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Optics Express

Optics Express

  • Editor: C. Martijn de Sterke
  • Vol. 20, Iss. 14 — Jul. 2, 2012
  • pp: 15781–15796

Plasmon nanoparticle superlattices as optical-frequency magnetic metamaterials

Hadiseh Alaeian and Jennifer A. Dionne  »View Author Affiliations


Optics Express, Vol. 20, Issue 14, pp. 15781-15796 (2012)
http://dx.doi.org/10.1364/OE.20.015781


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Abstract

Nanocrystal superlattices have emerged as a new platform for bottom-up metamaterial design, but their optical properties are largely unknown. Here, we investigate their emergent optical properties using a generalized semi-analytic, full-field solver based on rigorous coupled wave analysis. Attention is given to superlattices composed of noble metal and dielectric nanoparticles in unary and binary arrays. By varying the nanoparticle size, shape, separation, and lattice geometry, we demonstrate the broad tunability of superlattice optical properties. Superlattices composed of spherical or octahedral nanoparticles in cubic and AB2 arrays exhibit magnetic permeabilities tunable between 0.2 and 1.7, despite having non-magnetic constituents. The retrieved optical parameters are nearly polarization and angle-independent over a broad range of incident angles. Accordingly, nanocrystal superlattices behave as isotropic bulk metamaterials. Their tunable permittivities, permeabilities, and emergent magnetism may enable new, bottom-up metamaterials and negative index materials at visible frequencies.

© 2012 OSA

OCIS Codes
(160.4760) Materials : Optical properties
(240.6680) Optics at surfaces : Surface plasmons
(160.3918) Materials : Metamaterials
(160.4236) Materials : Nanomaterials
(250.5403) Optoelectronics : Plasmonics
(050.6624) Diffraction and gratings : Subwavelength structures

ToC Category:
Metamaterials

History
Original Manuscript: April 16, 2012
Revised Manuscript: June 16, 2012
Manuscript Accepted: June 19, 2012
Published: June 27, 2012

Citation
Hadiseh Alaeian and Jennifer A. Dionne, "Plasmon nanoparticle superlattices as optical-frequency magnetic metamaterials," Opt. Express 20, 15781-15796 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-14-15781


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