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Plasmon-enhanced Förster energy transfer between semiconductor quantum dots: multipole effects
Xiong-Rui Su, Wei Zhang, Li Zhou, Xiao-Niu Peng, and Qu-Quan Wang »View Author Affiliations
1Department of Physics, Wuhan University, Wuhan 430072, P. R. China
2Institute of Applied Physics and Computational Mathematics, P. O. Box 8009(28), Beijing 100088, P. R. China
*Corresponding author: qqwang@whu.edu.cn
Optics Express, Vol. 18, Issue 7, pp. 6516-6521 (2010)
http://dx.doi.org/10.1364/OE.18.006516
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Abstract
We experimentally demonstrated plasmon-asssisted energy transfer (ET) between CdSe semiconductor quantum dots (QDs) self-assembled in a monolayer by using time-resolved μ-photoluminescence (PL) technique. The enhancements of PL intensity and ET efficiency were manipulated by adjusting thickness (Δ) of SiO2 coating on large Ag nanoparticles. The PL enhancement factor of the acceptor QDs and the PL intensity ratio of acceptor-to-donor reached their maxima ~ 47 and ~ 14 when Δ = 7 nm, the corresponding ET efficiency reached 86%. We also presented theoretical analysis based on the rate equation. The theoretical calculations agreed with experimental data and revealed interesting physics of multipole effect, and metal nanoparticle induced quench effect and plasmon-enhanced Förster ET.
© 2010 OSA
OCIS Codes
(250.5230) Optoelectronics : Photoluminescence
(260.2160) Physical optics : Energy transfer
(300.6500) Spectroscopy : Spectroscopy, time-resolved
(250.5403) Optoelectronics : Plasmonics
ToC Category:
Optoelectronics
History
Original Manuscript: January 4, 2010
Revised Manuscript: February 24, 2010
Manuscript Accepted: February 25, 2010
Published: March 15, 2010
Citation
Xiong-Rui Su, Wei Zhang, Li Zhou, Xiao-Niu Peng, and Qu-Quan Wang, "Plasmon-enhanced Förster energy transfer between semiconductor quantum dots: multipole effects," Opt. Express 18, 6516-6521 (2010)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-18-7-6516
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References
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- X. Li, Y. Wu, D. Steel, D. Gammon, T. H. Stievater, D. S. Katzer, D. Park, C. Piermarocchi, and L. J. Sham, “An all-optical quantum gate in a semiconductor quantum dot,” Science 301(5634), 809–811 (2003). [CrossRef] [PubMed]
- R. Bose, J. F. McMillan, J. Gao, K. M. Rickey, C. J. Chen, D. V. Talapin, C. B. Murray, and C. W. Wong, “Temperature-tuning of near-infrared monodisperse quantum dot solids at 1.5 µm for controllable Forster energy transfer,” Nano Lett. 8(7), 2006–2011 (2008). [CrossRef] [PubMed]
- V. K. Komarala, Y. P. Rakovich, A. L. Bradley, S. J. Byrne, Y. K. Gun’ko, N. Gaponik, and A. Eychmüller, “Off-resonance surface plasmon enhanced spontaneous emission from CdTe quantum dots,” Appl. Phys. Lett. 89(25), 253118 (2006). [CrossRef]
- T. Franzl, D. S. Koktysh, T. A. Klar, A. L. Rogach, J. Feldmann, and N. Gaponik, “Fast energy transfer in layer-by-layer assembled CdTe nanocrystal bilayers,” Appl. Phys. Lett. 84(15), 2904–2906 (2004). [CrossRef]
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- X. M. Hua, J. I. Gersten, and A. Nitzan, “Theory of energy transfer between molecules near solid state particles,” J. Chem. Phys. 83(7), 3650–3659 (1985). [CrossRef]
- J. I. Gersten and A. Nitzan, “Accelerated energy transfer between molecules near a solid particle,” Chem. Phys. Lett. 104(1), 31–37 (1984). [CrossRef]
- Y. Li, A. Rizzo, M. Mazzeo, L. Carbone, L. Manna, R. Cingolani, and G. Gigli, “White organic light-emitting devices with CdSe/ZnS quantum dots as a red emitter,” J. Appl. Phys. 97(11), 113501 (2005). [CrossRef]
- Q. Q. Wang, J. B. Han, D. L. Guo, S. Xiao, Y. B. Han, H. M. Gong, and X. W. Zou, “Highly efficient avalanche multiphoton luminescence from coupled Au nanowires in the visible region,” Nano Lett. 7(3), 723–728 (2007). [CrossRef] [PubMed]
- J. Y. Yan, W. Zhang, S. Duan, X. G. Zhao, and A. O. Govorov, “Optical properties of coupled metal-semiconductor and metal-molecule nanocrystal complexes: role of multipole effects,” Phys. Rev. B 77(16), 165301 (2008). [CrossRef]
- A. O. Govorov, J. Lee, and N. A. Kotov, “Theory of plasmon-enhanced Förster energy transfer in optically excited semiconductor and metal nanoparticles,” Phys. Rev. B 76(12), 125308 (2007). [CrossRef]
- W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: hybrid excitons and the nonlinear Fano effect,” Phys. Rev. Lett. 97(14), 146804 (2006). [CrossRef] [PubMed]
- A. O. Govorov, G. W. Bryan, W. Zhang, T. Skeini, J. Lee, N. A. Kotov, J. M. Slocik, and R. R. Naik, “Exciton−plasmon interaction and hybrid excitons in semiconductor−metal nanoparticle assemblies,” Nano Lett. 6(5), 984–994 (2006). [CrossRef]
- V. K. Komarala, Y. P. Rakovich, A. L. Bradley, S. J. Byrne, Y. K. Gun’ko, N. Gaponik, and A. Eychmüller, “Off-resonance surface plasmon enhanced spontaneous emission from CdTe quantum dots,” Appl. Phys. Lett. 89(25), 253118 (2006). [CrossRef]
- Q. Q. Wang, J. B. Han, D. L. Guo, S. Xiao, Y. B. Han, H. M. Gong, and X. W. Zou, “Highly efficient avalanche multiphoton luminescence from coupled Au nanowires in the visible region,” Nano Lett. 7(3), 723–728 (2007). [CrossRef] [PubMed]
- Q. Q. Wang, J. B. Han, D. L. Guo, S. Xiao, Y. B. Han, H. M. Gong, and X. W. Zou, “Highly efficient avalanche multiphoton luminescence from coupled Au nanowires in the visible region,” Nano Lett. 7(3), 723–728 (2007). [CrossRef] [PubMed]
- Q. Q. Wang, J. B. Han, D. L. Guo, S. Xiao, Y. B. Han, H. M. Gong, and X. W. Zou, “Highly efficient avalanche multiphoton luminescence from coupled Au nanowires in the visible region,” Nano Lett. 7(3), 723–728 (2007). [CrossRef] [PubMed]
- M. Scheibner, I. V. Ponomarev, E. A. Stinaff, M. F. Doty, A. S. Bracker, C. S. Hellberg, T. L. Reinecke, and D. Gammon, “Photoluminescence spectroscopy of the molecular biexciton in vertically stacked InAs-GaAs quantum dot pairs,” Phys. Rev. Lett. 99(19), 197402 (2007). [CrossRef]
- S. A. Crooker, J. A. Hollingsworth, S. Tretiak, and V. I. Klimov, “Spectrally resolved dynamics of energy transfer in quantum-dot assemblies: towards engineered energy flows in artificial materials,” Phys. Rev. Lett. 89(18), 186802 (2002). [CrossRef] [PubMed]
- K. Hosoki, T. Tayagaki, S. Yamamoto, K. Matsuda, and Y. Kanemitsu, “Direct and stepwise energy transfer from excitons to plasmons in close-packed metal and semiconductor nanoparticle monolayer films,” Phys. Rev. Lett. 100(20), 207404 (2008). [CrossRef] [PubMed]
- X. M. Hua, J. I. Gersten, and A. Nitzan, “Theory of energy transfer between molecules near solid state particles,” J. Chem. Phys. 83(7), 3650–3659 (1985). [CrossRef]
- C. R. Kagan, C. B. Murray, M. Nirmal, and M. G. Bawendi, “Electronic energy transfer in CdSe quantum dot solids,” Phys. Rev. Lett. 76(9), 1517–1520 (1996). [CrossRef] [PubMed]
- K. Hosoki, T. Tayagaki, S. Yamamoto, K. Matsuda, and Y. Kanemitsu, “Direct and stepwise energy transfer from excitons to plasmons in close-packed metal and semiconductor nanoparticle monolayer films,” Phys. Rev. Lett. 100(20), 207404 (2008). [CrossRef] [PubMed]
- X. Li, Y. Wu, D. Steel, D. Gammon, T. H. Stievater, D. S. Katzer, D. Park, C. Piermarocchi, and L. J. Sham, “An all-optical quantum gate in a semiconductor quantum dot,” Science 301(5634), 809–811 (2003). [CrossRef] [PubMed]
- T. Franzl, D. S. Koktysh, T. A. Klar, A. L. Rogach, J. Feldmann, and N. Gaponik, “Fast energy transfer in layer-by-layer assembled CdTe nanocrystal bilayers,” Appl. Phys. Lett. 84(15), 2904–2906 (2004). [CrossRef]
- M. Durach, A. Rusina, V. I. Klimov, and M. I. Stockman, “Nanoplasmonic renormalization and enhancement of coulomb interactions,” N. J. Phys. 10(10), 105011 (2008). [CrossRef]
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Appl. Phys. Lett.
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Chem. Phys. Lett.
- J. I. Gersten and A. Nitzan, “Accelerated energy transfer between molecules near a solid particle,” Chem. Phys. Lett. 104(1), 31–37 (1984). [CrossRef]
Chemistry
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J. Am. Chem. Soc.
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J. Appl. Phys.
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J. Chem. Phys.
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J. Coll. Inter. Sci.
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J. Phys. Chem. B
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N. J. Phys.
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Nano Lett.
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Phys. Rev. B
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Phys. Rev. Lett.
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Science
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Other
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2010, Su, Appl. Phys. Lett.
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- R. Bose, J. F. McMillan, J. Gao, K. M. Rickey, C. J. Chen, D. V. Talapin, C. B. Murray, and C. W. Wong, “Temperature-tuning of near-infrared monodisperse quantum dot solids at 1.5 µm for controllable Forster energy transfer,” Nano Lett. 8(7), 2006–2011 (2008). [CrossRef] [PubMed]
- K. Hosoki, T. Tayagaki, S. Yamamoto, K. Matsuda, and Y. Kanemitsu, “Direct and stepwise energy transfer from excitons to plasmons in close-packed metal and semiconductor nanoparticle monolayer films,” Phys. Rev. Lett. 100(20), 207404 (2008). [CrossRef] [PubMed]
- A. O. Govorov, J. Lee, and N. A. Kotov, “Theory of plasmon-enhanced Förster energy transfer in optically excited semiconductor and metal nanoparticles,” Phys. Rev. B 76(12), 125308 (2007). [CrossRef]
- M. Scheibner, I. V. Ponomarev, E. A. Stinaff, M. F. Doty, A. S. Bracker, C. S. Hellberg, T. L. Reinecke, and D. Gammon, “Photoluminescence spectroscopy of the molecular biexciton in vertically stacked InAs-GaAs quantum dot pairs,” Phys. Rev. Lett. 99(19), 197402 (2007). [CrossRef]
- Q. Q. Wang, J. B. Han, D. L. Guo, S. Xiao, Y. B. Han, H. M. Gong, and X. W. Zou, “Highly efficient avalanche multiphoton luminescence from coupled Au nanowires in the visible region,” Nano Lett. 7(3), 723–728 (2007). [CrossRef] [PubMed]
- W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: hybrid excitons and the nonlinear Fano effect,” Phys. Rev. Lett. 97(14), 146804 (2006). [CrossRef] [PubMed]
- V. K. Komarala, Y. P. Rakovich, A. L. Bradley, S. J. Byrne, Y. K. Gun’ko, N. Gaponik, and A. Eychmüller, “Off-resonance surface plasmon enhanced spontaneous emission from CdTe quantum dots,” Appl. Phys. Lett. 89(25), 253118 (2006). [CrossRef]
- X. H. Wang, Y. M. Du, S. Ding, Q. Q. Wang, G. G. Xiong, M. Xie, X. C. Shen, and D. W. Pang, “Preparation and third-order optical nonlinearity of self-assembled chitosan/CdSe-ZnS core-shell quantum dots multilayer films,” J. Phys. Chem. B 110(4), 1566–1570 (2006). [CrossRef] [PubMed]
- A. O. Govorov, G. W. Bryan, W. Zhang, T. Skeini, J. Lee, N. A. Kotov, J. M. Slocik, and R. R. Naik, “Exciton−plasmon interaction and hybrid excitons in semiconductor−metal nanoparticle assemblies,” Nano Lett. 6(5), 984–994 (2006). [CrossRef]
- Y. Li, A. Rizzo, M. Mazzeo, L. Carbone, L. Manna, R. Cingolani, and G. Gigli, “White organic light-emitting devices with CdSe/ZnS quantum dots as a red emitter,” J. Appl. Phys. 97(11), 113501 (2005). [CrossRef]
- Q. Q. Wang, A. Muller, M. T. Cheng, H. J. Zhou, P. Bianucci, and C. K. Shih, “Coherent control of a V-type three-level system in a single quantum dot,” Phys. Rev. Lett. 95(18), 187404 (2005). [CrossRef] [PubMed]
- B. Wiley, Y. Sun, B. Mayers, and Y. Xia, “Shape-controlled synthesis of metal nanostructures: the case of silver,” Chemistry 11(2), 454–463 (2005). [CrossRef]
- T. Franzl, D. S. Koktysh, T. A. Klar, A. L. Rogach, J. Feldmann, and N. Gaponik, “Fast energy transfer in layer-by-layer assembled CdTe nanocrystal bilayers,” Appl. Phys. Lett. 84(15), 2904–2906 (2004). [CrossRef]
- A. R. Clapp, I. L. Medintz, J. M. Mauro, B. R. Fisher, M. G. Bawendi, and H. Mattoussi, “Fluorescence resonance energy transfer between quantum dot donors and dye-labeled protein acceptors,” J. Am. Chem. Soc. 126(1), 301–310 (2004). [CrossRef] [PubMed]
- X. Li, Y. Wu, D. Steel, D. Gammon, T. H. Stievater, D. S. Katzer, D. Park, C. Piermarocchi, and L. J. Sham, “An all-optical quantum gate in a semiconductor quantum dot,” Science 301(5634), 809–811 (2003). [CrossRef] [PubMed]
- I. Potapova, R. Mruk, S. Prehl, R. Zentel, T. Basché, and A. Mews, “Semiconductor nanocrystals with multifunctional polymer ligands,” J. Am. Chem. Soc. 125(2), 320–321 (2003). [CrossRef] [PubMed]
- S. A. Crooker, J. A. Hollingsworth, S. Tretiak, and V. I. Klimov, “Spectrally resolved dynamics of energy transfer in quantum-dot assemblies: towards engineered energy flows in artificial materials,” Phys. Rev. Lett. 89(18), 186802 (2002). [CrossRef] [PubMed]
- S. Wang, N. Mamedova, N. A. Kotov, W. Chen, and J. Studer, “Antigen/antibody immunocomplex from CdTe nanoparticle bioconjugates,” Nano Lett. 2(8), 817–822 (2002). [CrossRef]
- K. T. Shimizu, W. K. Woo, B. R. Fisher, H. J. Eisler, and M. G. Bawendi, “Surface-enhanced emission from single semiconductor nanocrystals,” Phys. Rev. Lett. 89(11), 117401 (2002). [CrossRef] [PubMed]
- C. R. Kagan, C. B. Murray, M. Nirmal, and M. G. Bawendi, “Electronic energy transfer in CdSe quantum dot solids,” Phys. Rev. Lett. 76(9), 1517–1520 (1996). [CrossRef] [PubMed]
- X. M. Hua, J. I. Gersten, and A. Nitzan, “Theory of energy transfer between molecules near solid state particles,” J. Chem. Phys. 83(7), 3650–3659 (1985). [CrossRef]
- J. I. Gersten and A. Nitzan, “Accelerated energy transfer between molecules near a solid particle,” Chem. Phys. Lett. 104(1), 31–37 (1984). [CrossRef]
- W. Stöber, A. Fink, and E. Bohn, “Controlled growth of monodisperse silica spheres in the micron size range,” J. Coll. Inter. Sci. 26(1), 62–69 (1968). [CrossRef]
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