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Solution-processed chalcogenide glass for integrated single-mode mid-infrared waveguidesCandice Tsay, Yunlai Zha, and Craig B. Arnold »View Author Affiliations
Candice Tsay,1
Yunlai Zha,1
and Craig B. Arnold1,2,*
1Department of Electrical Engineering, Princeton University, Princeton, NJ 08544, USA 2Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544, USA *Corresponding author: cbarnold@princeton.edu |
Optics Express, Vol. 18, Issue 25, pp. 26744-26753 (2010)
http://dx.doi.org/10.1364/OE.18.026744
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Abstract
Chalcogenide glass materials exhibit a variety of optical properties that make them desirable for near- and mid-infrared communications and sensing applications. However, processing limitations for these photorefractive materials have made the direct integration of waveguides with sources or detectors challenging. Here we demonstrate the viability of two complementary soft lithography methods for patterning and integrating chalcogenide glass waveguides from solution. One method, micro-molding in capillaries (MIMIC), is shown to fabricate multi-mode As2S3 waveguides which are directly integrated with quantum cascade lasers (QCLs). In a second method, we demonstrate the ability of micro-transfer molding (µTM), to produce arrays of single mode rib waveguides (2.5µm wide and 4.5µm high) over areas larger than 6 cm2 while maintaining edge roughness below 5.1 nm. These methods form a suite of processes that can be applied to chalcogenide solutions to create a diverse array of mid-IR optical and photonic structures ranging from <5 to 10’s of µm in dimension.
© 2010 OSA
OCIS Codes
(310.1860) Thin films : Deposition and fabrication
(130.2755) Integrated optics : Glass waveguides
ToC Category:
Chalcogenide Glass
History
Original Manuscript: September 29, 2010
Revised Manuscript: November 30, 2010
Manuscript Accepted: November 30, 2010
Published: December 6, 2010
Virtual Issues
Chalcogenide Glass (2010) Optics Express
Citation
Candice Tsay, Yunlai Zha, and Craig B. Arnold, "Solution-processed chalcogenide glass for integrated single-mode mid-infrared waveguides," Opt. Express 18, 26744-26753 (2010)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-18-25-26744
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References
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- S. Song, N. Carlie, J. Boudies, L. Petit, K. Richardson, and C. B. Arnold, “Spin-coating of Ge23Sb7S70 chalcogenide glass thin films,” J. Non-Cryst. Solids 355(45-47), 2272–2278 (2009). [CrossRef]
- J. Hu, V. Tarasov, N. Carlie, N.-N. Feng, L. Petit, A. Agarwal, K. Richardson, and L. Kimerling, “Si-CMOS-compatible lift-off fabrication of low-loss planar chalcogenide waveguides,” Opt. Express 15(19), 11798–11807 (2007). [CrossRef] [PubMed]
- J. Hu, V. Tarasov, A. Agarwal, L. Kimerling, N. Carlie, L. Petit, and K. Richardson, “Fabrication and testing of planar chalcogenide waveguide integrated microfluidic sensor,” Opt. Express 15(5), 2307–2314 (2007). [CrossRef] [PubMed]
- M. Solmaz, H. Park, C. K. Madsen, and X. Cheng, “Patterning chalcogenide glass by direct resist-free thermal nanoimprint,” J. Vac. Sci. Technol. B 26(2), 606–610 (2008). [CrossRef]
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- C. Gmachl, F. Capasso, D. L. Sivco, and Q. Y. Cho, “Recent progress in quantum cascade lasers and applications,” Rep. Prog. Phys. 64(11), 1533–1601 (2001). [CrossRef]
- N. L. Jeon, I. S. Choi, B. Xu, and G. M. Whitesides, “Large-area patterning by vacuum-assisted micromolding,” Adv. Mater. 11(11), 946–950 (1999). [CrossRef]
- R. G. DeCorby, N. Ponnampalam, M. M. Pai, H. T. Nguyen, P. K. Dwivedi, T. J. Clement, C. J. Haugen, J. N. McMullin, and S. O. Kasap, “High index contrast waveguides in chalcogenide glass and polymer,” IEEE J. Sel. Top. Quantum Electron. 11(2), 539–546 (2005). [CrossRef]
- G. P. Patsis, V. Constantoudis, A. Tserepi, E. Gogolides, and G. Grozev, “Quantification of line-edge roughness of photoresists I. A comparison between off-line and on-line analysis of top-down scanning electron microscopy images,” J. Vac. Sci. Technol. B 21(3), 1008–1018 (2003). [CrossRef]
- R. F. Curl, F. Capasso, C. Gmachl, A. A. Kosterev, B. McManus, R. Lewicki, M. Pusharsky, G. Wysocki, and F. K. Tittel, “Quantum cascade lasers in chemical physics,” Chem. Phys. Lett. 487(1-3), 1–18 (2010). [CrossRef]
- Y. Yang and Y. Dan, “Preparation of PMMA/SiO2 composite particles via emulsion polymerization,” Colloid Polym. Sci. 281(8), 794–799 (2003). [CrossRef]
- R. G. DeCorby, N. Ponnampalam, M. M. Pai, H. T. Nguyen, P. K. Dwivedi, T. J. Clement, C. J. Haugen, J. N. McMullin, and S. O. Kasap, “High index contrast waveguides in chalcogenide glass and polymer,” IEEE J. Sel. Top. Quantum Electron. 11(2), 539–546 (2005). [CrossRef]
- S. Song, S. S. Howard, Z. Liu, A. O. Dirisu, C. F. Gmachl, and C. B. Arnold, “Mode tuning of quantum cascade lasers through optical processing of chalcogenide glass claddings,” Appl. Phys. Lett. 89(4), 041115 (2006). [CrossRef]
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- J. Hu, N.-N. Feng, N. Carlie, L. Petit, A. Agarwal, K. Richardson, and L. Kimerling, “Optical loss reduction in high-index-contrast chalcogenide glass waveguides via thermal reflow,” Opt. Express 18(2), 1469–1478 (2010). [CrossRef] [PubMed]
- J. Hu, V. Tarasov, N. Carlie, N.-N. Feng, L. Petit, A. Agarwal, K. Richardson, and L. Kimerling, “Si-CMOS-compatible lift-off fabrication of low-loss planar chalcogenide waveguides,” Opt. Express 15(19), 11798–11807 (2007). [CrossRef] [PubMed]
- A. B. Seddon, W. J. Pan, D. Furniss, C. A. Miller, H. Rowe, D. Zhang, E. M. Brearty, Y. Zhang, A. Loni, P. Sewell, and T. M. Benson, “Fine embossing of chalcogenide glasses – a new fabrication route for photonic integrated circuits,” J. Non-Crys. Solids 352, 2515–2520 (2006). [CrossRef]
- C. Yu, A. Ganjoo, H. Jain, C. G. Pantano, and J. Irudayaraj, “Mid-IR biosensor: detection and fingerprinting of pathogens on gold island functionalized chalcogenide films,” Anal. Chem. 78(8), 2500–2506 (2006). [CrossRef] [PubMed]
- R. F. Curl, F. Capasso, C. Gmachl, A. A. Kosterev, B. McManus, R. Lewicki, M. Pusharsky, G. Wysocki, and F. K. Tittel, “Quantum cascade lasers in chemical physics,” Chem. Phys. Lett. 487(1-3), 1–18 (2010). [CrossRef]
- A. J. Hoffman, S. Schartner, S. S. Howard, K. J. Franz, F. Towner, and C. Gmachl, “Low voltage-defect quantum cascade laser with heterogeneous injector regions,” Opt. Express 15(24), 15818–15823 (2007). [CrossRef] [PubMed]
- C. Gmachl, F. Capasso, D. L. Sivco, and Q. Y. Cho, “Recent progress in quantum cascade lasers and applications,” Rep. Prog. Phys. 64(11), 1533–1601 (2001). [CrossRef]
- C. Tsay, E. Mujagić, C. K. Madsen, C. F. Gmachl, and C. B. Arnold, “Mid-infrared characterization of solution-processed As2S3 chalcogenide glass waveguides,” Opt. Express 18(15), 15523–15530 (2010). [CrossRef] [PubMed]
- C. Tsay, F. Toor, C. F. Gmachl, and C. B. Arnold, “Chalcogenide glass waveguides integrated with quantum cascade lasers for on-chip mid-IR photonic circuits,” Opt. Lett. 35(20), 3324–3326 (2010). [CrossRef] [PubMed]
- S. Song, S. S. Howard, Z. Liu, A. O. Dirisu, C. F. Gmachl, and C. B. Arnold, “Mode tuning of quantum cascade lasers through optical processing of chalcogenide glass claddings,” Appl. Phys. Lett. 89(4), 041115 (2006). [CrossRef]
- G. P. Patsis, V. Constantoudis, A. Tserepi, E. Gogolides, and G. Grozev, “Quantification of line-edge roughness of photoresists I. A comparison between off-line and on-line analysis of top-down scanning electron microscopy images,” J. Vac. Sci. Technol. B 21(3), 1008–1018 (2003). [CrossRef]
- G. P. Patsis, V. Constantoudis, A. Tserepi, E. Gogolides, and G. Grozev, “Quantification of line-edge roughness of photoresists I. A comparison between off-line and on-line analysis of top-down scanning electron microscopy images,” J. Vac. Sci. Technol. B 21(3), 1008–1018 (2003). [CrossRef]
- R. G. DeCorby, N. Ponnampalam, M. M. Pai, H. T. Nguyen, P. K. Dwivedi, T. J. Clement, C. J. Haugen, J. N. McMullin, and S. O. Kasap, “High index contrast waveguides in chalcogenide glass and polymer,” IEEE J. Sel. Top. Quantum Electron. 11(2), 539–546 (2005). [CrossRef]
- K. Richardson, D. Krol, and K. Hirao, “Glasses for photonic applications,” Int. J. Appl. Glass Science 1(1), 74–86 (2010). [CrossRef]
- A. J. Hoffman, S. Schartner, S. S. Howard, K. J. Franz, F. Towner, and C. Gmachl, “Low voltage-defect quantum cascade laser with heterogeneous injector regions,” Opt. Express 15(24), 15818–15823 (2007). [CrossRef] [PubMed]
- S. Song, S. S. Howard, Z. Liu, A. O. Dirisu, C. F. Gmachl, and C. B. Arnold, “Mode tuning of quantum cascade lasers through optical processing of chalcogenide glass claddings,” Appl. Phys. Lett. 89(4), 041115 (2006). [CrossRef]
- J. Hu, N.-N. Feng, N. Carlie, L. Petit, A. Agarwal, K. Richardson, and L. Kimerling, “Optical loss reduction in high-index-contrast chalcogenide glass waveguides via thermal reflow,” Opt. Express 18(2), 1469–1478 (2010). [CrossRef] [PubMed]
- J. Hu, V. Tarasov, A. Agarwal, L. Kimerling, N. Carlie, L. Petit, and K. Richardson, “Fabrication and testing of planar chalcogenide waveguide integrated microfluidic sensor,” Opt. Express 15(5), 2307–2314 (2007). [CrossRef] [PubMed]
- J. Hu, V. Tarasov, N. Carlie, N.-N. Feng, L. Petit, A. Agarwal, K. Richardson, and L. Kimerling, “Si-CMOS-compatible lift-off fabrication of low-loss planar chalcogenide waveguides,” Opt. Express 15(19), 11798–11807 (2007). [CrossRef] [PubMed]
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Adv. Mater.
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Anal. Bioanal. Chem.
- S.-S. Kim, C. Young, and B. Mizaikoff, “Miniaturized mid-infrared sensor technologies,” Anal. Bioanal. Chem. 390(1), 231–237 (2008). [CrossRef]
Anal. Chem.
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