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Nonlinear optical properties of Phosphorous-doped Si nanocrystals embedded in phosphosilicate glass thin films
Kenji Imakita, Masahiko Ito, Minoru Fujii, and Shinji Hayashi »View Author Affiliations
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe 657-8501, Japan
fujii@eedept.kobe-u.ac.jp
Optics Express, Vol. 17, Issue 9, pp. 7368-7376 (2009)
http://dx.doi.org/10.1364/OE.17.007368
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Abstract
Nonlinear optical properties of phosphorus (P) -doped silicon (Si) nanocrystals are studied by z-scan technique in femtosecond regime at around 1.6 eV. The nonlinear refractive index (n2) and nonlinear absorption coefficient (β) of Si-ncs are significantly enhanced by P-doping. The enhancement of n2 is accompanied by the increase of the linear absorption in the same energy region, suggesting that impurity-related energy states are responsible for the enhancement of the nonlinear optical response.
© 2009 Optical Society of America
OCIS Codes
(190.0190) Nonlinear optics : Nonlinear optics
(190.4720) Nonlinear optics : Optical nonlinearities of condensed matter
ToC Category:
Nonlinear Optics
History
Original Manuscript: March 9, 2009
Revised Manuscript: April 10, 2009
Manuscript Accepted: April 13, 2009
Published: April 20, 2009
Citation
Kenji Imakita, Masahiko Ito, Minoru Fujii, and Shinji Hayashi, "Nonlinear optical properties of Phosphorous-doped Si nanocrystals embedded in phosphosilicate glass thin films," Opt. Express 17, 7368-7376 (2009)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-17-9-7368
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References
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- M. Fujii, Y. Yamaguchi, Y. Takase, K. Ninomiya, and S. Hayashi, "Photoluminescence from impurity codoped and compensated Si nanocrystals," Appl. Phys. Lett. 87, 211919 (2005). [CrossRef]
- M. Fujii, Y. Yamaguchi, Y. Takase, K. Ninomiya, and S. Hayashi, "Control of photoluminescence properties of Si nanocrystals by simultaneously doping n- and p-type impurities," Appl. Phys. Lett. 85, 1158-1160 (2004). [CrossRef]
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- L. Pavesi, Z. Gaburro, L. Dal Negro, P. bettotti, G. Vijaya Prakash, M. Cazzaneli, and C. J. Oton, "Nanostructured silicon as a photonic material," Opt. Lasers Eng. J. Opt. Soc. Am. B 39, 345-367 (2003). [CrossRef]
- P. Bettotti, M. Cazzanelli, L. Dal Negro, B. Danese, Z. Gaburro, C. J. Oton, G. Vijaya Prakash, and L. Pavesi, "Silicon nanostructures for photonics," J. Phys:Condens. Matter 14, 8253-8281 (2002). [CrossRef]
- G. Vijaya Prakash, M. Cazzaneli, Z. Gaburro, L. Pavesi, and F. Lacona, G. Franzo, and F. Priolo., "Nonlinear optical properties of silicon nanocrystals grown by plasma-enhanced chemical vapor deposition," J. Appl. Phys. 91, 4607-4610 (2002). [CrossRef]
- S. Hemandez, P. Pellegrino, A. Martinez, Y. lebour, B. Garrido, R. Spano, M. Cazzanelli, N. Daldosso, L. Pavesi, E. Jordana, and J. M. Fedeli, "Linear and nonlinear optical properties of Si nanocrystals in SiO2 deposited by plasma-enhanced chemical-vapor deposition," J. Appl. Phys. 103, 064309 (2008). [CrossRef]
- S. Vijayalakshmi, M. A. George, and H. Grebel, "Nonlinear optical properties of silicon nanoclusters," Appl. Phys. Lett. 70, 708-710 (1997). [CrossRef]
- V. Sa-yakanit and H. R. Glyde, "Impurity-band density of states in heavily doped semiconductors: A variational calculation," Phys. Rev. B 22, 6222-6232 (1980). [CrossRef]
- S. Vijayalakshmi, A. Lan, Z. lqbal, and H. Grebel, "Nonlinear optical properties of laser ablated silicon nanostructures," J. Appl. Phys. 92, 2490-2494 (2002). [CrossRef]
- S. Vijayalakshumi, H. Grebel, G. Yaglioglu, R. Pino, R. Dorsinville, and C. W. White, "Nonlinear optical response of Si nanostructures in a silica matrix," J. Appl. Phys. 88, 6418-6422 (2000). [CrossRef]
- S. Vijayalakshmi, H. Grebel, Z. lqbal, and C. W. White, "Artificial dielectrics: Nonlinear properties of Si nanoclusters formed by ion implantation in SiO2 glassy matrix," J. Appl. Phys. 84, 6502-6506 (1998). [CrossRef]
- S. Vijayalakshmi, M. A. George, and H. Grebel, "Nonlinear optical properties of silicon nanoclusters," Appl. Phys. Lett. 70, 708-710 (1997). [CrossRef]
- B. J. Pawlak, T. Gregorkiewicz, C. A. J. Ammerlaan, W. Takkenberg, F. D. Tichelaar, and P. F. A. Alkemade, "Experimental investigation of band structure modification in silicon nanocrystals," Phys. Rev. B 64, 115308 (2001). [CrossRef]
- D. W. Hall, M. A. Newhouse, N. F. Borrelli, W. H. Dumbaugh, and D. L. Weidman, "Nonlinear optical susceptibilities of high-index glasses," Appl. Phys. Lett. 54, 1293 (1989). [CrossRef]
- S. Moon, A. Lin, B.H. Kim, P. R. Watekar, and W.-T. Han, "Linear and nonlinear optical properties of the optical fiber doped with silicon nano-particles," J. Non-Cryst. Solids 354, 602-606 (2008). [CrossRef]
- M. Fujii, Y. Yamaguchi, Y. Takase, K. Ninomiya, and S. Hayashi, "Photoluminescence from impurity codoped and compensated Si nanocrystals," Appl. Phys. Lett. 87, 211919 (2005). [CrossRef]
- M. Fujii, Y. Yamaguchi, Y. Takase, K. Ninomiya, and S. Hayashi, "Control of photoluminescence properties of Si nanocrystals by simultaneously doping n- and p-type impurities," Appl. Phys. Lett. 85, 1158-1160 (2004). [CrossRef]
- M. Fujii, A. Mimura, and S. Hayashi, "Hyperfine Structure of the Electron Spin Resonance of Phosphorus-Doped Si Nanocrystals," Phys. Rev. Lett. 89, 206805 (2002). [CrossRef] [PubMed]
- A. Mimura, M. Fujii, S. Hayashi, D. Kovalev, and F. Koch, "Photoluminescence and free-electron absorption in heavily phosphorus-doped Si nanocrystals," Phys. Rev. B 62, 12625-12627 (2000). [CrossRef]
- M. Fujii, A. Mimura, and S. Hayashi, "Improvement in photoluminescence efficiency of SiO2 films containing Si nanocrystals by P doping: An electron spin resonance study," J. Appl. Phys. 87, 1855-1857 (2000). [CrossRef]
- M. Fuji, D. Kovalev, J. Diener, F. Koch, S. Takkeoka, and S. Hayashi, "Breakdown of the k-conservation rule in Si1?xGex alloy nanocrystals: Resonant photoluminescence study," J. Appl. Phys. 88, 5772-5776 (2000). [CrossRef]
- S. Takeoka, M. Fujii, and S. Hayashi, "Size-dependent photoluminescence from surface-oxidized Si nanocrystals in a weak confinement regime," Phys. Rev. B 62, 16820-16825 (2000). [CrossRef]
- M. Fujii, S. Hayashi, and K. Yamamoto, "Photoluminescence from B-doped Si nanocrystals," J. Appl. Phys. 83, 7953-7956 (1998). [CrossRef]
- K. Imakita, M. Ito, M. Fujii, and S. Hayashi, J. Appl. Phys. (to be published).
- S. Hemandez, P. Pellegrino, A. Martinez, Y. lebour, B. Garrido, R. Spano, M. Cazzanelli, N. Daldosso, L. Pavesi, E. Jordana, and J. M. Fedeli, "Linear and nonlinear optical properties of Si nanocrystals in SiO2 deposited by plasma-enhanced chemical-vapor deposition," J. Appl. Phys. 103, 064309 (2008). [CrossRef]
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