. Commun. 240, 437-448 (2004). [CrossRef]
  8. R. A. Ganeev and A. I. Ryasnyansky, "Nonlinear optical characteristics of nanoparticles in suspensions and solid matrices,"Appl. Phys. B 84, 295-302 (2006). [CrossRef]
  9. J. Jayabalan, A. Singh, R. Chari, and S. M. Oak, "Ultrafast third-order nonlinearity of silver nanospheres and nanodiscs,"Nanotechnology 18, 315704-315710 (2007). [CrossRef]
  10. D. Rativa, R. E. de Araujo, and A. S. L. Gomes, "Non resonant third-order nonlinearity of nanometric and subnanometric silver particles in aqueous solution," J. Nanosci. Nanotechnol DOI. 10.1166/jnn.2008.416, (2008).
  11. E. L. Falcão-Filho, C. B. de Araújo, and J. J. Rodrigues, Jr., "High-order nonlinearities of aqueous colloids containing silver nanoparticles," J. Opt. Soc. Am. B 24, 2948-2956 (2007). [CrossRef]
  12. P. C. Lee and D. Meisel,"Adsorption and surface-enhanced Raman of dyes on silver and gold sols," J. Phys. Chem. 86, 3391-3395 (1982). [CrossRef]
  13. M. Sheik-Bahae, A. A. Said, T. H. Wei, D. J. Hagan, and E.W. Van Stryland,"Sensitive measurements of optical nonlinearities using a single beam,"Quantum Electron. 26, 760-769 (1990). [CrossRef]
  14. P. B. Johnson and R. W. Christy, "Optical constants of noble metals,"Phys. Rev. B,  6, 4370-4379 (1972). [CrossRef]
  15. G. Mie,"Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen,"Leipzig, Ann. Phys. 330, 377-445 (1908). [CrossRef]
  16. W. C. Huang and L. J. Tzeng,"Quantum size effect on the optical properties of small metallic particles,"Phys. Rev. B. 49, 17279-17285 (1994). [CrossRef]
  17. J. E. Sipe and R. W. Boyd, "Nonlinear susceptibility of composite optical materials in the Maxwell Garnett model," Phys. Rev. A 46, 1614-1629 (1992). [CrossRef] [PubMed]
  18. Y. Hamanaka, A. Nakamura, N. Hayashi, and S. Omi, "Dispersion curves of complex third-order optical susceptibilities around the surface plasmon resonance in Ag nanocrystal glass composites," J. Opt. Soc. Am. B 20, 1227-1232 (2003). [CrossRef]
  19. A. A. Said, M. Sheik-Bahae, D. J. Hagan, T. H. Wei, J. Wang, J. Young, and E. W Van Stryland, "Determination of bound-electronic and free-carrier nonlinearities in ZnSe, GaAs, CdTe, and ZnTe," J. Opt. Soc. Am. B. 9, 405-414 (1992). [CrossRef]
  20. N. C. Kothari, "Effective-medium theory of a nonlinear composite medium using the T-matrix approach: Exact results for spherical grains," Phys. Rev. A 41, 4486-4492 (1990). [CrossRef] [PubMed]
  21. D. Marquardt, "An Algorithm for Least-Squares Estimation of Nonlinear Parameters," J. Appl. Math 11, 431-441 (1963).

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