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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 19, Iss. 15 — Jul. 18, 2011
  • pp: 13722–13731

Molecular orbital imaging via above-threshold ionization with circularly polarized pulses

Xiaosong Zhu, Qingbin Zhang, Weiyi Hong, Peixiang Lu, and Zhizhan Xu  »View Author Affiliations


Optics Express, Vol. 19, Issue 15, pp. 13722-13731 (2011)
http://dx.doi.org/10.1364/OE.19.013722


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Abstract

Above-threshold ionization (ATI) for aligned or orientated linear molecules by circularly polarized laser pulsed is investigated. It is found that the all-round structural information of the molecular orbital is extracted with only one shot by the circularly polarized probe pulse rather than with multi-shot detections in a linearly polarized case. The obtained photoelectron momentum spectrum directly depicts the symmetry and electron distribution of the occupied molecular orbital, which results from the strong sensitivity of the ionization probability to these structural features. Our investigation indicates that the circularly polarized probe scheme would present a simple method to study the angle-dependent ionization and image the occupied electronic orbital.

© 2011 OSA

OCIS Codes
(020.4180) Atomic and molecular physics : Multiphoton processes
(260.3230) Physical optics : Ionization
(270.6620) Quantum optics : Strong-field processes

ToC Category:
Atomic and Molecular Physics

History
Original Manuscript: April 21, 2011
Revised Manuscript: May 26, 2011
Manuscript Accepted: June 17, 2011
Published: July 1, 2011

Citation
Xiaosong Zhu, Qingbin Zhang, Weiyi Hong, Peixiang Lu, and Zhizhan Xu, "Molecular orbital imaging via above-threshold ionization with circularly polarized pulses," Opt. Express 19, 13722-13731 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-15-13722


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References

  1. P. Agostini, F. Fabre, G. Mainfray, and G. Petite, “Free-free transitions following six-photon ionization of xenon atoms,” Phys. Rev. Lett. 42, 1127–1130 (1979). [CrossRef]
  2. C. I. Blaga, F. Catoire, P. Colosimo, G. G. Paulus, H. G. Muller, P. Agostini, and L. F. DiMauro, “Strong-field photoionization revisited,” Nat. Phys. 5, 335–338 (2009). [CrossRef]
  3. W. Quan, Z. Lin, M. Wu, H. Kang, H. Liu, X. Liu, J. Chen, J. Liu, X. T. He, S. G. Chen, H. Xiong, L. Guo, H. Xu, Y. Fu, Y. Cheng, and Z. Z. Xu, “Classical aspects in above-threshold ionization with a mid-infrared strong laser field,” Phys. Rev. Lett. 103, 093001 (2009). [PubMed]
  4. A. Becker and F. H. M. Faisal, “Intense-field many-body S-matrix theory,” J. Phys. B 38, R1–R56 (2005). [CrossRef]
  5. Z. Zhou and S. Chu, “Precision calculation of above-threshold multiphoton ionization in intense short-wavelength laser fields: The momentum-space approach and time-dependent generalized pseudospectral method,” Phys. Rev. A 83, 013405 (2011). [CrossRef]
  6. Q. Liao, P. X. Lu, P. F. Lan, W. Cao, and Y. H. Li, “Phase dependence of high-order above-threshold ionization in asymmetric molecules,” Phys. Rev. A 77, 013408 (2008). [CrossRef]
  7. C. Huang, Q. Liao, Y. M. Zhou, and P. X. Lu, “Role of Coulomb focusing on the electron transverse momentum of above-threshold ionization,” Opt. Express 1814293–14300 (2010). [CrossRef] [PubMed]
  8. T. Brabec and F. Krausz, “Intense few-cycle laser fields: Frontiers of nonlinear optics,” Rev. Mod. Phys. 72, 545 (2000). [CrossRef]
  9. T. M. Tong, Z. X. Zhao, and C. D. Lin, “Theory of molecular tunneling ionization,” Phys. Rev. A 66, 033402 (2002). [CrossRef]
  10. D. Pavičić, K. F. Lee, D. M. Rayner, P. B. Corkum, and D. M. Villeneuve, “Direct measurement of the angular dependence of ionization for N2, O2, and CO2 in intense laser fields,” Phys. Rev. Lett. 98, 243001 (2007). [CrossRef] [PubMed]
  11. M. Abu-samha and L. B. Madsen, “Photoelectron angular distributions from polar molecules probed by intense femtosecond lasers,” Phys. Rev. A 82, 043413 (2010). [CrossRef]
  12. G. Lagmago Kamta and A. D. Bandrauk, “Imaging electron molecular orbitals via ionization by intense femtosecond pulses,” Phys. Rev. A 74, 033415 (2006). [CrossRef]
  13. M. Lein, “Molecular imaging using recolliding electrons,” J. Phys. B 40, R135–R173 (2007) [CrossRef]
  14. J. Itatani, J. Levesque, D. Zeidler, H. Niikura, H. Pépin, J. C. Kieffer, P. B. Corkum, and D. M. Villeneuve, “Tomographic imaging of molecular orbitals,” Nature 432, 867–871 (2004). [CrossRef] [PubMed]
  15. M. Meckel, D. Comtois, D. Zeidler, A. Staudte, D. Pavičić, H. C. Bandulet, H. Pépin, J. C. Kieffer, R. D‘̀orner, D. M. Villeneuve, and P. B. Corkum, “Laser-induced electron tunneling and diffraction,” Science 320, 1478–1482 (2008). [CrossRef] [PubMed]
  16. H. Stapelfeldt, “Colloquium: aligning molecules with strong laser pulses,” Rev. Mod. Phys. 75, 543–557 (2003). [CrossRef]
  17. L. Holmegaard, J. H. Nielsen, I. Nevo, and H. Stapelfeldt, “Laser-induced alignment and orientation of quantum-state-selected large molecules,” Phys. Rev. Lett. 102, 023001 (2009). [CrossRef] [PubMed]
  18. K. Oda, M. Hita, S. Minemoto, and H. Sakai, “All-optical molecular orientation,” Phys. Rev. Lett. 104, 213901 (2010). [CrossRef] [PubMed]
  19. D. Shafir, Y. Mairesse, D. M. Villeneuve, P. B. Corkum, and N. Dudovich, “Atomic wavefunctions probed through strong-field light-matter interaction,” Nat. Phys. 5, 412–416 (2009). [CrossRef]
  20. H. Niikura, N. Dudovich, D. M. Villeneuve, and P. B. Corkum, “Mapping molecular orbital symmetry on high-order harmonic generation spectrum using two-color laser fields,” Phys. Rev. Lett. 105, 053003 (2010). [CrossRef] [PubMed]
  21. Y. M. Zhou, C. Huang, A. H. Tong, Q. Liao, and P. X. Lu, “Correlated electron dynamics in nonsequential double ionization by orthogonal two-color laser pulses,” Opt. Express 19, 2301–2308 (2011). [CrossRef] [PubMed]
  22. L. Holmegaard, J. L. Hansen, L. Kalhøj, S. L. Kragh, H. Stapelfeldt, F. Filsinger, J. K‘̀upper, G. Meijer, D. Dimitrovski, M. Abu-samha, C. P. J. Martiny, and L. B. Madsen, “Photoelectron angular distributions from strong-field ionization of oriented molecules,” Nat. Phys. 6, 428–432 (2010). [CrossRef]
  23. D. Dimitrovski, C. P. J. Martiny, and L. B. Madsen, “Strong-field ionization of polar molecules: Stark-shift-corrected strong-field approximation,” Phys. Rev. A 82, 053404 (2010). [CrossRef]
  24. L. V. Keldysh, “Ionization in the field of a strong electromagnetic wave,” Sov. Phys. JETP 20, 1307–1314 (1965).
  25. F. H. M. Faisal, “Multiple absorption of laser photons by atoms,” J. Phys. B 6, L89–L92 (1973). [CrossRef]
  26. H. R. Reiss, “Effect of an intense electromagnetic field on a weakly bound system,” Phys. Rev. A 22, 1786–1813 (1980). [CrossRef]
  27. M. Lewenstein, Ph. Balcou, M. Yu. Ivanov, A. L’Huillier, and P. B. Corkum “Theory of high-harmonic generation by low-frequency laser fields,” Phys. Rev. A 49, 2117–2132 (1994). [CrossRef] [PubMed]
  28. A. Etches and L. B. Madsen, “Extending the strong-field approximation of high-order harmonic generation to polar molecules: gating mechanisms and extension of the harmonic cutoff,” J. Phys. B 43, 155602 (2010). [CrossRef]
  29. C. Figueira de Morisson Faria and B. B. Augstein, “Molecular high-order harmonic generation with more than one active orbital: quantum interference effects,” Phys. Rev. A 81, 043409 (2010). [CrossRef]
  30. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, and J. A. Pople “Gaussian 03, Revision C.02,” Gaussian Inc., Wallingford, CT (2010).
  31. M. F. Ciappina, C. C. Chirilǎ, and M. Lein, “Influence of Coulomb continuum wave functions in the description of high-order harmonic generation with H2+,” Phys. Rev. A 75, 043405 (2007). [CrossRef]
  32. P. B. Corkum, “Plasma perspective on strong-filed multiphoton ionization,” Phys. Rev. Lett. 71, 1994–1997 (2000). [CrossRef]
  33. J. Muth-B‘̀ohm, A. Becker, and F. H. M. Faisal, “Suppressed molecular ionization for a class of diatomics in intense femtosecond laser fields,” Phys. Rev. Lett. 85, 2280 (2000). [CrossRef] [PubMed]

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