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Enhanced optical absorption of dye-sensitized solar cells with microcavity-embedded TiO2 photoanodesDa-Wei Liu, I-Chun Cheng, Jian Z. Chen, Hsin-Wei Chen, Kuo-Chuan Ho, and Chin-Cheng Chiang »View Author Affiliations
Da-Wei Liu,1
I-Chun Cheng,1,*
Jian Z. Chen,2
Hsin-Wei Chen,3
Kuo-Chuan Ho,3
and Chin-Cheng Chiang1
1Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei 10617, Taiwan 2Institute of Applied Mechanics, National Taiwan University, Taipei 10617, Taiwan 3Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan *Corresponding author: ichuncheng@cc.ee.ntu.edu.tw |
Optics Express, Vol. 20, Issue S2, pp. A168-A176 (2012)
http://dx.doi.org/10.1364/OE.20.00A168
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Abstract
This paper reports the enhanced performance of dye-sensitized solar cells (DSSCs) with microcavity-embedded nanoporous TiO2 photoanodes. For DSSCs with photoanodes composed of a stack TiO2 sublayers with microcavity concentrations arranged from low to high on the light illumination path, the short-circuit current density and the conversion efficiency were improved. A pronounced increase in optical absorption and incident monochromatic photon-to-current conversion efficiency in the long-wavelength region indicated that the enhancement of cell performance was due to the multiple scattering of light by the microcavities and the light confinement by the stack of TiO2 sublayers with a high-to-low effective index of refraction.
© 2012 OSA
OCIS Codes
(040.5350) Detectors : Photovoltaic
(350.6050) Other areas of optics : Solar energy
ToC Category:
Photovoltaics
History
Original Manuscript: July 1, 2011
Revised Manuscript: November 2, 2011
Manuscript Accepted: December 5, 2011
Published: January 9, 2012
Citation
Da-Wei Liu, I-Chun Cheng, Jian Z. Chen, Hsin-Wei Chen, Kuo-Chuan Ho, and Chin-Cheng Chiang, "Enhanced optical absorption of dye-sensitized solar cells with microcavity-embedded TiO2 photoanodes," Opt. Express 20, A168-A176 (2012)
http://www.opticsinfobase.org/oe/abstract.cfm?URI=oe-20-S2-A168
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References
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- L. H. Hu, S. Y. Dai, J. Weng, S. F. Xiao, Y. F. Sui, Y. Huang, S. H. Chen, F. T. Kong, X. Pan, L. Y. Liang, and K. J. Wang, “Microstructure design of nanoporous TiO2 photoelectrodes for dye-sensitized solar cell modules,” J. Phys. Chem. B111(2), 358–362 (2007). [CrossRef] [PubMed]
- C.-P. Hsu, K.-M. Lee, J. T.-W. Huang, C.-Y. Lin, C.-H. Lee, L.-P. Wang, S.-Y. Tsai, and K.-C. Ho, “EIS analysis on low temperature fabrication of TiO2 porous films for dye-sensitized solar cells,” Electrochim. Acta53(25), 7514–7522 (2008). [CrossRef]
- L. H. Hu, S. Y. Dai, J. Weng, S. F. Xiao, Y. F. Sui, Y. Huang, S. H. Chen, F. T. Kong, X. Pan, L. Y. Liang, and K. J. Wang, “Microstructure design of nanoporous TiO2 photoelectrodes for dye-sensitized solar cell modules,” J. Phys. Chem. B111(2), 358–362 (2007). [CrossRef] [PubMed]
- S. Ito, S. M. Zakeeruddin, R. Humphry-Baker, P. Liska, R. Charvet, P. Comte, M. K. Nazeeruddin, P. Péchy, M. Takata, H. Miura, S. Uchida, and M. Grätzel, “High-efficiency organic-dye-sensitized solar cells controlled by nanocrystalline-TiO2 electrode thickness,” Adv. Mater.18(9), 1202–1205 (2006). [CrossRef]
- S. Ito, S. M. Zakeeruddin, R. Humphry-Baker, P. Liska, R. Charvet, P. Comte, M. K. Nazeeruddin, P. Péchy, M. Takata, H. Miura, S. Uchida, and M. Grätzel, “High-efficiency organic-dye-sensitized solar cells controlled by nanocrystalline-TiO2 electrode thickness,” Adv. Mater.18(9), 1202–1205 (2006). [CrossRef]
- M. Chigane, M. Watanabe, M. Izaki, I. Yamaguchi, and T. Shinagawa, “Preparation of hollow titanium dioxide shell thin films by electrophoresis and electrolysis for dye-sensitized solar cells,” Electrochem. Solid-State Lett.12(5), E5–E8 (2009). [CrossRef]
- J. H. Yoon, S. R. Jang, R. Vittal, J. Lee, and K. J. Kim, “TiO2 nanorods as additive to TiO2 film for improvement in the performance of dye-sensitized solar cells,” J. Photochem. Photobiol., A.180(1–2), 184–188 (2006). [CrossRef]
- C. J. BarbéF. Arendse, P. Comte, M. Jirousek, F. Lenzmann, V. Shklover, and M. Gratzel, “Nanocrystalline titanium oxide electrodes for photovoltaic applications,” J. Am. Ceram. Soc.80(12), 3157–3171 (1997). [CrossRef]
- S. Hore, C. Vetter, R. Kern, H. Smit, and A. Hinsch, “Influence of scattering layers on efficiency of dye-sensitized solar cells,” Sol. Energy Mater. Sol. Cells90(9), 1176–1188 (2006). [CrossRef]
- S. Hore, P. Nitz, C. Vetter, C. Prahl, M. Niggemann, and R. Kern, “Scattering spherical voids in nanocrystalline TiO2 – enhancement of efficieny in dye-sensitized solar cells,” Chem. Commun. (Camb.)41(15), 2011–2013 (2005). [CrossRef]
- R. Kern, R. Sastrawan, J. Ferber, R. Stangl, and J. Luther, “Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions,” Electrochim. Acta47(26), 4213–4225 (2002). [CrossRef]
- J.-H. Yum, S.-S. Kim, D.-Y. Kim, and Y.-E. Sung, “Electrophoretically deposited TiO2 photo-electrodes for use in flexible dye-sensitized solar cells,” J. Photochem. Photobiol., A173(1), 1–6 (2005). [CrossRef]
- S.-C. Yang, D.-J. Yang, J. Kim, J.-M. Hong, H.-G. Kim, I.-D. Kim, and H. Lee, “Hollow TiO2 hemispheres obtained by colloidal templating for application in dye-sensited solar cells,” Adv. Mater. (Deerfield Beach Fla.)20(5), 1059–1064 (2008). [CrossRef]
- S.-C. Yang, D.-J. Yang, J. Kim, J.-M. Hong, H.-G. Kim, I.-D. Kim, and H. Lee, “Hollow TiO2 hemispheres obtained by colloidal templating for application in dye-sensited solar cells,” Adv. Mater. (Deerfield Beach Fla.)20(5), 1059–1064 (2008). [CrossRef]
- E. S. Kwak, W. Lee, N.-G. Park, J. Kim, and H. Lee, “Compact inverse-opal electrode using non-aggregated TiO2 nanoparticles for dye-sensitized solar cells,” Adv. Funct. Mater.19(7), 1093–1099 (2009). [CrossRef]
- S.-C. Yang, D.-J. Yang, J. Kim, J.-M. Hong, H.-G. Kim, I.-D. Kim, and H. Lee, “Hollow TiO2 hemispheres obtained by colloidal templating for application in dye-sensited solar cells,” Adv. Mater. (Deerfield Beach Fla.)20(5), 1059–1064 (2008). [CrossRef]
- J. H. Yoon, S. R. Jang, R. Vittal, J. Lee, and K. J. Kim, “TiO2 nanorods as additive to TiO2 film for improvement in the performance of dye-sensitized solar cells,” J. Photochem. Photobiol., A.180(1–2), 184–188 (2006). [CrossRef]
- J.-H. Yum, S.-S. Kim, D.-Y. Kim, and Y.-E. Sung, “Electrophoretically deposited TiO2 photo-electrodes for use in flexible dye-sensitized solar cells,” J. Photochem. Photobiol., A173(1), 1–6 (2005). [CrossRef]
- S. Choi, E. N. Cho, S. M. Lee, Y. W. Kim, and D. W. Lee, “Evaluation of characteristics for dye-sensitized solar cell with reflector applied,” Opt. Express19(S4), A710–A715 (2011). [CrossRef] [PubMed]
- S. Choi, E. N. Cho, S. M. Lee, Y. W. Kim, and D. W. Lee, “Development of a high-efficiency laminated dye-sensitized solar cell with a condenser lens,” Opt. Express19(S4), A818–A823 (2011). [CrossRef] [PubMed]
- L. H. Hu, S. Y. Dai, J. Weng, S. F. Xiao, Y. F. Sui, Y. Huang, S. H. Chen, F. T. Kong, X. Pan, L. Y. Liang, and K. J. Wang, “Microstructure design of nanoporous TiO2 photoelectrodes for dye-sensitized solar cell modules,” J. Phys. Chem. B111(2), 358–362 (2007). [CrossRef] [PubMed]
- C.-Y. Kuo and S.-Y. Lu, “Fabrication of a multi-scale nanostructure of TiO2 for application in dye-sensitized solar cells,” Nanotechnology19(9), 095705 (2008). [CrossRef] [PubMed]
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