OSA's Digital Library

Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 19, Iss. 5 — Feb. 28, 2011
  • pp: 4310–4315

Fluorescence and phosphorescence properties of new long-lasting phosphor Ba4(Si3O8)2:Eu2+, Dy3+

Yu Gong, Yuhua Wang, Yanqin Li, Xuhui Xu, and Wei Zeng  »View Author Affiliations


Optics Express, Vol. 19, Issue 5, pp. 4310-4315 (2011)
http://dx.doi.org/10.1364/OE.19.004310


View Full Text Article

Enhanced HTML    Acrobat PDF (1046 KB)





Browse Journals / Lookup Meetings

Browse by Journal and Year


   


Lookup Conference Papers

Close Browse Journals / Lookup Meetings

Article Tools

Share
Citations

Abstract

A novel long-lasting phosphorescence (LLP) material Ba4(Si3O8)2:Eu2+, Dy3+ with high chemical stability was achieved successfully. Two emission centers (Eu (I) and Eu (II)) were found in Ba4(Si3O8)2 due to the substitution of Eu2+ in different Ba2+ sites. Both Eu (I) and Eu (II) had contribution to the afterglow process, however, the decay rate of Eu (I) was higher than that of Eu (II). Ba3.982(Si3O8)2: 0.008Eu2+, 0.01Dy3+ exhibited a long-lasting phosphorescence whose duration was more than 24 h. Through the analysis of the thermoluminescence (TL) curves, we found that Eu2+ single doped Ba4(Si3O8)2 has a possibility to be a kind of storage phosphor. This work provides a new and efficient candidate for LLP and storage materials.

© 2011 OSA

OCIS Codes
(160.4670) Materials : Optical materials
(160.4760) Materials : Optical properties
(250.5230) Optoelectronics : Photoluminescence

ToC Category:
Materials

History
Original Manuscript: December 7, 2010
Revised Manuscript: February 10, 2011
Manuscript Accepted: February 10, 2011
Published: February 18, 2011

Citation
Yu Gong, Yuhua Wang, Yanqin Li, Xuhui Xu, and Wei Zeng, "Fluorescence and phosphorescence properties of new long-lasting phosphor Ba4(Si3O8)2:Eu2+, Dy3+," Opt. Express 19, 4310-4315 (2011)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-19-5-4310


Sort:  Author  |  Year  |  Journal  |  Reset  

References

  1. S. Lian, Y. Qi, C. Rong, L. Yu, A. Zhu, D. Yin, and S. Liu, “Effectively Leveraging Solar Energy through Persistent Dual Red Phosphorescence:Preparation, Characterization, and Density Functional Theory Study of Ca2Zn4Ti16O38:Pr3+,” J. Phys. Chem. C 114(15), 7196–7204 (2010). [CrossRef]
  2. T. Matsuzawa, Y. Aoki, N. Takeuchi, and Y. Murayama, “A new long phosphorescent phosphor with high brightness, SrAl2O4: Eu2+, Dy3+,” J. Electrochem. Soc. 143(8), 2670 (1996). [CrossRef]
  3. M. Kowatari, D. Koyama, Y. Satoh, K. Iinuma, and S. Uchida, “The temperature dependence of luminescence from a long-lasting phosphor exposed to ionizing radiation,” Nucl. Instrum. Methods Phys. Res. A 480(2-3), 431–439 (2002). [CrossRef]
  4. C.-N. Xu, T. Watanabe, M. Akiyama, and X.-G. Zheng, “Direct view of stress distribution in solids by mechanoluminescence,” Appl. Phys. Lett. 74(17), 2414–2416 (1999). [CrossRef]
  5. C.-N. Xu, X.-G. Zheng, M. Akiyama, K. Nonaka, and T. Watanabe, “Dynamic visualization of stress distribution by mechanoluminescence image,” Appl. Phys. Lett. 76(2), 179–181 (2000). [CrossRef]
  6. M. Akiyama, C.-N. Xu, Y. Liu, K. Nonaka, and T. Watanabe, “Influence of Eu, Dy co-doped strontium aluminate composition on mechanoluminescence intensity,” J. Lumin. 97(1), 13–18 (2002). [CrossRef]
  7. H. Aizawa, T. Katsumata, J. Takahashi, K. Matsunaga, S. Komuro, T. Morikawa, and E. Toba, “Fiber-optic thermometer using afterglow phosphorescence from long duration phosphor,” Electrochem. Solid-State Lett. 5(9), H17–H19 (2002). [CrossRef]
  8. T. L. Barry, “Fluorescence of Eu2+ activated phase in binary alkaline earth orthosilicate systems,” J. Electrochem. Soc. 115(11), 1181 (1968). [CrossRef]
  9. Y. Lin, Z. Tang, Z. Zhang, X. Wang, and J. Zhang, “Preparation of a new long afterglow blue-emitting Sr2MgSi2O7-based photoluminescent phosphor,” J. Mater. Sci. Lett. 20(16), 1505–1506 (2001). [CrossRef]
  10. Y. Lin, Z. Zhang, Z. Tang, X. Wang, and Z. Zheng, “Luminescent properties of a new long afterglow Eu2+ and Dy3+ activated Ca3MgSi2O8 phospho,” J. Eur. Ceram. Soc. 21(5), 683–685 (2001). [CrossRef]
  11. C. Shi, Y. Fu, B. Liu, G. Zhang, Y. Chen, Z. Qi, and X. Luo, “The roles of Eu2+ and Dy3+ in the blue long-lasting phosphor Sr2MgSi2O7: Eu2+, Dy3+,” J. Lumin. 122–123, 11–13 (2007). [CrossRef]
  12. L. Jiang, C. Chang, D. Mao, and C. Feng, “Luminescent properties of Ca2MgSi2O7 phosphor activated by Eu2+, Dy3+ and Nd3+,” Opt. Mater. 27(1), 51–55 (2004). [CrossRef]
  13. G. Blasse, and B. C. Grabmaier, Luminescent Materials (Springer, 1994).
  14. K.-F. Hesse and F. Liebau, “Crystal chemistry of silica-rich Barium silicates,” Z. Kristallogr. 153(1_2), 3–17 (1980). [CrossRef]
  15. B. Henderson, and G. G. Imbush, Optical Spectroscopy of Inorganic Solids (Clarendon, 1989).
  16. Y. Lin, Z. Tang, Z. Zhang, and C. W. Nan, “Anomalous luminescence in Sr4Al14O25:Eu, Dy phosphors,” Appl. Phys. Lett. 81(6), 996 (2002). [CrossRef]
  17. T. Kinoshita, M. Yamazaki, H. Kawazoe, and H. Hosono, “Long lasting phosphorescence and photostimulated luminescence in Tb-ion-activated reduced calcium aluminate glasses,” J. Appl. Phys. 86(7), 3729 (1999). [CrossRef]
  18. T. Aitasalo, P. Deren, J. Hölsä, H. Junger, J.-C. Krupa, M. Lastusaari, J. Legendziewicz, J. Niittykoski, and W. Strek, “Persistent luminescence phenomena in materials doped with rare earth ions,” J. Solid State Chem. 171(1-2), 114–122 (2003). [CrossRef]
  19. S. Schweizer, “Physics and Current Understanding of X-Ray Storage Phosphors,” Phys. Status Solidi A 187(2), 335–393 (2001). [CrossRef]
  20. W. Chen, “Luminescence, Storage Mechanisms, and Applications of X-Ray Storage Phosphors.” In Handbook of Luminescence, Display Materials and Devices; H. S. Nalwa, L. S. Rohwer, eds. (American Scientific Publishers, 2003); Vol. 2, pp 1–44.

Cited By

Alert me when this paper is cited

OSA is able to provide readers links to articles that cite this paper by participating in CrossRef's Cited-By Linking service. CrossRef includes content from more than 3000 publishers and societies. In addition to listing OSA journal articles that cite this paper, citing articles from other participating publishers will also be listed.

Figures

Fig. 1 Fig. 2 Fig. 3
 
Fig. 4 Fig. 5
 

« Previous Article  |  Next Article »

OSA is a member of CrossRef.

CrossCheck Deposited