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Inverted polymer solar cells with amorphous indium zinc oxide as the electron-collecting electrode |
Optics Express, Vol. 18, Issue S4, pp. A506-A512 (2010)
http://dx.doi.org/10.1364/OE.18.00A506
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Abstract
We report on the fabrication and performance of polymer-based inverted solar cells utilizing amorphous indium zinc oxide (a-IZO) as the electron-collecting electrode. Amorphous IZO films of 200 nm thickness were deposited by room temperature sputtering in a high-purity argon atmosphere. The films possessed a high optical transmittance in the visible region (≥ 80%), a low resistivity (3.3 × 10−4 Ωcm), a low surface roughness (root mean square = 0.68 nm), and a low work function (4.46 ± 0.02 eV). Inverted solar cells with the structure a-IZO/P3HT: PCBM/PEDOT:PSS/Ag exhibited a power conversion efficiency of 3% estimated for AM 1.5G, 100 mW/cm2 illumination.
© 2010 OSA
OCIS Codes
(040.5350) Detectors : Photovoltaic
(230.0250) Optical devices : Optoelectronics
(310.6860) Thin films : Thin films, optical properties
(350.6050) Other areas of optics : Solar energy
(310.7005) Thin films : Transparent conductive coatings
ToC Category:
Photovoltaics
History
Original Manuscript: August 10, 2010
Revised Manuscript: September 9, 2010
Manuscript Accepted: September 10, 2010
Published: September 17, 2010
Citation
Hyeunseok Cheun, Jungbae Kim, Yinhua Zhou, Yunnan Fang, Amir Dindar, Jaewon Shim, Canek Fuentes-Hernandez, Kenneth H. Sandhage, and Bernard Kippelen, "Inverted polymer solar cells with amorphous indium zinc oxide as the electron-collecting electrode," Opt. Express 18, A506-A512 (2010)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-18-S4-A506
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References
- B. Kippelen and J. L. Bredas, “Organic photovoltaics,” Energy Environ. Sci. 2(3), 251–261 (2009). [CrossRef]
- C. J. Brabec, “Organic photovoltaics: technology and market,” Sol. Energy Mater. Sol. Cells 83(2-3), 273–292 (2004). [CrossRef]
- S. R. Forrest, “The path to ubiquitous and low-cost organic electronic appliances on plastic,” Nature 428(6986), 911–918 (2004). [CrossRef] [PubMed]
- S. K. Hau, H. L. Yip, N. S. Baek, J. Y. Zou, K. O'Malley, and A. K. Y. Jen, “Air-stable inverted flexible polymer solar cells using zinc oxide nanoparticles as an electron selective layer,” Appl. Phys. Lett. 92(25), 253301 (2008). [CrossRef]
- Y. H. Zhou, H. Cheun, W. J. Potscavage, C. Fuentes-Hernandez, S. Kim, and B. Kippelen, “Inverted organic solar cells with ITO electrodes modified with an ultrathin Al2O3 buffer layer deposited by atomic layer deposition,” J. Mater. Chem. 20(29), 6189–6194 (2010). [CrossRef]
- C. Waldauf, M. Morana, P. Denk, P. Schilinsky, K. Coakley, S. A. Choulis, and C. J. Brabec, “Highly efficient inverted organic photovoltaics using solution based titanium oxide as electron selective contact,” Appl. Phys. Lett. 89(23), 233517 (2006). [CrossRef]
- M. S. White, D. C. Olson, S. E. Shaheen, N. Kopidakis, and D. S. Ginley, “Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer,” Appl. Phys. Lett. 89(14), 143517 (2006). [CrossRef]
- T. Kuwabara, Y. Kawahara, T. Yamaguchi, and K. Takahashi, “Characterization of Inverted-Type Organic Solar Cells with a ZnO Layer as the Electron Collection Electrode by ac Impedance Spectroscopy,” ACS Appl Mater Interfaces 1(10), 2107–2110 (2009). [CrossRef]
- J. W. Kang, W. I. Jeong, J. J. Kim, H. K. Kim, D. G. Kim, and G. H. Lee, “High-performance flexible organic light-emitting diodes using amorphous indium zinc oxide anode,” Electrochem. Solid-State Lett. 10(6), J75–J78 (2007). [CrossRef]
- Y. S. Park, K. H. Choi, and H. K. Kim, “Atmospheric Plasma Treatment of Flexible IZO Electrode Grown on PET Substrate for Flexible Organic Solar Cells,” Electrochem. Solid-State Lett. 12(12), H426–H429 (2009). [CrossRef]
- S. H. Han, Y. H. Kim, S. H. Lee, M. H. Choi, J. Jang, and D. J. Choo, “Stable organic thin-film transistor in a pixel for plastic electronics,” Org. Electron. 9(6), 1040–1043 (2008). [CrossRef]
- J. B. Kim, C. Fuentes-Hernandez, S. J. Kim, S. Choi, and B. Kippelen, “Flexible hybrid complementary inverters with high gain and balanced noise margins using pentacene and amorphous InGaZnO thin-film transistors,” Org. Electron. 11(6), 1074–1078 (2010). [CrossRef]
- B. Yaglioglu, Y. J. Huang, H. Y. Yeom, and D. C. Paine, “A study of amorphous and crystalline phases in In2O3-10wt.% ZnO thin films deposited by DC magnetron sputtering,” Thin Solid Films 496(1), 89–94 (2006). [CrossRef]
- T. Sasabayashi, N. Ito, E. Nishimura, M. Kon, P. K. Song, K. Utsumi, A. Kaijo, and Y. Shigesato, “Comparative study on structure and internal stress in tin-doped indium oxide and indium-zinc oxide films deposited by r.f. magnetron sputtering,” Thin Solid Films 445(2), 219–223 (2003). [CrossRef]
- Y. S. Park, H. K. Kim, S. W. Jeong, and W. J. Cho, “Highly flexible indium zinc oxide electrode grown on PET substrate by cost efficient roll-to-roll sputtering process,” Thin Solid Films 518(11), 3071–3074 (2010). [CrossRef]
- T. J. Marks, J. G. C. Veinot, J. Cui, H. Yan, A. Wang, N. L. Edleman, J. Ni, Q. Huang, P. Lee, and N. R. Armstrong, “Progress in high work function TCO OLED anode alternatives and OLED nanopixelation,” Synth. Met. 127(1-3), 29–35 (2002). [CrossRef]
- Y. Gassenbauer and A. Klein, “Electronic surface properties of rf-magnetron sputtered In2O3: Sn,” Solid State Ion. 173(1-4), 141–145 (2004). [CrossRef]
- A. Klein, C. Korber, A. Wachau, F. Sauberlich, Y. Gassenbauer, R. Schafranek, S. P. Harvey, and T. O. Mason, “Surface potentials of magnetron sputtered transparent conducting oxides,” Thin Solid Films 518(4), 1197–1203 (2009). [CrossRef]
- R. Martins, P. Almeida, P. Barquinha, L. Pereira, A. Pimentel, I. Ferreira, and E. Fortunato, “Electron transport and optical characteristics in amorphous indium zinc oxide films,” J. Non-Cryst. Solids 352(9-20), 1471–1474 (2006). [CrossRef]
- H. C. Pan, M. H. Shiao, C. Y. Su, and C. N. Hsiao, “Influence of sputtering parameter on the optical and electrical properties of zinc-doped indium oxide thin films,” J. Vac. Sci. Technol. A 23(4), 1187–1191 (2005). [CrossRef]
- M. Glatthaar, M. Niggemann, B. Zimmermann, P. Lewer, M. Riede, A. Hinsch, and J. Luther, “Organic solar cells using inverted layer sequence,” Thin Solid Films 491(1-2), 298–300 (2005). [CrossRef]
- H. Cheun, C. Fuentes-Hernandez, Y. H. Zhou, W. J. Potscavage, C. Fuentes-Hernandez, S. Kim, J. Shim, D. Amir, and B. Kippelen, “Electrical and optical properties of ZnO processed by atomic layer deposition in Inverted polymer solar cells,” J. Phys. Chem. C . submitted.
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