Yellow-emitting NaCaPO<sub>4</sub>:Mn<sup>2+</sup> phosphor for field emission displays

doi:10.1364/OE.19.016423

Yellow-emitting NaCaPO₄:Mn²⁺ phosphor for field emission displays

Guogang Li, Xingong Xu, Chong Peng, Mengmeng Shang, Dongling Geng, Ziyong Cheng, Jun Chen, and Jun Lin »View Author Affiliations

Optics Express, Vol. 19, Issue 17, pp. 16423-16431 (2011)
http://dx.doi.org/10.1364/OE.19.016423

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Abstract

Yellow-emitting NaCaPO₄:Mn²⁺ phosphors were prepared by the Pechini sol-gel process. Under low voltage electron beam excitation, the NaCaPO₄: Mn²⁺ phosphor screen shows bright yellow emission (centering at 560 nm due to the ⁴T₁→⁶A₁ transition of Mn²⁺) with the CIE color coordinate (0.428, 0.552), which has a higher color purity than commercial yellow-emitting FED phosphor (Zn, CdS):Ag⁺. The color range and chromaticity saturation may be greatly enhanced when the yellow-emitting NaCaPO₄: Mn²⁺ is added as an additional phosphor of the typical tricolor FEDs phosphors, which make them have potential to improve the display quality of full-color FEDs.

OCIS Codes
(160.2540) Materials : Fluorescent and luminescent materials
(160.4760) Materials : Optical properties
(300.6280) Spectroscopy : Spectroscopy, fluorescence and luminescence

ToC Category:
Materials

History
Original Manuscript: May 26, 2011
Revised Manuscript: July 12, 2011
Manuscript Accepted: July 17, 2011
Published: August 11, 2011

Citation
Guogang Li, Xingong Xu, Chong Peng, Mengmeng Shang, Dongling Geng, Ziyong Cheng, Jun Chen, and Jun Lin, "Yellow-emitting NaCaPO₄:Mn²⁺ phosphor for field emission displays," Opt. Express 19, 16423-16431 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-17-16423

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References

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Chalamala, B.
Chan, T. S.
Chen, J.
Choi, Y. G.
Choi, Y. Y.
Cocivera, M.
Deng, S. Z.
Dhoble, S. J.
Dierre, B.
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Gnade, B.
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Hao, J.
Hao, J. H.
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Huang, Y. L.
Inoue, K.
Jia, G.
Jiang, Y. D.
Jüstel, T.
Kai, W.
Ke, W. C.
Kumar, A.
Li, H.
Liang, H. B.
Lin, C. C.
Lin, J.
Liu, K.
Liu, R. S.
Liu, X. M.
Nikol, H.
Park, H. D.
Penczek, J.
Psuja, P.
Ronda, C.
Sekiguchi, T.
Seo, H. J.
Sharma, A. K.
Shi, L.
Shinde, K. N.
Sohn, K. S.
Son, K. H.
Song, Y. H.
Stoffers, C.
Strek, W.
Su, Q.
Summers, C. J.
Tamura, K.
Tang, J. K.
Wagner, B. K.
Wang, J.
Wang, Z.
Wang, Z. L.
Wei, Y.
Xiao, Z. R.
Xie, M. B.
Xie, R. J.
Xu, N. S.
Xu, S.
Xu, X. G.
Yang, M.
Yang, S.
Yang, S.-H.
Yeh, C. W.
Yocom, P. N.
Yokoyama, M.
You, H. P.
Zaremba, D.
Zhang, F.-L.
Zhang, H. J.
Zhang, Q. H.
Zhang, S.
Zheng, Y. H.

Acta Mater.

Q. H. Zhang, J. Wang, C. W. Yeh, W. C. Ke, R. S. Liu, J. K. Tang, M. B. Xie, H. B. Liang, and Q. Su, “Structure, composition, morphology, photoluminescence and cathodoluminescence properties of ZnGeN2 and ZnGeN2:Mn2+ for field emission displays,” Acta Mater. 58(20), 6728–6735 (2010). [CrossRef]

Adv. Funct. Mater.

A. K. Sharma, K. H. Son, B. Y. Han, and K. S. Sohn, “Simultaneous Optimization of Luminance and Color Chromaticity of Phosphors Using a Nondominated Sorting Genetic Algorithm,” Adv. Funct. Mater. 20(11), 1750–1755 (2010). [CrossRef]

Angew. Chem. Int. Ed.

T. Jüstel, H. Nikol, and C. Ronda, “New Developments in the Field of Luminescent Materials for Lighting and Displays,” Angew. Chem. Int. Ed. 37(22), 3084–3103 (1998). [CrossRef]

Appl. Phys. Lett.

X. M. Liu and J. Lin, “Nanocrystalline LaGaO3:Tm3+ as an efficient blue phosphor for field emission displays with high color purity,” Appl. Phys. Lett. 90(18), 184108 (2007). [CrossRef]
Y. D. Jiang, F.-L. Zhang, C. J. Summers, and Z. L. Wang, “Synthesis and properties of Sr2CeO4 blue emission powder phosphor for field emission displays,” Appl. Phys. Lett. 74(12), 1677–1679 (1999). [CrossRef]
J. H. Hao, J. Gao, and M. Cocivera, “Green, blue, and yellow cathodoluminescence of Ba2B5O9Cl thin-films doped with Tb3+, Tm3+, and Mn2+,” Appl. Phys. Lett. 82, 2224–2226 (2003). [CrossRef]
J. H. Hao, J. Gao, and M. Cocivera, “Tuning of the blue emission from europium-doped alkaline earth chloroborate thin films activated in air,” Appl. Phys. Lett. 82(17), 2778–2780 (2003). [CrossRef]
N. Hirosaki, R. J. Xie, K. Inoue, T. Sekiguchi, B. Dierre, and K. Tamura, “Blue-emitting AlN:Eu2+ phosphors for field emission displays,” Appl. Phys. Lett. 91(6), 061101 (2007). [CrossRef]
F.-L. Zhang, S. Yang, C. Stoffers, J. Penczek, P. N. Yocom, D. Zaremba, B. K. Wagner, and C. J. Summers, “Low voltage cathodoluminescence properties of blue emitting SrGa2S4:Ce3+ and ZnS:Ag,Cl phosphors,” Appl. Phys. Lett. 72(18), 2226–2228 (1998). [CrossRef]

Electrochem. Solid-State Lett.

S. Zhang, Y. Huang, W. Kai, L. Shi, and H. J. Seo, “Tunable red luminescence of Mn2+ -doped NaCaPO4 phosphors,” Electrochem. Solid-State Lett. 13(2), J11–J14 (2010). [CrossRef]

Eur. J. Inorg. Chem.

N. Guo, Y. H. Song, H. P. You, G. Jia, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “Optical Properties and Energy Transfer of NaCaPO4:Ce3+,Tb3+ Phosphors for Potential Application in Light-Emitting Diodes,” Eur. J. Inorg. Chem. 2010(29), 4636–4642 (2010). [CrossRef]

IEEE Spectr.

B. Chalamala, Y. Wei, and B. Gnade, “FED up with fat tubes,” IEEE Spectr. 35(4), 42–51 (1998). [CrossRef]

J. Am. Chem. Soc.

C. C. Lin, Z. R. Xiao, G. Y. Guo, T. S. Chan, and R. S. Liu, “Versatile phosphate phosphors ABPO(4) in white light-emitting diodes: collocated characteristic analysis and theoretical calculations,” J. Am. Chem. Soc. 132(9), 3020–3028 (2010). [CrossRef] [PubMed]

J. Electrochem. Soc.

H. Li, Z. Wang, S. Xu, and J. Hao, “Improved Performance of Spherical BaWO4: Tb3+ Phosphors for Field-Emission Displays,” J. Electrochem. Soc. 156(5), J112–J116 (2009). [CrossRef]
K. S. Sohn, Y. G. Choi, Y. Y. Choi, and H. D. Park, “Energy transfer between Tb3+ ions in YAlO3 host,” J. Electrochem. Soc. 147(9), 3552–3558 (2000). [CrossRef]

J. Mater. Chem.

X. M. Liu and J. Lin, “LaGaO3:A (A = Sm3+ and/or Tb3+) as promising phosphors for field emission displays,” J. Mater. Chem. 18(2), 221–228 (2007). [CrossRef]

J. Nanomater.

P. Psuja, D. Hreniak, and W. Strek, “Rare-earth doped nanocrystalline phosphors for field emission displays,” J. Nanomater. 2007, 81350 (2007). [CrossRef]

J. Phys. Chem. A

L. Shi, Y. L. Huang, and H. J. Seo, “Emission red shift and unusual band narrowing of Mn2+ in NaCaPO4 phosphor,” J. Phys. Chem. A 114(26), 6927–6934 (2010). [CrossRef] [PubMed]

J. Vac. Sci. Technol. A

S.-H. Yang and M. Yokoyama, “Enhanced luminance of ZnGa2O4 phosphor by In2O3 doping,” J. Vac. Sci. Technol. A 19(5), 2463–2467 (2001). [CrossRef]

J. Vac. Sci. Technol. B

X. G. Xu, J. Chen, S. Z. Deng, N. S. Xu, and J. Lin, “Cathodoluminescent properties of nanocrystalline Lu3Ga5O12:Tb3+ phosphor for field emission display application,” J. Vac. Sci. Technol. B 28(3), 490–494 (2010). [CrossRef]

Phys. Rev.

C. Feldman, “Range of 1-10 kev Electrons in Solids,” Phys. Rev. 117(2), 455–459 (1960). [CrossRef]

Physica B

K. N. Shinde, S. J. Dhoble, and A. Kumar, “Photoluminescence studies of NaCaPO4:RE (RE=Dy3+, Mn2+ or Gd3+),” Physica B 406(1), 94–99 (2011). [CrossRef]

Other

G. Blasse and B. C. Grabmaier, Luminescence Materials (Springer-Verlag, Berlin and Heideberg, 1994), ch. 4–5.

2011, Shinde, Physica B
2010, Zhang, Electrochem. Solid-State Lett.
2010, Guo, Eur. J. Inorg. Chem.
2010, Zhang, Acta Mater.
2010, Lin, J. Am. Chem. Soc.
2010, Sharma, Adv. Funct. Mater.
2010, Shi, J. Phys. Chem. A
2010, Xu, J. Vac. Sci. Technol. B
2009, Li, J. Electrochem. Soc.
2007, Liu, Appl. Phys. Lett.
2007, Hirosaki, Appl. Phys. Lett.
2007, Psuja, J. Nanomater.
2007, Liu, J. Mater. Chem.
2003, Hao, Appl. Phys. Lett.
2003, Hao, Appl. Phys. Lett.
2001, Yang, J. Vac. Sci. Technol. A
2000, Sohn, J. Electrochem. Soc.
1999, Jiang, Appl. Phys. Lett.
1998, Zhang, Appl. Phys. Lett.
1998, Chalamala, IEEE Spectr.
1998, Jüstel, Angew. Chem. Int. Ed.
1960, Feldman, Phys. Rev.

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