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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 19, Iss. 15 — Jul. 18, 2011
  • pp: 14083–14092

White emission of lithium ytterbium tetraphosphate nanocrystals

W. Strek, L. Marciniak, A. Bednarkiewicz, A. Lukowiak, R. Wiglusz, and D. Hreniak  »View Author Affiliations


Optics Express, Vol. 19, Issue 15, pp. 14083-14092 (2011)
http://dx.doi.org/10.1364/OE.19.014083


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Abstract

An efficient anti-Stokes white broadband emission induced by 976 nm laser diode in lithium ytterbium tetraphosphate (LiYbP4O12) nanocrystals was investigated. The emission occurs at room temperature and atmospheric pressure. Its intensity demonstrates an evident threshold dependence on the temperature and excitation density characteristic to avalanche process. The white emission is accompanied by very efficient photoconductivity characterized by microampere photocurrent which increases with the fourth order of applied incident light power (~P4). We show that this emission is critically dependent on temperature and increases significantly in vacuum. It is concluded that the anti-Stokes white emission is associated with theYb3+- CT luminescence.

© 2011 OSA

OCIS Codes
(160.5690) Materials : Rare-earth-doped materials
(190.7220) Nonlinear optics : Upconversion
(300.2530) Spectroscopy : Fluorescence, laser-induced
(160.4236) Materials : Nanomaterials

ToC Category:
Materials

History
Original Manuscript: April 15, 2011
Revised Manuscript: June 6, 2011
Manuscript Accepted: June 26, 2011
Published: July 8, 2011

Virtual Issues
Vol. 6, Iss. 8 Virtual Journal for Biomedical Optics

Citation
W. Strek, L. Marciniak, A. Bednarkiewicz, A. Lukowiak, R. Wiglusz, and D. Hreniak, "White emission of lithium ytterbium tetraphosphate nanocrystals," Opt. Express 19, 14083-14092 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-15-14083


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References

  1. J. A. Gonzalezortega, N. Perea, and G. A. Hirata, “White light emission from Y2SiO5:Ce, Tb films excited by electroluminescence,” Opt. Mater. 29(1), 47–50 (2006). [CrossRef]
  2. B. Wang, L. Sun, and H. Ju, “Luminescence and energy transfer of white-light emitting CaAl2SiO6:Ce3C, Tb3C Phosphors,” Solid State Commun. 150(31-32), 1460–1462 (2010). [CrossRef]
  3. W. Gao, Y. Hu, W. Zhuang, S. Zhang, Y. Liu, and H. He, “A novel method for the synthesis of YAG:Ce phosphor,” J. Rare Earths 27(6), 886–890 (2009). [CrossRef]
  4. S. Sivakumar, F. C. J. M. van Veggel, and M. Raudsepp, “Bright white light through up-conversion of a single NIR source from sol-gel-derived thin film made with Ln3+-doped LaF3 nanoparticles,” J. Am. Chem. Soc. 127(36), 12464–12465 (2005). [CrossRef] [PubMed]
  5. E. C. Fuchs, C. Sommer, F. P. Wenzl, B. Bitschnau, A. H. Paulitsch, A. Mühlanger, and K. Gatterer, “Polyspectral white light emission from Eu3+, Tb3+, Dy3+, Tm3+ co-doped GdAl3(BO3)4 phosphors obtained by combustion synthesis,” Mater. Sci. Eng. B 156(1-3), 73–78 (2009). [CrossRef]
  6. X. Hou, S. Zhou, T. Jia, H. Lin, and H. Teng, “White light emission in Tm3+/Er3+/Yb3+ tri-doped Y2O3 transparent ceramic,” J. Alloy. Comp. 509(6), 2793–2796 (2011). [CrossRef]
  7. F. Lahoz, I. R. Martin, and J. M. Calvilla-Quintero, “Ultraviolet and white photon avalanche upconversion in Ho3+-doped nanophase glass ceramics,” Appl. Phys. Lett. 86(5), 051106 (2005). [CrossRef]
  8. J. Wang and P. A. Tanner, “Upconversion for white light generation by a single compound,” J. Am. Chem. Soc. 132(3), 947–949 (2010). [CrossRef] [PubMed]
  9. J. Wang, J. H. Hao, and P. A. Tanner, “Luminous and tunable white-light upconversion for YAG (Yb3Al5O12) and (Yb,Y)2O3 nanopowders,” Opt. Lett. 35(23), 3922–3924 (2010). [CrossRef] [PubMed]
  10. W. Strek, L. Marciniak, A. Bednarkiewicz, A. Lukowiak, D. Hreniak, and R. Wiglusz, “„The effect of pumping power on fluorescence behavior of LiNdP4O12 nanocrystals,” Opt. Mater. , doi:. [CrossRef]
  11. L. Marciniak, W. Strek, A. Bednarkiewicz, A. Lukowiak, and D. Hreniak, “„Bright upconversion emission of Nd3 + in LiLa1-xNdxP4O12 nanocrystalline powders,” Opt. Mater. , doi:. [CrossRef]
  12. R. J. Wiglusz, R. Pazik, A. Lukowiak, and W. Strek, “Synthesis, structure, and optical properties of LiEu(PO3)4 nanoparticles,” Inorg. Chem. 50(4), 1321–1330 (2011). [CrossRef] [PubMed]
  13. S. Guy, M. F. Joubert, and B. Jacquier, “Photon avalanche and the mean-field approximation,” Phys. Rev. B 55(13), 8240–8248 (1997). [CrossRef]
  14. M. F. Joubert, “Photon avalanche upconversion in rare earth laser materials,” Opt. Mater. 11(2-3), 181–203 (1999). [CrossRef]
  15. L. D. Landau and I. M. Lifshitz, Course of Theoretical Physics, vol.5 (Pergamon Press, 1959).
  16. F. Auzel, “Multiphonon-assisted anti-Stokes and Stokes fluorescence of triply ionized rare-earth ions,” J. Lumin. 12–13, 715–722 (1976). [CrossRef]
  17. F. Auzel and Y. Chen, “Photon avalanche luminescence of Er3+ ions in LiYF4 crystal,” J. Lumin. 65(1), 45–56 (1995). [CrossRef]
  18. T. Miyakawa and D. L. Dexter, “Phonon Sidebands, Multiphonon Relaxation of Excited States, and Phonon-Assisted Energy Transfer between Ions in Solids,” Phys. Rev. B 1(7), 2961–2969 (1970). [CrossRef]
  19. P. G. Klemens and M. Gell, “Thermal conductivity of thermal barrier coatings,” Mater. Sci. Eng. A 245(2), 143–149 (1998). [CrossRef]
  20. J. Nakano, “Thermal properties of solid-state laser crystal LiNdP4O12,” J. Appl. Phys. 52(3), 1239–1243 (1981). [CrossRef]
  21. F. D. Patel, E. C. Honea, J. Speth, S. A. Payne, R. Hutcheson, and R. Equall, “Laser demonstration of Yb3Al5O12 (YbAG) and materials properties of highly doped Yb: YAG,” Quantum 37(1), 135–144 (2001). [CrossRef]
  22. P. Dorenbos, T. Shalapska, G. Stryganyuk, A. Gektin, and A. Voloshinovskii, “„Spectroscopy and energy level location of the trivalent lanthanides in LiYP4O12,” J. Lumin. 131(4), 633–639 (2011). [CrossRef]
  23. M. Miah, “One-, two-, and three-photon processes in CdI2 crystal,” Opt. Mater. 25(4), 353–357 (2004). [CrossRef]
  24. C. Brandt, S. T. Fredrich-Thornton, K. Petermann, and G. Huber, “Photoconductivity in Yb-doped oxides at high excitation densities,” Appl. Phys. B 102(4), 765–768 (2011). [CrossRef]
  25. R. K. Verma, A. Rai, K. Kumar, and S. B. Rai, “Up and down conversion fluorescence studies on combustion synthesized Yb3+/Yb2+: MO-Al2O3 (M = Ca, Sr and Ba) phosphors,” J. Lumin. 130(7), 1248–1253 (2010). [CrossRef]
  26. S. Redmond, S. C. Rand, X. L. Ruan, and M. J. Kaviany, “Multiple scattering and nonlinear thermal emission of Yb3+, Er3+:Y2O3 nanopowders,” J. Appl. Phys. 95(8), 4069–4077 (2004). [CrossRef]
  27. C. Joshi, K. Kumar, and S. B. Rai, “Intense white luminescence from combustion synthesized Ca12Al14O33:Yb3+/Yb2+ single phase phosphor,” J. Fluoresc. 20(4), 953–959 (2010). [CrossRef] [PubMed]
  28. G. Stryganyuk, S. Zazubovich, A. Voloshinovskii, M. Pidzyrailo, G. Zimmerer, R. Peters, and K. Petermann, “„Charge transfer luminescence of Yb3+ ions in LiY1-xYbxP4O14 phosphates,” J. Phys. Condens. Matter 19(3), 036202 (2007). [CrossRef]
  29. U. Happek, A. A. Basun, J. Choi, J. K. Krebs, and M. Raukas, “Electron transfer processes in rare earth doped insulators,” J. Alloy. Comp. 303-304(1-2), 198–206 (2000). [CrossRef]

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