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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 17, Iss. 4 — Feb. 16, 2009
  • pp: 2954–2961

Quantum-rod dispersed photopolymers for multi-dimensional photonic applications

Xiangping Li, James W. M. Chon, Richard A. Evans, and Min Gu  »View Author Affiliations


Optics Express, Vol. 17, Issue 4, pp. 2954-2961 (2009)
http://dx.doi.org/10.1364/OE.17.002954


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Abstract

Nanocrystal quantum rods (QRs) have been identified as an important potential key to future photonic devices because of their unique two-photon (2P) excitation, large 2P absorption cross section and polarization sensitivity. 2P excitation in a conventional solid photosensitive medium has driven all-optical devices towards three-dimensional (3D) platform architectures such as 3D photonic crystals, optical circuits and optical memory. The development of a QR-sensitized medium should allow for a polarization-dependent change in refractive index. Such a localized polarization control inside the focus can confine the light not only in 3D but also in additional polarization domain. Here we report on the first 2P absorption excitation of QR-dispersed photopolymers and its application to the fabrication of polarization switched waveguides, multi-dimensional optical patterning and optical memory. This fabrication was achieved by a 2P excited energy transfer process between QRs and azo dyes which facilitated 3D localized polarization sensitivity resulting in the control of light in four dimensions.

© 2009 Optical Society of America

OCIS Codes
(210.4680) Optical data storage : Optical memories
(210.4810) Optical data storage : Optical storage-recording materials
(210.1635) Optical data storage : Coding for optical storage

ToC Category:
Optical Data Storage

History
Original Manuscript: December 1, 2008
Revised Manuscript: February 10, 2009
Manuscript Accepted: February 11, 2009
Published: February 12, 2009

Citation
Xiangping Li, James W. Chon, Richard A. Evans, and Min Gu, "Quantum-rod dispersed photopolymers for multi-dimensional photonic applications," Opt. Express 17, 2954-2961 (2009)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-17-4-2954


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References

  1. S. Noda, M. Fujita, and T. Asano, "Spontaneous-emission control by photonic crystals and nanocavities," Nat. Photonics 1, 449-458 (2007). [CrossRef]
  2. K. Minoshima, A. M. Kowalevicz, I. Hartl, E. P. Ippen, and J. G. Fujimoto, "Photonic device fabrication in glass by use of nonlinear materials processing with a femtosecond laser oscillator," Opt. Lett. 26, 1516-1518 (2001). [CrossRef]
  3. D. A. Parthenopoulos, and P. M. Rentzepis, "Three-dimensional optical storage memory," Science 245, 843-845 (1989). [CrossRef] [PubMed]
  4. B. H. Cumpston, S. P. Ananthavel, S. Barlow, D. L. Dyer, J. E. Ehrlich, L. L. Erskine, A. A. Heikal, S. M. Kuebler, I.-Y. S. Lee, D. McCord-Maughon, J. Qin, H. Rockel, M. Rumi, X.-L. Wu, S. R. Marder, and J. W. Perry, "Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication," Nature 398, 51-54 (1999). [CrossRef]
  5. E. Walker, and P. M. Rentzepis, "Two-photon technology: a new dimension," Nat. Photonics 2, 406-408 (2008). [CrossRef]
  6. J. Serbin, and M. Gu, "Experimental evidence for superprism effects in three-dimensional polymer photonic crystals," Adv. Mater. 18, 221-224 (2006). [CrossRef]
  7. S. Kawata, H.-B. Sun, T. Tanaka, and K. Takada, "Finer features for functional microdevices," Nature 412, 697-698 (2001). [CrossRef] [PubMed]
  8. H. Ishitobi, Z. Sekkat, and S. Kawata, "Photo-orientation by multiphoton photoselection," J. Opt. Soc. Am. B 23, 868-873 (2006). [CrossRef]
  9. X. Li, J. W. M. Chon, S. Wu, R. A. Evans, and M. Gu, "Rewritable polarization-encoded multilayer data storage in 2,5-dimethyl-4-(p-nitrophenylazo)anisole doped polymer," Opt. Lett. 32, 277-279 (2007). [CrossRef] [PubMed]
  10. E. Rothenberg, Y. Ebenstein, M. Kazes, and U. Banin, "Two-photon fluorescence microscopy of single semiconductor quantum rods: Direct observation of highly polarized nonlinear absorption dipole," J. Phys. Chem. B. 108, 2797-2800 (2004). [CrossRef]
  11. K.-T. Yong, J. Qian, I. Roy, H. H. Lee, E. J. Bergey, K. M. Tramposch, S. He, M. T. Swihart, A. Maitra, and P. N. Prasad, "Quantum rod bioconjugates as targeted probes for confocal and two-photon fluorescence imaging of cancer cells," Nano. Lett. 7, 761-765 (2007). [CrossRef] [PubMed]
  12. A. P. Alivisatos, "Semiconductor clusters, nanocrystals, and quantum dots," Science 271, 933-937 (1996). [CrossRef]
  13. X. Peng, L. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, and A. P. Alivisatos, "Shape control of CdSe nanocrystals," Nature 404, 59-61 (2000). [CrossRef] [PubMed]
  14. X. Li, J. Van Embden, J. W. M. Chon, and M. Gu, "Enhanced two-photon absorption of CdS nanocrystal rods," to be submitted.
  15. J. Hu, L.-S. Li, W. Yang, L. Manna, L.-W. Wang, and A. P. Alivisatos, "Linearly polarized emission from colloidal semiconductor quantum rods," Science 292, 2060-2063 (2001). [CrossRef] [PubMed]
  16. L. De Boni, J. J. RodriguesJr., D. S. Dos SantosJr., C. H. T. P. Silva, D. T. Balogh, O. N. OliveiraJr., S. C. Zilio, L. Misoguti, and C. R. Mendonca, "Two-photon absorption in azoaromatic compounds," Chem. Phys. Lett. 361, 209-213 (2002). [CrossRef]
  17. Z. Sekkat, J. Wood, E. F. Aust, W. Knoll, W. Volksen, and R. D. Miller, "Light-induced orientation in a high glass transition temperature polyimide with polar azo dyes in the side chain," J. Opt. Soc. Am. B 13, 1713-1724 (1996). [CrossRef]
  18. F. Shieh, A. E. Saunders, and B. A. Korgel, "General shape control of colloidal CdS, CdSe, CdTe quantum rods and quantum rod heterostructures," J. Phys. Chem. B. 109, 8538-8542 (2005). [CrossRef]
  19. X. Chen, A. Nazzal, D. Goorskey, M. Xiao, Z. Adam Peng, and X. Peng, "Polarization spectroscopy of single CdSe quantum rods," Phys. Rev. B 64, 2453041-2453044 (2001). [CrossRef]
  20. J. R. Lakowicz, Principles of fluorescence spectroscopy (Kluwer Academic/Plenum, New York, 1999).

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