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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 17, Iss. 16 — Aug. 3, 2009
  • pp: 13298–13308

Engineering SERS via absorption control in novel hybrid Ni/Au nanovoids

Robin M. Cole, Sumeet Mahajan, Phil N. Bartlett, and Jeremy J. Baumberg  »View Author Affiliations


Optics Express, Vol. 17, Issue 16, pp. 13298-13308 (2009)
http://dx.doi.org/10.1364/OE.17.013298


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Abstract

Nanoscale voids (or ‘anti-nanoparticles’) embedded in gold films possess plasmon modes with a strong field component at the cavity entrance, radically different to nanoparticle plasmon modes. By creating Ni/Au hybrid rim nanostructures we show how selective coupling to void plasmons provides strong electric field enhancements leading to large surface-enhanced Raman scattering (SERS) signals from molecules adsorbed on the nanovoid film. Since the rim plasmon modes are relatively independent of the supporting void material these results pave the way for hybrid nanovoid structures which combine plasmonic and catalytic properties of the constituent materials in a controllable and reproducible way.

© 2009 Optical Society of America

OCIS Codes
(190.0190) Nonlinear optics : Nonlinear optics
(220.0220) Optical design and fabrication : Optical design and fabrication

ToC Category:
Nonlinear Optics

History
Original Manuscript: June 17, 2009
Revised Manuscript: July 8, 2009
Manuscript Accepted: July 9, 2009
Published: July 20, 2009

Citation
Robin M. Cole, Sumeet Mahajan, Phil N. Bartlett, and Jeremy J. Baumberg, "Engineering SERS via absorption control in novel hybrid Ni/Au nanovoids," Opt. Express 17, 13298-13308 (2009)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-17-16-13298


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References

  1. A. Otto, "Excitation of nonradiative surface plasma waves in silver by the method of frustrated total reflection " Z. Phys. 216, 398-410 (1968). [CrossRef]
  2. R. H. Ritchie, E. T. Arakawa, J. J. Cowan, and R. N. Hamm, "Surface-plasmon resonance effect in grating diffraction," Phys. Rev. Lett. 21, 1530 (1968). [CrossRef]
  3. T. A. Kelf, Y. Sugawara, R. M. Cole, J. J. Baumberg, M. E. Abdelsalam, S. Cintra, S. Mahajan, A. E. Russell, and P. N. Bartlett, "Localized and delocalized plasmons in metallic nanovoids," Phys. Rev. B 74 (2006). [CrossRef]
  4. L. Cui, S. Mahajan, R. M. Cole, B. Soares, P. N. Bartlett, J. J. Baumberg, I. P. Hayward, B. Ren, A. E. Russell, and Z.-Q. Tian, "UV SERS at well ordered Pd sphere segment void (SSV) nanostuctures " Phys. Chem. Chem. Phys. 11, 1023-1026 (2008). [CrossRef]
  5. S. Mahajan, M. Abdelsalam, Y. Suguwara, S. Cintra, A. Russell, J. Baumberg, and P. Bartlett, "Tuning plasmons on nano-structured substrates for NIR-SERS," Phys. Chem. Chem. Phys. 9, 104-109 (2007). [CrossRef]
  6. D. Matthias, and N. Lukas, "Optical frequency mixing at coupled gold nanoparticles," Phys. Rev. Lett. 98, 026104 (2007). [CrossRef]
  7. A. L. Demming, F. Festy, and D. Richards, "Plasmon resonances on metal tips: Understanding tip- enhanced Raman scattering," J. Chem. Phys. 122, 184716 (2005). [CrossRef] [PubMed]
  8. R. M. Stockle, Y. D. Suh, V. Deckert, and R. Zenobi, "Nanoscale chemical analysis by tip-enhanced Raman spectroscopy," Chem. Phys. Lett. 318, 131-136 (2000). [CrossRef]
  9. R. M. Cole, J. J. Baumberg, F. J. Garcia de Abajo, S. Mahajan, M. Abdelsalam, and P. N. Bartlett, "Understanding plasmons in nanoscale voids," Nano Lett. 7, 2094-2100 (2007). [CrossRef]
  10. S. Mahajan, R. M. Cole, B. Soares, S. Pelfrey, A. Russell, J. Baumberg, and P. N. Bartlett, "Relating SERS intensity to specific plasmon modes on sphere segment void surfaces," J. Phys. Chem. C 113, 9284- 9289 (2009). [CrossRef]
  11. Z.-Q. Tian, B. Ren, and D.-Y. Wu, "Surface-enhanced Raman scattering:From noble to transition metals and from rough surfaces to ordered nanostructures," J. Phys. Chem. B 106, 9463-9483 (2002). [CrossRef]
  12. B. Ren, Q. J. Huang, W. B. Cai, B. W. Mao, F. M. Liu, and Z. Q. Tian, "Surface Raman spectra of pyridine and hydrogen on bare platinum and nickel electrodes," J. Electroanal. Chem. 415, 175-178 (1996). [CrossRef]
  13. Z. Q. Tian, and B. Ren, "Adsorption and reaction at electrochemical interfaces as probed by surface- enhanced Raman spectroscopy," Ann. Rev. Phys. Chem. 55, 197-229 (2004). [CrossRef]
  14. Z.-Q. Tian, B. Ren, J.-F. Li, and Z.-L. Yang, "Expanding generality of surface-enhanced Raman spectroscopy with borrowing SERS activity strategy," Chem.l Commun.3514-3534 (2007). [CrossRef]
  15. S. Park, P. Yang, P. Corredor, and M. J. Weaver, "Transition metal-coated nanoparticle films: Vibrational characterization with Surface-enhanced Raman scattering," J. Am. Chem. Soc. 124, 2428-2429 (2002). [CrossRef] [PubMed]
  16. P. N. Bartlett, J. J. Baumberg, P. R. Birkin, M. A. Ghanem, and M. C. Netti, "Highly ordered macroporous gold and platinum films formed by electrochemical deposition through templates assembled from submicron diameter monodisperse polystyrene spheres," Chem. Mater. 14, 2199-2208 (2002). [CrossRef]
  17. P. N. Bartlett, P. R. Birkin, and M. A. Ghanem, "Electrochemical deposition of macroporous platinum, palladium and cobalt films using polystyrene latex sphere templates," Chem. Commun.1671-1672 (2000). [CrossRef]
  18. P. N. Bartlett, P. R. Birkin, M. A. Ghanem, and C.-S. Toh, "Electrochemical syntheses of highly ordered macroporous conducting polymers grown around self-assembled colloidal templates," J. Mater. Chem. 11, 849-853 (2001). [CrossRef]
  19. P. N. Bartlett, T. Dunford, and M. A. Ghanem, "Templated electrochemical deposition of nanostructured macroporous PbO2," J. Mater. Chem. 12, 3130-3135 (2002). [CrossRef]
  20. P. N. Bartlett, M. A. Ghanem, I. S. El Hallag, P. de Groot, and A. Zhukov, "Electrochemical deposition of macroporous magnetic networks using colloidal templates," J. Mater. Chem. 13, 2596-2602 (2003). [CrossRef]
  21. P. N. Bartlett, J. J. Baumberg, S. Coyle, and M. E. Abdelsalam, "Optical properties of nanostructured metal films," Faraday Discuss. 125, 117-132 (2004). [CrossRef] [PubMed]
  22. N. D. Denkov, O. D. Velev, P. A. Kralchevsky, I. B. Ivanov, H. Yoshimura, and K. Nagayama, "Mechanism of formation of two-dimensional crystals from latex particles on substrates," Langmuir 8, 3183-3190 (1992). [CrossRef]
  23. A. S. Dimitrov, and K. Nagayama, "Continuous convective assembling of fine particles into two- dimensional arrays on solid surfaces," Langmuir 12, 1303-1311 (1996). [CrossRef]
  24. P. Jiang, J. F. Bertone, K. S. Hwang, and V. L. Colvin, "Single Crystal colloidal multilayers of controlled thickness," Chem. Mater. 11, 2132-2140 (1999). [CrossRef]
  25. J. J. Baumberg, T. Kelf, Y. Sugawara, S. Cintra, M. Abdelsalam, P. N. Bartlett, and A. E. Russell, "Angle- resolved surface-enhanced Raman scattering on metallic nanostructured plasmonic crystals," Nano Lett. 5, 2262-2267 (2005). [CrossRef] [PubMed]
  26. M. Moskovits, "Surface-enhanced spectroscopy," Rev. Mod. Phys. 57 (1985). [CrossRef]
  27. M. Moskovits, "Surface-enhanced Raman spectroscopy: A brief retrospective," J. Raman Spectrosc. 36, 485-496 (2005). [CrossRef]
  28. N. M. B. Perney, F. J. G. de Abajo, J. J. Baumberg, A. Tang, M. C. Netti, M. D. B. Charlton, and M. E. Zoorob, "Tuning localized plasmon cavities for optimized surface-enhanced Raman scattering," Phys. Rev. B35426 (2007). [CrossRef]
  29. E. C. L. Ru, and P. G. Etchegoin, "Rigourous justification of the E4 enhancement factor in surface enhanced Raman spectroscopy," Chem. Phys. Lett. 423, 63-66 (2006). [CrossRef]
  30. A. Ulman, "Formation and structure of self-assembled monolayers," Chem. Rev. 96, 1533-1554 (1996). [CrossRef] [PubMed]
  31. J. C. Love, L. A. Estroff, J. K. Kriebel, R. G. Nuzzo, and G. M. Whitesides, "Self-assembled monolayers of thiolates on metals as a form of nanotechnology," Chem. Rev. 105, 1103-1169 (2005). [CrossRef] [PubMed]
  32. Z. Mekhalif, J. Riga, J. J. Pireaux, and J. Delhalle, "Self-assembled monolayers of n-dodecanethiol on electrochemically modified polycrystalline nickel surfaces," Langmuir 13, 2285-2290 (1997). [CrossRef]
  33. Z. Mekhalif, F. Laffineur, N. Couturier, and J. Delhalle, "Elaboration of self-assembled monolayers of n- alkanethiols on nickel polycrystalline substrates: time, concentration, and solvent effects," Langmuir 19, 637-645 (2003). [CrossRef]

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