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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 18, Iss. 26 — Dec. 20, 2010
  • pp: 27067–27078

Enhancing signal detection and completely eliminating scattering using quasi-phase-cycling in 2D IR experiments

Robbert Bloem, Sean Garrett-Roe, Halina Strzalka, Peter Hamm, and Paul Donaldson  »View Author Affiliations


Optics Express, Vol. 18, Issue 26, pp. 27067-27078 (2010)
http://dx.doi.org/10.1364/OE.18.027067


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Abstract

We demonstrate how quasi-phase-cycling achieved by sub-cycle delay modulation can be used to replace optical chopping in a box-CARS 2D IR experiment in order to enhance the signal size, and, at the same time, completely eliminate any scattering contamination. Two optical devices are described that can be used for this purpose, a wobbling Brewster window and a photoelastic modulator. They are simple to construct, easy to incorporate into any existing 2D IR setup, and have attractive features such as a high optical throughput and a fast modulation frequency needed to phase cycle on a shot-to-shot basis.

© 2010 Optical Society of America

OCIS Codes
(120.6200) Instrumentation, measurement, and metrology : Spectrometers and spectroscopic instrumentation
(300.6300) Spectroscopy : Spectroscopy, Fourier transforms
(320.7150) Ultrafast optics : Ultrafast spectroscopy

ToC Category:
Instrumentation, Measurement, and Metrology

History
Original Manuscript: October 20, 2010
Revised Manuscript: November 11, 2010
Manuscript Accepted: November 16, 2010
Published: December 8, 2010

Citation
Robbert Bloem, Sean Garrett-Roe, Halina Strzalka, Peter Hamm, and Paul Donaldson, "Enhancing signal detection and completely eliminating scattering using quasi-phase-cycling in 2D IR experiments," Opt. Express 18, 27067-27078 (2010)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-18-26-27067


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