OSA's Digital Library

Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 18, Iss. 21 — Oct. 11, 2010
  • pp: 22032–22040

Preparation and luminescence of bulk oxyfluoride glasses doped with Ag nanoclusters

V. K. Tikhomirov, V. D. Rodríguez, A. Kuznetsov, D. Kirilenko, G. Van Tendeloo, and V. V. Moshchalkov  »View Author Affiliations


Optics Express, Vol. 18, Issue 21, pp. 22032-22040 (2010)
http://dx.doi.org/10.1364/OE.18.022032


View Full Text Article

Enhanced HTML    Acrobat PDF (4641 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations

Abstract

Bulk oxyfluoride glasses doped with Ag nanoclusters have been prepared using the melt quenching technique. When pumped in the absorption band of Ag nanoclusters between 300 to 500 nm, these glasses emit a very broad luminescence band covering all the visible range with a weak tail extending into the near infrared. The maximum of the luminescence band and its color shifts to the blue with a shortening of the excitation wavelength and an increasing ratio of oxide to fluoride components, resulting in white color luminescence at a particular ratio of oxide to fluoride; with a quantum yield above 20%.

© 2010 OSA

OCIS Codes
(160.2750) Materials : Glass and other amorphous materials
(250.5230) Optoelectronics : Photoluminescence
(160.4236) Materials : Nanomaterials

ToC Category:
Materials

History
Original Manuscript: August 2, 2010
Revised Manuscript: September 3, 2010
Manuscript Accepted: September 5, 2010
Published: October 4, 2010

Citation
V. K. Tikhomirov, V. D. Rodríguez, A. Kuznetsov, D. Kirilenko, G. Van Tendeloo, and V. V. Moshchalkov, "Preparation and luminescence of bulk oxyfluoride glasses doped with Ag nanoclusters," Opt. Express 18, 22032-22040 (2010)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-18-21-22032


Sort:  Author  |  Year  |  Journal  |  Reset  

References

  1. Z. Shen, H. Duan, and H. Frey, “Water-soluble fluorescent Ag nanoclusters obtained from multiarm star poly(acrylic acid) as molecular hydrogel templates,” Adv. Mater. 19(3), 349–352 (2007). [CrossRef]
  2. I. Díez, M. Pusa, S. Kulmala, H. Jiang, A. Walther, A. S. Goldman, A. Müller, O. Ikkala, and R. Ras, “Color tuneability and electrochemiluminescence of silver nanoclusters,” Angew. Chem. Int. Ed. 48(12), 2122–2125 (2009). [CrossRef]
  3. R. J. T. Houk, B. W. Jacobs, F. El Gabaly, N. N. Chang, A. A. Talin, D. D. Graham, S. D. House, I. M. Robertson, and M. D. Allendorf, “Silver cluster formation, dynamics, and chemistry in metal-organic frameworks,” Nano Lett. 9(10), 3413–3418 (2009). [CrossRef] [PubMed]
  4. W. W. Guo, J. P. Yuan, Q. Z. Dong, and E. K. Wang, “Highly sequence-dependent formation of fluorescent silver nanoclusters in hybridized DNA duplexes for single nucleotide mutation identification,” J. Am. Chem. Soc. 132(3), 932–934 (2010). [CrossRef]
  5. H. X. Xu and K. S. Suslick, “Sonochemical synthesis of highly fluorescent ag nanoclusters,” ACS Nano 4(6), 3209–3214 (2010). [CrossRef] [PubMed]
  6. L. Maretti, P. S. Billone, Y. Liu, and J. C. Scaiano, “Facile photochemical synthesis and characterization of highly fluorescent silver nanoparticles,” J. Am. Chem. Soc. 131(39), 13972–13980 (2009). [CrossRef] [PubMed]
  7. M. Ferrari, F. Gonella, M. Montagna, and C. Tosello, “Detection and size determination of Ag nanoclusters in ion exchanged soda-lime glasses by waveguide Raman spectroscopy,” J. Appl. Phys. 79(4), 2055–2059 (1996). [CrossRef]
  8. M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008). [CrossRef] [PubMed]
  9. J. Shen, J. Zheng, J. Zhang, C. Zhou, and L. Jiang, “UV-laser-induced nanoclusters in silver ion-exchanged soda-lime silicate glass,” Physica B 387(1-2), 32–35 (2007). [CrossRef]
  10. G. Nunzi Conti, V. K. Tikhomirov, M. Bettinelli, S. Berneschi, M. Brenci, B. Chen, S. Pelli, A. Speghini, and G. C. Righini, “Characterization of ion-exchanged waveguides in tungsten tellurite and zinc tellurite Er3+-doped glasses,” Opt. Eng. 42(10), 2805–2811 (2003). [CrossRef]
  11. V. D. Rodríguez, V. K. Tikhomirov, J. Méndez-Ramos, A. Yanes, and V. V. Moshchalkov, “Towards broad range and highly efficient down-conversion of solar spectrum by Er3+-Yb3+ co-doped nano-structured glass-ceramics,” Sol. Energy Mater. Sol. Cells 94(10), 1612–1617 (2010). [CrossRef]
  12. V. K. Tikhomirov, D. Furniss, I. M. Reaney, M. Beggiora, M. Ferrari, M. Montagna, and R. Rolli, “Fabrication and characterization of nanoscale, Er3+-doped, ultratransparent oxyfluoride glass-ceramics,” Appl. Phys. Lett. 81(11), 1937–1939 (2002). [CrossRef]
  13. V. K. Tikhomirov, T. Vosch, E. Fron, J. Hofkens, M. Van der Auweraer, V. V. Moshchalkov, Catholic University Leuven, are preparing a manuscript to be called “Luminescence lifetimes in glass doped with Ag nanoclusters.”
  14. Z. Wu and R. Jin, “On the ligand’s role in the fluorescence of gold nanoclusters,” Nano Lett. 10(7), 2568–2573 (2010). [CrossRef] [PubMed]
  15. P. Boutinnand, A. Monnier, and H. Bill, “Luminescence mechanisms of Ag+ cubic centers in strontium fluoride crystals,” J. Phys. Condens. Matter 6(42), 8931–8947 (1994). [CrossRef]
  16. J. C. Pickering and V. Zilio, “New accurate data for the spectrum of neutral silver,” Eur. Phys. J. D 13(2), 181–185 (2001). [CrossRef]
  17. S. Hull, “Superionic crystal structures and conduction processes,” Rep. Prog. Phys. 67(7), 1233–1314 (2004). [CrossRef]
  18. Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439(1-3), 81–84 (2007). [CrossRef]
  19. E. Borsella, F. Gonella, P. Mazzoldi, A. Quaranta, G. Bataglin, and R. Polloni, “Spectroscopic investigation of silver in soda-lime glass,” Chem. Phys. Lett. 284(5-6), 429–434 (1998). [CrossRef]
  20. C. Strohhofer and A. Polman, “Silver as a sensitizer for erbium,” Appl. Phys. Lett. 81(8), 1414–1416 (2002). [CrossRef]
  21. M. Mattarelli, M. Montagna, K. Vishnubathla, A. Chiasera, M. Ferrari, and G. C. Righini, “Mechanisms of silver to erbium energy transfer in silicate glasses,” Phys. Rev. B 75, 125102 (2007). [CrossRef]

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.


« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited