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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 20, Iss. 13 — Jun. 18, 2012
  • pp: 14596–14603

Three-photon-absorption-induced optical stabilization effects in a bifluorenylidene derivative

Junhui Liu and Yuanxu Wang  »View Author Affiliations


Optics Express, Vol. 20, Issue 13, pp. 14596-14603 (2012)
http://dx.doi.org/10.1364/OE.20.014596


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Abstract

A bifluorenylidene derivative with extended π-conjugated system has been designed and successfully synthesized. The compound displays strong three-photon absorption effect. The obtained three-photon absorption cross section is as high as 81.3 × 10−76 cm6s2. Distinguished 3PA-induced optical limiting and optical stabilization performances have been achieved. The on-axis transmitted intensity approached a constant even though the incident laser pulse fluctuation was 300%.

© 2012 OSA

OCIS Codes
(190.4400) Nonlinear optics : Nonlinear optics, materials
(190.4710) Nonlinear optics : Optical nonlinearities in organic materials

ToC Category:
Nonlinear Optics

History
Original Manuscript: May 4, 2012
Manuscript Accepted: May 18, 2012
Published: June 15, 2012

Citation
Junhui Liu and Yuanxu Wang, "Three-photon-absorption-induced optical stabilization effects in a bifluorenylidene derivative," Opt. Express 20, 14596-14603 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-13-14596


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References

  1. S. Maiti, J. B. Shear, R. M. Williams, W. R. Zipfel, and W. W. Webb, “Measuring serotonin distribution in live cells with three-photon excitation,” Science275(5299), 530–532 (1997). [CrossRef] [PubMed]
  2. J. M. Leeder and D. L. Andrews, “A molecular theory for two-photon and three-photon fluorescence polarization,” J. Chem. Phys.134(9), 094503 (2011). [CrossRef] [PubMed]
  3. K. D. Belfield, M. V. Bondar, F. E. Hernández, O. V. Przhonska, X. Wang, and S. Yao, “A superfluorescent fluorenyl probe with efficient two-photon absorption,” Phys. Chem. Chem. Phys.13(10), 4303–4310 (2011). [CrossRef] [PubMed]
  4. G. S. He, P. P. Markowicz, T. C. Lin, and P. N. Prasad, “Observation of stimulated emission by direct three-photon excitation,” Nature415(6873), 767–770 (2002). [CrossRef] [PubMed]
  5. K. D. Belfied, M. V. Bondar, C. O. Yanez, F. E. Hernández, and O. V. Przhonska, “Two-photon absorption and lasing properties of new fluorene derivatives,” J. Mater. Chem.19(40), 7498–7502 (2009). [CrossRef]
  6. P. L. Wu, X. J. Feng, H. L. Tam, M. S. Wong, and K. W. Cheah, “Efficient three-photon excited deep blue photoluminescence and lasing of diphenylamino and 1,2,4-triazole endcapped oligofluorenes,” J. Am. Chem. Soc.131(3), 886–887 (2009). [CrossRef] [PubMed]
  7. X. J. Feng, P. L. Wu, K. F. Li, M. S. Wong, and K. W. Cheah, “Highly efficient multiphoton-absorbing quadrupolar oligomers for frequency upconversion,” Chemistry17(8), 2518–2526 (2011). [PubMed]
  8. G. S. He, J. D. Bhawalkar, P. N. Prasad, and B. A. Reinhardt, “Three-photon-absorption-induced fluorescence and optical limiting effects in an organic compound,” Opt. Lett.20(14), 1524–1526 (1995). [CrossRef] [PubMed]
  9. Y. Morel, A. Irimia, P. Najechalski, Y. Kervella, O. Stephan, P. L. Baldeck, and C. Andraud, “Two-photon absorption and optical power limiting of bifluorene molecule,” J. Chem. Phys.114(12), 5391–5396 (2001). [CrossRef]
  10. I. Cohanoschi, L. Echeverría, and F. E. Hernández, “Three-photon absorption measurements in hematoporphyrin IX: “Ground-breaking opportunities in deep photodynamic therapy,” Chem. Phys. Lett.419(1-3), 33–36 (2006). [CrossRef]
  11. L. Y. Zhu, Y. P. Yi, Z. G. Shuai, J. L. Brédas, D. Beljonne, and E. Zojer, “Structure-property relationships for three-photon absorption in stilbene-based dipolar and quadrupolar chromophores,” J. Chem. Phys.125(4), 044101 (2006). [CrossRef] [PubMed]
  12. Y. P. Yi, L. Y. Zhu, and Z. G. Shuai, “The correction vector method for three-photon absorption: The effects of π conjugation in extended rylenebis(dicarboximide)s,” J. Chem. Phys.125(16), 164505 (2006). [CrossRef] [PubMed]
  13. P. Cronstrand, Y. Luo, P. Norman, and H. Àgren, “Ab initio calculations of three-photon absorption,” Chem. Phys. Lett.375(1-2), 233–239 (2003). [CrossRef]
  14. P. C. Jha, Y. Luo, I. Polyzos, P. Persephonis, and H. Ågren, “Two- and three-photon absorption of organic ionic pyrylium based materials,” J. Chem. Phys.130(17), 174312 (2009). [CrossRef] [PubMed]
  15. I. Wang, M. Bouriau, P. L. Baldeck, C. Martineau, and C. Andraud, “Three-dimensional microfabrication by two-photon-initiated polymerization with a low-cost microlaser,” Opt. Lett.27(15), 1348–1350 (2002). [CrossRef] [PubMed]
  16. S. Delysse, P. Filloux, V. Dumarcher, C. Fiouini, and J. M. Nunzi, “Multiphoton absorption in organic dye solutions,” Opt. Mater.9(1-4), 347–351 (1998). [CrossRef]
  17. J. H. Liu, Y. L. Mao, Y. Z. Gu, M. J. Huang, W. F. Zhang, L. J. Guo, and W. B. Ma, “Large irradiance limiting induced by three-photon absorption of a symmetrical fluorene-based molecule,” Opt. Express16(7), 4739–4746 (2008). [CrossRef] [PubMed]

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