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High-order nonlinear optical response of a polymer nanocomposite film incorporating semiconducotor CdSe quantum dotsXiangming Liu, Yusuke Adachi, Yasuo Tomita, Juro Oshima, Takuya Nakashima, and Tsuyoshi Kawai »View Author Affiliations
Xiangming Liu,1
Yusuke Adachi,1
Yasuo Tomita,1,*
Juro Oshima,2
Takuya Nakashima,3
and Tsuyoshi Kawai3
1Department of Electronics Engineering, University of Electro-Communications, 1-5-1 Chofugaoka, Chofu, Tokyo 182-8585, Japan 2Chemical Research Laboratories, Nissan Chemical Industries, Ltd., 2-10-1 Tsuboinishi Funabashi, Chiba 274-8507, Japan 3Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan *Corresponding author: ytomita@uec.ac.jp |
Optics Express, Vol. 20, Issue 12, pp. 13457-13469 (2012)
http://dx.doi.org/10.1364/OE.20.013457
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Abstract
We report on observation of high-order optical nonlinearities in our recently developed photopolymerizable semiconductor CdSe quantum dot (QD)-polymer nanocomposite films at various volume fractions of CdSe QDs as high as 0.91 vol.% (3.6 wt.%). We performed Z-scan and degenerate multi-wave mixing (DMWM) measurements using a 532-nm picosecond laser delivering single 35 ps pulses at a repetition rate of 10 Hz. Using the uniformly cured polymer nanocomposite films, we observed the third- and fifth-order nonlinear optical effects in closed-aperture Z-scan measurements by which it was found that saturable nonlinear absorption (light-induced transparency) and large negative nonlinear refraction were induced. We also measured dependences of the effective third- and fifth-order nonlinear refraction constants on CdSe QD volume fraction. Based on the Maxwell-Garnett model, we estimated the third- and fifth-order nonlinear optical susceptibilities of CdSe QD and discussed a contribution of the third-order effect to the fifth-order one due to the cascaded (local-field) effect. Coexistence of the third- and fifth-order nonlinear refraction was also confirmed by DMWM.
© 2012 OSA
OCIS Codes
(160.4330) Materials : Nonlinear optical materials
(160.5470) Materials : Polymers
(160.6000) Materials : Semiconductor materials
(190.4400) Nonlinear optics : Nonlinear optics, materials
(190.5970) Nonlinear optics : Semiconductor nonlinear optics including MQW
(190.4223) Nonlinear optics : Nonlinear wave mixing
(160.4236) Materials : Nanomaterials
(160.5335) Materials : Photosensitive materials
ToC Category:
Nonlinear Optics
History
Original Manuscript: April 3, 2012
Revised Manuscript: April 30, 2012
Manuscript Accepted: April 30, 2012
Published: May 31, 2012
Citation
Xiangming Liu, Yusuke Adachi, Yasuo Tomita, Juro Oshima, Takuya Nakashima, and Tsuyoshi Kawai, "High-order nonlinear optical response of a polymer nanocomposite film incorporating semiconducotor CdSe quantum dots," Opt. Express 20, 13457-13469 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-12-13457
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