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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 16, Iss. 3 — Feb. 4, 2008
  • pp: 1529–1545

Substrate-enhanced infrared near-field spectroscopy

Javier Aizpurua, Thomas Taubner, F. Javier García de Abajo, Markus Brehm, and Rainer Hillenbrand  »View Author Affiliations


Optics Express, Vol. 16, Issue 3, pp. 1529-1545 (2008)
http://dx.doi.org/10.1364/OE.16.001529


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Abstract

We study the amplitude and phase signals detected in infrared scattering-type near field optical microscopy (s-SNOM) when probing a thin sample layer on a substrate. We theoretically describe this situation by solving the electromagnetic scattering of a dipole near a planar sample consisting of a substrate covered by thin layers. We perform calculations to describe the effect of both weakly (Si and SiO2) and strongly (Au) reflecting substrates on the spectral s-SNOM signal of a thin PMMA layer. We theoretically predict, and experimentally confirm an enhancement effect in the polymer vibrational spectrum when placed on strongly reflecting substrates. We also calculate the scattered fields for a resonant tip-substrate interaction, obtaining a dramatic enhancement of the signal amplitude and spectroscopic contrast of the sample layer, together with a change of the spectral line shape. The enhanced contrast opens the possibility to perform ultra-sensitive near field infrared spectroscopy of monolayers and biomolecules.

© 2008 Optical Society of America

OCIS Codes
(240.6490) Optics at surfaces : Spectroscopy, surface
(300.6340) Spectroscopy : Spectroscopy, infrared
(180.4243) Microscopy : Near-field microscopy
(290.5825) Scattering : Scattering theory

ToC Category:
Microscopy

History
Original Manuscript: November 21, 2007
Revised Manuscript: January 16, 2008
Manuscript Accepted: January 17, 2008
Published: January 22, 2008

Virtual Issues
Vol. 3, Iss. 3 Virtual Journal for Biomedical Optics

Citation
Javier Aizpurua, Thomas Taubner, F. Javier García de Abajo, Markus Brehm, and Rainer Hillenbrand, "Substrate-enhanced infrared near-field spectroscopy," Opt. Express 16, 1529-1545 (2008)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-16-3-1529


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References

  1. Y. Inouye, and S. Kawata, "Near-field scanning optical microscope with a metallic probe tip," Opt. Lett. 19,159-161 (1994). [CrossRef] [PubMed]
  2. F. Zenhausern, Y. Martin, and H. K. Wickramasinghe, "Scanning Interferometric Apertureless Microscopy: Optical Imaging at 10 Angstrom Resolution," Science 269,1083-1085 (1995). [CrossRef] [PubMed]
  3. R. Hillenbrand, and F. Keilmann, "Complex optical constants on a subwavelength scale," Phys. Rev. Lett. 85,3029-3032 (2000). [CrossRef] [PubMed]
  4. R. Bachelot, G. Lerondel, S. Blaize, S. Aubert, A. Bruyant, P. Royer, "Probing photonic and optoelectronic structures by apertureless scanning near-field optical microscopy," Microsc. Res. Tech. 64,441-452 (2004). [CrossRef] [PubMed]
  5. N. Anderson, A. Bouhelier, and L. Novotny, "Near-field photonics: tip-enhanced microscopy and spectroscopy on the nanoscale," J. Opt. A 8,S227-S233 (2006). [CrossRef]
  6. Z. H. Kim, and S. R. Leone, "High-resolution apertureless near-field optical imaging using gold nanosphere probes," J. Phys. Chem. B 110,19804-19809 (2006) [CrossRef] [PubMed]
  7. A. Lahrech, R. Bachelot, P. Gleyzes, and A. C. Boccara, "Infrared-reflection-mode near-field microscopy using an apertureless probe with a resolution of lambda / 600," Opt. Lett. 21,1315-1317 (1995). [CrossRef]
  8. B. Knoll, and F. Keilmann, "Near-field probing of vibrational absorption for chemical microscopy," Nature 399,134-137 (1999). [CrossRef]
  9. B. B. Akhremitchev, and G. C. Walker, "Apertureless Scanning Near-Field Infrared Microscopy of Rough Polymeric Surface," Langmuir. 17,2774-2781 (2001). [CrossRef]
  10. I. Kopf, J. S. Samson, G. Wollny, C. Grunwald, E. Brundermann, and M. Havenith, "Chemical imaging of microstructured self-assembled monolayers with nanometer resolution," J. Phys. Chem. C 111,8166-8171 (2007). [CrossRef]
  11. M.B. Raschke, L. Molina, T. Elsaesser, D.H. Kim,W. Knoll, and K. Hinrichs, "Apertureless near-field vibrational imaging of block-copolymer nanostructures with ultrahigh spatial resolution," ChemPhysChem 6, 2197-2203 (2005). [CrossRef] [PubMed]
  12. A. Huber, D. Kazantsev, F. Keilmann, J. Wittborn, and R. Hillenbrand, "Simultaneous infrared material recognition and conductivity mapping by nanoscale near-field microscopy," Adv. Mater. 19,2209-2212 (2007). [CrossRef]
  13. T. Taubner, D. Korobkin, Y. Urzhumov, G. Shvets, and R. Hillenbrand, "Near-field Microscopy Through a SiC Superlens," Science 313,1595-1595 (2006). [CrossRef] [PubMed]
  14. A. Cvitkovic, N. Ocelic, J. Aizpurua, R. Guckenberger, and R. Hillenbrand, "Infrared Imaging of Single Nanoparticles via Strong Field Enhancement in a Scanning Nanogap," Phys. Rev. Lett. 97,060801 (2006). [CrossRef] [PubMed]
  15. A. Cvitkovic, N. Ocelic, and R. Hillenbrand, "Material-specific optical recognition of sub-10 nm particles by substrate-enhanced scattering-type near-field microscopy," Nano Lett. 7,3177-3181 (2007). [CrossRef] [PubMed]
  16. T. Taubner, R. Hillenbrand, and F. Keilmann, "Nanoscale polymer identification by spectral signature in scattering infrared near-field microscopy," Appl. Phys. Lett. 85,5064-5066 (2004). [CrossRef]
  17. M. Brehm, T. Taubner, R. Hillenbrand, and F. Keilmann, "Infrared Spectroscopic Mapping of Single Nanoparticles and Viruses at Nanoscale Resolution," Nanoletters 6,1307-1310 (2006). [CrossRef]
  18. T. Taubner, R. Hillenbrand, and F. Keilmann, "Performance of visible and mid-infrared scattering-type near-field optical microscopes," J. Microsc. 210,311-314 (2003). [CrossRef] [PubMed]
  19. J. A. Porto, P. Johansson, S. P. Apell, and T. Lopez-Rios, "Resonance shift effects in apertureless scanning near-field optical microscopy," Phys. Rev. B. 67, 085409 (2003). [CrossRef]
  20. R. M. Roth, N. C. Panoiu, M. M. Adams, R. M. Osgood, C. C. Neacsu, and M. B. Raschke, "Resonant-plasmon field enhancement from asymmetrically illuminated conical metallic-probe tips," Opt. Express 14,2921-2931 (2006). [CrossRef] [PubMed]
  21. R. Esteban, R. Vogelgesang, and K. Kern, "Simulation of optical near and far fields of dielectric apertureless scanning probe," Nanotechnology 17,475-482 (2006). [CrossRef]
  22. R. Esteban, R. Vogelgesang, and K. Kern, "Tip-substrate interaction in optical near-field microscopy," Phys. Rev. B 75,195410 (2007). [CrossRef]
  23. F. Keilmann, and R. Hillenbrand, "Near-field optical microscopy by elastic light scattering from a tip," Phil. Trans. Roy. Soc. A 362, 787-805 (2004). [CrossRef]
  24. V. Romanov, and G. C. Walker, "Infrared near-field detection of a narrow resonance due to molecular vibrations in a nanoparticle," Langmuir 23,2829-2837 (2007). [CrossRef] [PubMed]
  25. R. Hillenbrand, T. Taubner, and F. Keilmann, "Phonon-enhanced light-matter interaction at the nanometer scale," Nature 418,159-162 (2002). [CrossRef] [PubMed]
  26. T. Taubner, F. Keilmann, and R. Hillenbrand, "Nanomechanical resonance tuning and phase effects in optical near-field interaction," Nano Lett. 4,1669-1672 (2004). [CrossRef]
  27. M. B. Raschke and C. Lienau, "Apertureless near-field optical microscopy: Tip-sample coupling in elastic light scattering," Appl. Phys. Lett. 83,5089-5091 (2003). [CrossRef]
  28. T. Taubner, F. Keilmann, and R. Hillenbrand, "Nanoscale-resolved subsurface imaging by scattering-type near-field optical microscopy," Opt. Express 13,8893-8899 (2005). [CrossRef] [PubMed]
  29. N. Anderson, P. Anger, A. Hartschuh, and L. Novotny, "Subsurface Raman imaging with nanoscale resolution," Nano Lett. 6,744-749 (2006). [CrossRef] [PubMed]
  30. G. Y. Panasyuk, V. A. Markel, P. S. Carney, and J. C. Schotland, "Nonlinear inverse scattering and threedimensional near-field optical imaging," Appl. Phys. Lett. 89,221116 (2006). [CrossRef]
  31. E.G. Bortchagovsky, and U. C. Fischer, "On the modulation of optical transmission spectra of thin dye layers by a supporting medium," J. Chem. Phys. 117,5384-5392 (2002). [CrossRef]
  32. S. G. Moiseev, and S. V. Sukhov, "Near-Field optical microscopy in the presence of an intermediate layer," Opt. Spectrosc. 98,308-313 (2005). [CrossRef]
  33. M. Brehm, "Infrarot-Mikrospektroskopie mit einem Nahfeldmikroskop," PhD. Thesis 2006, TU Mnchen, Verlag Dr. Hut, ISBN 978-3-89963-482-2.
  34. N. Ocelic, A. Huber, and R. Hillenbrand, "Pseudoheterodyne detection for background-free near-field spectroscopy," App. Phys. Lett. 89,101124 (2006). [CrossRef]
  35. H. Weyl, "Ausbreitung elektromagnetischer Wellen uber einem ebenen Leiter," Ann. Phys. (Leipzig) 60,481-500 (1919). [CrossRef]
  36. G. W. Ford and W. H. Weber, "Electromagnetic interactions of molecules with metal surfaces," Phys. Rep. 113,195-287 (1984). [CrossRef]
  37. F. J. García de Abajo, "Light scattering by particle and hole arrays," Rev. Mod. Phys. 79,1267-1290 (2007). [CrossRef]
  38. E. D. Palik, "Handbook of optical constants of solids," Academic, New York, (1985).
  39. U. Fano, "Effects of Configuration Interaction on Intensities and Phase Shifts," Phys. Rev. B 124,1866-1878 (1961). [CrossRef]
  40. B.B. Akhremitchev, Y.J. Sun, L. Stebounova, and G.C. Walker, "Monolayer-sensitive infrared imaging of DNA stripes using apertureless near-field microscopy," Langmuir 18,5325-5328 (2002). [CrossRef]
  41. F. Neubrech, T. Kolb, R. Lovrincic, G. Fahsold, A. Pucci, J. Aizpurua, T. W. Cornelius, M. E. Toimil-Molares, R. Neumann, and S. Karim, "Resonances of individual metal nanowires in the infrared," Appl. Phys. Lett. 89,253104 (2006). [CrossRef]
  42. K.R. Rodriguez, H. Tian, J.M. Heer, S. Teeters-Kennedy, and J.V. Coe, "Interaction of an infrared surface plasmon with an excited molecular vibration," J. Chem. Phys. 126,151101 (2007). [CrossRef] [PubMed]
  43. H. Wang, J. Kundu, and N. J. Halas, "Plasmonic Nanoshell Arrays Combine Surface-Enhanced Vibrational Spectroscopies on a Single Substrate," Angew. Chem. 46,9040-9044 (2007). [CrossRef]
  44. A. V. Zayats, "Electromagnetic field enhancement in the context of apertureless near-field microscopy," Opt. Comm. 161,156-162 (1999). [CrossRef]
  45. A. Christ, Y. Ekinci, H. H. Solak, N. A. Gippius, S. G. Tikhodeev, and O. J. F. Martin, "Controlling the Fano interference in a plasmonic lattice," Phys. Rev. B 76, 201405(R) (2007). [CrossRef]
  46. U. C. Fischer, "Latex Projections Patterns, in Procedures in Scanning Probe Microscopy," Editors: R.J. Colton, et al., John Wiley & Sons. 10-11 (1998).
  47. T. R. Jensen, M. D. Malinsky, C. L. Haynes, and R. P. Van Duyne, "Nanosphere lithography: Tunable Localised Surface Plasmon Resonance Spectra of Silver Nanoparticles," J. Phys. Chem. B 104,10549-10556 (2000). [CrossRef]
  48. M.S. Anderson, "Enhanced infrared absorption with dielectric nanoparticles," Appl. Phys. Lett. 83,2964-2966 (2003). [CrossRef]
  49. F. Neubrech, A. Pucci, T. W. Cornelius, and S. Karim, A. Garcia-Etxarri, and J. Aizpurua, "Giant vibrational signals from molecules by the action of a tailored infrared nanoantenna," in preparation.

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